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Photosensitive resin composition, printing plate precursor, and flexographic printing plate

A technology of photosensitive resin and composition, applied in printing, printing plate, printing process and other directions, can solve the problems of not satisfying water developability, dryness and image reproducibility at the same time, time-consuming development process, low image reproducibility, etc. Achieve the effects of excellent image reproducibility, excellent image reproducibility, and excellent image reproducibility

Active Publication Date: 2015-08-19
SUMITOMO RIKO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, the photosensitive resin composition of Patent Document 1 has a problem that the developing process takes a long time because there are many components with low water solubility and / or water permeability.
The long development time is not only a problem of workability, but also the surface of the original printing plate is rubbed by the brush for a long time in order to remove the unhardened part during development, so the image reproducibility is low due to the loss of fine dots, etc.
[0009] In addition, Patent Document 2 contains a surfactant in the photosensitive resin composition in order to shorten the developing time, although this is effective for shortening the developing time, however, since the main component of the photosensitive resin composition is water-soluble or water-swellable polymer matter, so the drying time after water development is too long, so the practicality is low
[0010] Furthermore, if the surfactant of the composition disclosed in Patent Document 2 is simply added to the water-dispersible latex, the photopolymerizable monomer, the rubber, and the photopolymerization initiator of the composition disclosed in Patent Document 1, fine grains on the negative film can be reproduced. Image reproducibility of screen dots may decrease
[0011] Therefore, conventional photosensitive resin compositions do not satisfy water developability, dryness, and image reproducibility at the same time.

Method used

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  • Photosensitive resin composition, printing plate precursor, and flexographic printing plate
  • Photosensitive resin composition, printing plate precursor, and flexographic printing plate
  • Photosensitive resin composition, printing plate precursor, and flexographic printing plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0090]

[0091] 45.5 parts by mass of water-dispersible latex (25 parts by mass of solid polymer), 15 parts by mass of acrylic modified liquid BR, and 5 parts by mass of acrylic monomer were mixed, heated at 120° C. to evaporate water in a dryer In 2 hours, a mixture of the polymer obtained from the water-dispersible latex and the photopolymerizable monomer was obtained. This mixture was kneaded with 30 parts by mass of NBR and 2 parts by mass of surfactant in a kneader for 45 minutes. Then, 0.2 part by mass of a thermal polymerization inhibitor, 1 part by mass of a photopolymerization initiator, and 0.03 part by mass of an ultraviolet absorber were added to the kneader, and kneaded for 5 minutes to obtain the photosensitive resin composition of Example 1 .

[0092]

[0093] The photosensitive resin composition obtained above was sandwiched between a 125 μm thick PET film substrate pre-coated with an adhesive on one side and a 100 μm thick PET film protective film pre-coa...

Embodiment 2~11

[0096] (Examples 2 to 11, Comparative Examples 1 to 4)

[0097] From the components shown in Table 1 or Table 2, a photosensitive resin composition was prepared in the same manner as in Example 1, and then, a printing plate precursor and a flexographic printing plate were prepared in the same manner as in Example 1.

Embodiment 12

[0101]

[0102] Using the components shown in Table 1, the photosensitive resin composition of Example 12 was prepared in the same manner as in Example 1.

[0103]

[0104] Using blade stirring, 28.8 parts by mass of carbon black (manufactured by Mitsubishi Chemical Co., Ltd., trade name: MA8), 28.8 parts by mass of acrylic resin (manufactured by Negami Kogyo Co., Ltd., trade name: ハイパ一ル M4501) and 4.5 parts by mass 105.2 parts by mass of methyl isobutyl ketone was mixed with 105.2 parts by mass of a plasticizer (manufactured by Wako Pure Chemical Industries, Ltd., acetyl tributyl citrate). The obtained liquid mixture was dispersed with a triple roll mill, and methyl isobutyl ketone in a solid state of 15% by mass was added to obtain a coating material. Then, it was coated on a 100-μm-thick PET film with a dry coating film thickness of 2 μm using a bar coater, and dried at 120° C. for 5 minutes to obtain an infrared ablation layer / protective film laminate structure.

[01...

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Abstract

Disclosed is a photosensitive resin composition that provides an excellent water developability, drying property, and image reproducibility. The photosensitive resin composition comprises a water-dispersible latex (A), a rubber (B), a surfactant (C), a photopolymerizable monomer (D), and a photopolymerization initiator (E). A ratio of a mass of the component (C) to a total mass of the components (A), (B), and (C) is within a range of 0.1 to 20%. A ratio of a mass of the component (A) to a total mass of the components (A) and (B) is within 20 to 90%. A size of a dispersed phase consisting mainly of the component (B) is 10 µm or smaller.

Description

technical field [0001] The present invention relates to a photosensitive resin composition, a printing plate precursor, and a flexographic printing plate. Background technique [0002] In the past, letterpress printing, gravure printing or offset printing was performed on objects to be printed, such as packaging materials, labels and magazines, etc., using printing plates. Among them, letterpress printing is performed using letterpress. In this letterpress, flexographic printing plates can be used for a variety of objects to be printed, including objects to be printed that are made of soft materials. [0003] The original plate of the flexographic printing plate includes a photosensitive layer made of a photosensitive resin composition on a substrate of PET resin or the like. The flexographic printing plate irradiates the photosensitive layer with ultraviolet rays through the negative film in contact with the photosensitive layer, and the unhardened portion is removed to f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/00B41N1/12G03F7/004
CPCG03F7/032G03F7/033Y10T428/24479
Inventor 井上大辅松冈甲树
Owner SUMITOMO RIKO CO LTD
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