Pharmaceutical compound for treating wastewater containing complex heavy metals and/or radioactive substances and application of pharmaceutical compound
A technology of compounding chemicals and heavy metals, applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of no obvious effect of anion removal, difficulty in resin regeneration, large investment in equipment and systems, etc., and achieve the effect of good sedimentation and enrichment effect.
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Embodiment 1
[0028] Example 1: Complex multi-metal comprehensive wastewater treatment.
[0029] A composite agent (RM-1, custom brand) that can be used to treat complex heavy metals and / or radioactive waste water of the present invention is prepared by uniformly mixing the following components:
[0030]
[0031] Then use inorganic Mn, Zn, Cu, Hg, Cd, Pb, Cr, Ni salts to prepare a wastewater sample containing multiple heavy metal ions as shown in Table 1 below, take out 100ml of water sample, place it in a beaker, and add to the water 100mL of the above-mentioned composite drug solution with a mass concentration of 2% (the following percentages are not specified unless otherwise specified) (the added amount of the composite drug in this example is 1.13 times the theoretical amount of heavy metals), which will be produced after 5 minutes of stirring A large amount of metal complex precipitates, then add 8ml, 1% concentration of magnesium hydroxide inorganic flocculant, stir for 5min, then add 5ml...
Embodiment 2
[0035] Example 2: Treatment of zinc oxide metallurgical wastewater.
[0036] A composite medicament (RM-2) of the present invention that can be used to treat complex heavy metals and / or radioactive waste water is prepared by uniformly mixing the following components:
[0037]
[0038] The zinc oxide metallurgical wastewater in this embodiment is a comprehensive wastewater produced by industrially leaching secondary zinc oxide powder with ammonium bicarbonate, removing impurities, distilling ammonia, and recycling ammonia to obtain basic zinc carbonate, which is washed with water and filtered press ( Washing water, press filter water), the heavy metals and ammonia nitrogen contained in it are shown in Table 2 below. To 100m in this embodiment 3 Add a solution of the above compound agent with a mass concentration of 3% to the wastewater 10m 3 (The addition amount of the composite agent in this example is 1.4 times the theoretical amount of heavy metals). After stirring for 5 minutes,...
Embodiment 3
[0042] Example 3: Treatment of metallurgical wastewater.
[0043] A composite medicament (RM-3) of the present invention that can be used to treat complex heavy metals and / or radioactive waste water is prepared by uniformly mixing the following components:
[0044] 6-methyl-8-hydroxyquinoline 28kg
[0045] Polyethylene polyamino sodium dithioformate 28kg and
[0046] Sodium diisopropyl dithiophosphate 44kg.
[0047] For the metallurgical wastewater of this embodiment, different doses of the composite agent (RM-3) of this embodiment were put into the range of 0.5 to 1.5 times, and the relationship between the addition and the treatment effect of heavy metals was tested. The results are shown in Table 3 below Show.
[0048] Table 3: The influence of the compound dosage on the treatment effect
[0049]
[0050] It can be seen from Table 3 that as the added amount of the compound agent increases, the removal rate increases. The removal rate increases rapidly within the range of 0.5 to 1.5 t...
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