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A kind of anti-ultraviolet aging glass fiber reinforced polypropylene composite material and preparation method thereof

A technology for anti-ultraviolet aging and composite materials, applied in the field of anti-ultraviolet aging glass fiber reinforced polypropylene composite materials and their preparation, can solve the problem of limited anti-ultraviolet aging characteristics, failure to completely solve the antagonistic use, and lack of anti-ultraviolet aging properties, etc. problems, to achieve the effect of easy process, low equipment cost, and increased force

Active Publication Date: 2017-02-01
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process of this material is simple and easy, and the product performance is good, but the composite material also does not add a light stabilizer or adopt an anti-ultraviolet aging method, and does not have anti-ultraviolet aging performance
[0008] Chinese invention patent CN101735513A discloses an alkali-free short fiber reinforced polypropylene composite material. The composite material has excellent mechanical properties. At the same time, the light stability performance is improved by adding a hindered amine light stabilizer. The antagonism between alkalis has not been completely resolved, so the anti-ultraviolet aging properties are limited

Method used

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  • A kind of anti-ultraviolet aging glass fiber reinforced polypropylene composite material and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033]Weigh respectively dry copolymerized polypropylene 87.0%, alkali-free glass fiber 10.0%, compatibilizer PP-g-MAH is 2.5%, antioxidant 1010 is 0.3%, antioxidant 168 is 0.1%, light Stabilizer phenyl o-hydroxybenzoate is mixed at 0.1%, and the uniformly mixed material is added to a twin-screw extruder, melted and extruded, and then water-cooled, and cut into 1-5mm in length by a pelletizer particle. Among them, the processing temperature of the extruder is 180°C, 195°C, 210°C, 210°C, 220°C from the feeding port to the die port in sequence, the main engine speed is 60-80rpm, and the vacuum degree is 0.3MPa. Then, the composite material particles and ASA were added into a high-speed mixer in a mass ratio of 95:5 for mechanical mixing. The speed of the high-speed mixer was 1000 rpm, and the final product could be obtained after stirring for 3 minutes.

Embodiment 2

[0035] Take by weighing 80.0% dry good copolymer polypropylene, alkali-free glass fiber 17.0%, compatibilizer PP-g-MAH is 1.2%, compatibilizer ASA-g-MAH is 1%, antioxidant 1010 is 0.3%, the antioxidant DSTDP is 0.1%, and the light stabilizer 2-hydroxyl-4-n-octyloxybenzophenone is 0.4% for mixing, and the uniformly mixed material is added to the twin-screw extruder, and melted Extruded, then water-cooled, cut into particles with a length of 1-5mm by a pelletizer. Among them, the processing temperature of the extruder is 180°C, 195°C, 210°C, 210°C, 220°C from the feeding port to the die port in sequence, the main engine speed is 60-80rpm, and the vacuum degree is 0.3MPa. Then add the particles and ASA into the high-speed mixer according to the mass ratio of 95:5 and mix mechanically. The speed of the high-speed mixer is 1000rpm, and it can be stirred for 3 minutes.

Embodiment 3

[0037] Weigh 75.0% of dry copolymerized polypropylene by weight, 20.0% of alkali-free glass fiber, 2.3% of compatibilizer PP-g-MAH, 2.0% of EPDM-g-MAH, and 0.1% of antioxidant 1010 %, the light stabilizer 2,4-dihydroxybenzophenone is mixed at 0.6%, and the uniformly mixed material is added to a twin-screw extruder, melted and extruded, and then water-cooled, cut by a pelletizer Grow particles with a length of 1-5mm. Among them, the processing temperature of the extruder is 180°C, 195°C, 210°C, 210°C, 220°C from the feeding port to the die port in sequence, the main engine speed is 60-80rpm, and the vacuum degree is 0.3MPa. Then add the particles and ASA into the high-speed mixer according to the mass ratio of 93:7 and mix mechanically. The speed of the high-speed mixer is 1000rpm, and stir for 3 minutes.

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Abstract

The invention discloses an anti-ultraviolet aging glass fiber reinforced polypropylene composite material and a preparation method thereof. The composite material is composed of glass fiber reinforced polypropylene composite material particles and ASA at a mass ratio of 95:5-90:10; The fiber-reinforced polypropylene composite particle is composed of polypropylene, glass fiber, compatibilizer, antioxidant and light stabilizer. The material has strong anti-ultraviolet aging properties, and at the same time has the high strength and high toughness of the glass fiber reinforced polypropylene composite material; and the preparation process is simple, the production cost is low, and there is no secondary pollution.

Description

technical field [0001] The invention belongs to the technical field of polymer composite materials, and in particular relates to an anti-ultraviolet aging glass fiber reinforced polypropylene composite material and a preparation method thereof. Background technique [0002] Glass fiber reinforced plastic is a light-weight and high-strength engineering structural material. Because the fiber has good mechanical properties, when there is an external force, the load is transmitted through the fiber, so the tensile, bending, impact strength and resistance of glass fiber reinforced plastic Creep and fatigue resistance are far better than non-reinforced plastics, and have excellent rigidity, toughness, and warpage resistance, and their prices are much lower than engineering plastics. Glass fiber reinforced plastics are widely used, and about 50% of glass fiber reinforced plastics are used in the automotive industry in Western Europe. The performance of glass fiber reinforced plast...

Claims

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Application Information

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IPC IPC(8): C08L23/14C08L51/06C08K13/06C08K9/06C08K9/04C08K7/14C08K5/134C08K5/3475C08K5/132C08L51/00
Inventor 杨桂生汪海孙利明
Owner HEFEI GENIUS NEW MATERIALS
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