Method for reducing pouring temperature of iron-based surface composite material

A surface composite material and pouring temperature technology, applied in the field of iron-based composite materials, can solve the problems of difficulty in sand mold preheating, performance degradation of high-chromium cast iron, difficulty in meeting the requirements of the workpiece for wear-resistant layer thickness, etc., and achieve easy operation , low cost effect

Inactive Publication Date: 2013-02-13
XINGHUA PRECISION CASTING & FORGING IND RES INST CO LTD
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Problems solved by technology

[0002] High chromium cast iron has excellent wear resistance and is widely used in wear-resistant parts such as grinding rollers, liners, and blow bars in industries such as cement and electric power. Under harsh abrasive conditions such as hard abrasives and high impact, high-chromium castings fail rapidly and cannot meet the requirements of users; therefore, particle-reinforced iron-based surface composites with better wear resistance have attracted more and more researchers. And producers are concerned, studies have shown that the melt infiltration method is currently one of the most suitable processes for preparing iron-based surface composites, but due to the limitations of reinforcing materials and preparation processes, the thickness of the composite layer of iron-based surface composites is often not More than 10mm, in many cases it is difficult to meet the requirements of the workpiece for the thickness of the wear-resistant layer
[0003] Patent CN102310183A discloses a high wear-resistant iron-based composite material and its preparation method. The preparation method includes the following steps: 1) Select large-sized fused zirconium corundum particles; 2) Prepare zirconium corundum particle ceramic blocks from the above-mentioned fused zirconia corundum particles, and cool them for use; 3) Place the above-mentioned zirconium corundum particle ceramic blocks on the top of the resin sand mold cavity for casting and infiltration process, and take out the box; 4) Heat treatment of the obtained zirconium corundum particles reinforced iron-based composite material, the inventive method is simple and convenient, and the thickness of the composite layer can be adjusted in a wide range; some researchers also proposed that ZTA with a particle size of 1-3 mm (ZrO2toughened Al2O3) ceramic particles are made into a honeycomb porous ceramic preform, and then cast high-chromium cast iron metal liquid casting Infiltrated ceramic preforms, successfully prepared ceramic particles reinforced high-chromium cast iron matrix composites (Casting, 2012, 61(2): 165.); however, the pouring temperature of the above two methods is lower than the usual pouring temperature of high-chromium cast iron workpieces The former is 1540~1590℃, and the latter is also 1450~1500℃; in these casting infiltration methods, due to the cooling effect of the preformed block of ceramic particles, it is difficult to achieve compounding at a lower pouring temperature, and higher On the one hand, the high pouring temperature reduces the performance of high chromium cast iron, and at the same time puts forward higher requirements for smelting equipment. Although preheating the sand mold can improve the composite effect to a certain extent, it is difficult to preheat the sand mold, and the effect is also low. Not obvious; therefore, it is urgent to take an effective method to reduce the pouring temperature of high chromium cast iron under the premise of ensuring the composite effect

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  • Method for reducing pouring temperature of iron-based surface composite material

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Embodiment 1

[0016] This embodiment specifically implements a method for reducing the pouring temperature of the particle-reinforced iron-based surface composite material. The thickness of the surface composite layer of the iron-based composite material to be prepared is 30 mm. The specific process is: 2 O 3 Powder, Cr 2 O 3 The powder and Al powder are mixed in a mass ratio of 15:5:10 by ball milling until they are uniform, and then pressed into a cylinder with a diameter of 5mm and a length of 33mm under a pressure of 50MPa, and are wrapped in aluminum foil and heated at 150°C 40min, then fix the columnar reactant on the inner wall of the flask by bonding method, and put it into a ceramic particle preformed block with hexagonal prism holes made of fused zirconium corundum particles by conventional adhesive bonding method , The inner circle diameter of the hexagonal prism hole is 7mm, and the hexagonal prism hole corresponds to the position of the cylindrical reactant, and each hole correspo...

Embodiment 2

[0018] This embodiment specifically implements a method for reducing the pouring temperature of the particle-reinforced iron-based surface composite material. The thickness of the surface composite layer of the iron-based composite material to be prepared is 40 mm. The specific process is: 2 O 3 Powder, Cr 2 O 3 The powder and Al powder are mixed in a mass ratio of 21:9:10 by ball milling until uniform, and then pressed into a cylinder with a diameter of 8 mm and a length of 45 mm under a pressure of 100 MPa, which is wrapped in aluminum foil and heated at 200 ℃ 40min, then fix the columnar reactant on the inner wall of the flask by inserting method, and put it into a ceramic particle preformed block with hexagonal prism holes made of fused zirconium corundum particles by conventional adhesive bonding method. The inner circle diameter of the hexagonal prism hole is 11mm, and the hexagonal prism hole corresponds to the position of the cylindrical reactant, and each hole correspond...

Embodiment 3

[0020] This embodiment specifically implements a method for reducing the casting temperature of the particle-reinforced iron-based surface composite material. The thickness of the surface composite layer of the iron-based composite material to be prepared is 35mm, and the specific process is: 2 O 3 Powder, Cr 2 O 3 The powder and Al powder are mixed in a mass ratio of 18:7:10 by ball milling until they are uniform, and then pressed into a cylinder with a diameter of 7mm and a length of 39mm under a pressure of 80MPa, which is wrapped in aluminum foil and heated at 180°C 35min, then fix the columnar reactant on the inner wall of the flask by inserting method, and put it in the ZrO 2 Toughened Al 2 O 3 The preformed block of ceramic particles with hexagonal prism holes is made of particles. The inner diameter of the hexagonal prism hole is 9mm. The hexagonal prism hole corresponds to the position of the cylindrical reactant, and each hole corresponds to a cylindrical reactant unit. ...

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Abstract

The invention relates to an iron-based composite material and especially relates to a method for reducing pouring temperature of iron-based surface composite material through heat release of thermit reaction, wherein the principle is as follows: triggering the thermit reaction by heating molten iron, counteracting the cooling effect of a ceramic particle pre-forming block on the molten iron through the heat release part of the thermit reaction, and simultaneously forming an alloy having the ingredients the same as that of a high-chromium iron substrate through the thermit reaction; in order to generate no effect on the distribution of the ceramic reinforcement particles and improve the wearing resistance of the hexagonal prism hole or honeycomb hole part, the reactant of the thermit reaction is processed to a cylindrical shape and is added in the hexagonal prism hole or honeycomb hole of the ceramic particle pre-forming block, the reactant powder is mixed and is pressed to the cylindrical shape so as to conveniently process and apply the cylindrical reactant, and the reactant powder is wrapped by an aluminum foil to prevent the cylinder from being broken and prevent the reactant powder from dropping.

Description

technical field [0001] The invention relates to an iron-based composite material, in particular to a method for reducing the pouring temperature of an iron-based surface composite material by utilizing the exothermic heat of the aluminothermic reaction. technical background [0002] High chromium cast iron has excellent wear resistance, and is widely used in wear-resistant parts such as grinding rollers, liners, and blow bars in cement and electric power industries. Parts fail rapidly and still cannot meet the requirements of users; therefore, particle-reinforced iron-based surface composites with better wear resistance have attracted more and more researchers and producers' attention. Studies have shown that the melt infiltration method is currently the One of the most suitable processes for preparing iron-based surface composite materials. However, due to the limitations of reinforcing materials and preparation processes, the thickness of the composite layer of iron-based ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22D19/14
Inventor 陈刚赵玉涛季鹏飞丁鼎
Owner XINGHUA PRECISION CASTING & FORGING IND RES INST CO LTD
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