Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof
A technology of dimethylsiloxane and polyether copolymer, applied in the field of new linear polydimethylsiloxane-polyether copolymer, can solve problems such as high viscosity
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[0102] For the preparation of the copolymers of the present invention, the following linear aminosiloxanes are used, which are obtained from the method described in US5486634 by converting the corresponding α,ω-SiH-poly Dimethylsiloxane hydrosilation:
[0103]
[0104] The diepoxy compound used was from DOW Epoxy Systems ( The polypropylene glycol diglycidyl ether of R19) has an epoxy equivalent weight of 329 g / mol and an epoxy value of 171 mg KOH / g.
[0105] Viscosity was measured according to DIN 53019 at 25°C using a Brookfield (type LVT) rotary viscometer.
[0106] Determining the quaternary ammonium nitrogen content of the siloxane:
[0107] Determination of quaternary ammonium nitrogen by potentiometric titration using a dodecyl sulfate solution as titrant with a special solvent-resistant sensor electrode such as the Surfactrode Resistant (Metrohm AG) and a reference electrode (Ag / AgCl bridge double junction , Metrohm AG) composed of electrode combinations. Weigh...
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