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Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof

A technology of dimethylsiloxane and polyether copolymer, applied in the field of new linear polydimethylsiloxane-polyether copolymer, can solve problems such as high viscosity

Inactive Publication Date: 2012-10-10
EVONIK DEGUSSA GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The disadvantage of using is the inherently high viscosity which is characteristic of these random copolymeric structures

Method used

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  • Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof
  • Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof
  • Novel linear polydimethylsiloxane polyether copolymers having amino and/or quaternary ammonium groups and use thereof

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Experimental program
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Embodiment Construction

[0102] For the preparation of the copolymers of the present invention, the following linear aminosiloxanes are used, which are obtained from the method described in US5486634 by converting the corresponding α,ω-SiH-poly Dimethylsiloxane hydrosilation:

[0103]

[0104] The diepoxy compound used was from DOW Epoxy Systems ( The polypropylene glycol diglycidyl ether of R19) has an epoxy equivalent weight of 329 g / mol and an epoxy value of 171 mg KOH / g.

[0105] Viscosity was measured according to DIN 53019 at 25°C using a Brookfield (type LVT) rotary viscometer.

[0106] Determining the quaternary ammonium nitrogen content of the siloxane:

[0107] Determination of quaternary ammonium nitrogen by potentiometric titration using a dodecyl sulfate solution as titrant with a special solvent-resistant sensor electrode such as the Surfactrode Resistant (Metrohm AG) and a reference electrode (Ag / AgCl bridge double junction , Metrohm AG) composed of electrode combinations. Weigh...

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Abstract

Linear polydimethylsiloxane polyether copolymers having amino and / or quaternary ammonium groups obtainable by the reaction of organopolysiloxanes functionalised with secondary aminoalkyl groups with the reaction products from compounds containing epoxy groups and amines, to the use thereof and to a method for producing same.

Description

technical field [0001] The present invention relates to novel linear polydimethylsiloxane-polyether copolymers having amino and / or quaternary ammonium groups. The invention also relates to these polymers as fabrics, for example woven fabrics, in particular textile woven fabrics, tissue, nonwovens and / or fibers of natural and / or synthetic origin and / or leather, hair or Use of softeners for raw hides and related to their use in cosmetic applications, for example in hair care, skin care and personal hygiene. Background technique [0002] Softeners for fabrics, for example woven fabrics, in particular textile woven fabrics, knitted fabrics, nonwovens and / or fibers of natural and / or synthetic raw materials, are substances which give the material a soft hand. Particularly suitable softeners are polysiloxanes with quaternary ammonium groups. The ionic groups anchor the silicone to the fiber by virtue of electrostatic attraction. In this way friction is reduced and the desired so...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A61Q5/00C08G77/388C08G77/46
CPCC08G77/46A61Q19/00A61K8/898D06M15/647A61Q5/00C08G77/388D06M15/6436A61P17/00A61K8/89C08L83/12
Inventor F·舒伯特W·克诺特M·费伦茨K-D·克莱因T·毛雷尔R·朔伊尔曼B·W·克吕泽纳R·K·帕南迪科尔
Owner EVONIK DEGUSSA GMBH
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