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Low-temperature copper-based brazing filler metal for high-temperature resistance clean steel and preparation method thereof

A copper-based brazing filler metal and clean steel technology, applied in manufacturing tools, welding equipment, metal processing equipment, etc., can solve the problems that cannot meet the requirements of clean steel brazing, the influence of the base metal structure, and the high impurity content, and the cost is low. , Excellent brazing performance and the effect of reducing the introduction of impurities

Active Publication Date: 2012-11-14
ZHENGZHOU RES INST OF MECHANICAL ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, the solder produced by the current production process has a high brazing temperature for ordinary copper-based solder, which is likely to have a certain impact on the structure of the base metal; and second, the impurity content is generally high, which cannot meet the requirements for clean steel brazing.

Method used

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  • Low-temperature copper-based brazing filler metal for high-temperature resistance clean steel and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] a, by weight percentage: Cu84.68%, Ni4%, Mn10%, Zr0.2%, Hf0.2%, B0.02%, Ti0.1%, Ge0.8%;

[0021] b. The high melting point elements Ni, Zr, Hf are smelted with copper respectively to form master alloys A1, A2, A3; the master alloy A1 is composed of Cu:Ni=90:30 in weight ratio; the master alloy A2 is composed of Composition of Cu:Zr=91:9 in weight ratio; the master alloy A3 is composed of Cu:Hf=90:20 in weight ratio;

[0022] c, smelting easily oxidizable elements boron B, Ti, Ge and copper in a vacuum furnace respectively to form master alloys B1, B2, B3; said master alloy B1 is made up of Ni:B=86:14 in weight ratio; said The master alloy B2 is composed of Cu:Ti=80:20 in weight ratio; the master alloy B3 is composed of Cu:Ge=88:12 in weight ratio;

[0023] d. Put the remaining amount of copper and master alloy A1 in an induction furnace protected by argon gas, raise the temperature to 500-600°C at a speed of 30°C / min, and then raise the temperature to 1100-1300°C at a ...

Embodiment 2

[0026] a, by weight percentage: Cu52.25%, Ni10%, Mn30%, Zr1.8%, Hf3.5%, B0.2%, Ti0.25%, Ge2.0%;

[0027] b. The high melting point elements Ni, Zr, Hf are smelted with copper respectively to form master alloys A1, A2, A3; the master alloy A1 is composed of Cu:Ni=90:30 in weight ratio; the master alloy A2 is composed of Composition of Cu:Zr=91:9 in weight ratio; the master alloy A3 is composed of Cu:Hf=90:20 in weight ratio;

[0028] c, smelting easily oxidizable elements boron B, Ti, Ge and copper in a vacuum furnace respectively to form master alloys B1, B2, B3; said master alloy B1 is made up of Ni:B=86:14 in weight ratio; said The master alloy B2 is composed of Cu:Ti=80:20 in weight ratio; the master alloy B3 is composed of Cu:Ge=88:12 in weight ratio;

[0029] d. Put the remaining amount of copper and master alloy A1 in an induction furnace protected by argon gas, raise the temperature to 500-600°C at a speed of 30°C / min, and then raise the temperature to 1100-1300°C at a...

Embodiment 3

[0032] a, by weight percentage: Cu72.48, Ni5%, Mn20%, Zr0.5%, Hf 0.2%, W0.2%, Co0.5%, Ti 0.2%, B0.02%, Ge0.8%, Li0.1%;

[0033] b. The high melting point elements Ni, Zr, Hf, W, Co are smelted with copper respectively to form master alloys A1, A2, A3, A4, A5; the master alloy A1 is composed of Cu:Ni=90:30 by weight ; The master alloy A2 is composed of Cu:Zr=91:9 in weight ratio; the master alloy A3 is composed of Cu:Hf=90:20 in weight ratio; the master alloy A4 is composed of Cu in weight ratio : W=98:2 composition; the master alloy A5 is composed of Cu:Co=95:5 in weight ratio;

[0034] b. The easily oxidizable elements boron B, Ti, Ge, Li are smelted with copper in a vacuum furnace respectively to form master alloys B1, B2, B3, B4; the master alloy B1 is composed of Ni:B=86:14 in weight ratio Composition; the master alloy B2 is composed of Cu:Ti=80:20 by weight ratio; the master alloy B3 is composed of Cu:Ge=88:12 by weight ratio; the master alloy B4 is composed of Cu:Ge=88...

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Abstract

The invention provides a low-temperature copper-based brazing filler metal for high-temperature resistance clean steel and a preparation method thereof. The low-temperature copper-based brazing filler metal is prepared by raw materials in percentage by weight as follows: 4-10% of Ni, 10-30% of Mn, 0.2-1.8% of Zr, 0.2-3.5% of Hf, 0-1% of W, 0-1% of Co, 0.1-0.25% of Ti, 0.02-0.2% of B, 0.8-2.0% of Ge, 0-0.5% of Li and a residual amount of Cu. According to the low-temperature copper-based brazing filler metal provided by the invention, various trace elements are added in copper, so that the using property of the brazing filler metal is improved; a melting process is protected by using gas, a high-temperature resistant quartz glass tube is inserted into molten brazing filler metal alloy after being vacuumized to be in a negative pressure state, so that filament welding strips with different diameters can be directly obtained; techniques of later-stage squeezing, drawing in a reducing manner and the like can be cancelled; the introduction amount of impurities in a production process of the brazing filler metal can be reduced; the cleanliness of the brazing filler metal is improved; the brazing filler metal does not contain an easily-volatile element Zn and can be applicable to vacuum brazing; the brazing filler metal does not contain silver and does not contain any toxic elements; and the brazing filler metal has the advantages of low cost, no pollution, good brazing property and the like.

Description

technical field [0001] The invention relates to a low-temperature copper-based solder composition which can be made into filaments or flakes for high-temperature-resistant clean steel brazing and a preparation method thereof. Background technique [0002] Impurities in steel have a great influence on the production and performance of steel, so the research on clean steel is of great significance. Now, clean steel has been widely used as a material used under harsh conditions. Research and development and production of high-quality clean steel brazing materials with good production and service performance are becoming an important direction for the development of today's welding materials industry. [0003] At present, the solders used for brazing connection of steel materials in the process of use include tin-based, silver-based, copper-based, manganese-based, nickel-based, etc. The tin-based solder has a relatively low melting point, but its strength is also relatively low...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/30B23K35/40
Inventor 张冠星龙伟民鲍丽马力程亚芳朱坤黄俊兰樊江磊黄成志隋方飞
Owner ZHENGZHOU RES INST OF MECHANICAL ENG CO LTD
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