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Carbon fiber-containing ammonia storage mixture porous solid sample coupon and preparation method thereof

A porous solid and carbon fiber technology, which is applied in the direction of ammonia compounds, chemical instruments and methods, and other chemical processes, can solve the problems of no dosage ratio, no clear claim details, technical personnel can not implement, etc., to meet the use requirements , The effect of improving the ammonia storage characteristics

Active Publication Date: 2013-02-20
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this patent uses solid material for direct compression molding, uses a binder, only states that it may be a silica fiber binder, and does not have a dosage ratio, and other claims and examples only declare solid materials It may include granular materials, porous materials, crystalline materials, amorphous materials or their combinations. Without clear claim details, it is almost impossible for those skilled in the industry to implement, thus resulting in this patent

Method used

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  • Carbon fiber-containing ammonia storage mixture porous solid sample coupon and preparation method thereof

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Effect test

Embodiment 1

[0018] (1) 68wt% of industrial anhydrous strontium chloride salt powder, 8wt% of carbon fiber, 4wt% of industrial ball clay, 12wt% of deionized water and 8wt% of industrial alcohol to form a mixture;

[0019] (2) The mixture is stirred evenly by a mixer for 1 hour to form a semi-dry mixed powder;

[0020] (3) Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 30 minutes to form a wet body sample;

[0021] (4) The sample block is at 80°C and the vacuum degree is 10 -1 Drying under the condition of kPa for 4h can obtain the active ammonia storage mixture porous solid sample block containing 10wt% carbon fiber.

[0022] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill the ammonia slowly within the pre...

Embodiment 2

[0024] (1) A mixture of 80wt% industrial anhydrous strontium chloride salt powder, 4wt% carbon fiber, 3wt% industrial spherical clay, 7wt% deionized water and 6wt% industrial alcohol;

[0025] (2) The mixture is stirred evenly by a mixer for 10 hours to form a semi-dry mixed powder;

[0026] (3) Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 60 minutes to form a wet body sample;

[0027] (4) The sample block was dried for 1 hour at 60°C under a vacuum of 1kPa to obtain a porous solid sample block of the active ammonia storage mixture containing 4.6wt% carbon fibers.

[0028] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill the ammonia slowly within the pressure range of 0.4Mpa, the ammonia filli...

Embodiment 3

[0030] (1) A mixture of 75wt% industrial anhydrous strontium chloride salt powder, 10wt% carbon fiber, 2wt% industrial ball clay, 3wt% deionized water and 10wt% industrial alcohol;

[0031] (2) The mixture is stirred evenly by a mixer for 4 hours to form a semi-dry mixed powder;

[0032] (3) Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 40 minutes to form a wet body sample;

[0033] (4) Dry the sample block at 100°C for 4 hours to obtain a porous solid sample block of the active ammonia storage mixture containing 11wt% carbon fibers.

[0034] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.2Mpa, the ammonia filling time is 7h; after ammonia filling...

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Abstract

The invention relates to a carbon fiber-containing ammonia storage active mixture porous solid sample coupon and a preparation method thereof. The ammonia storage active mixture porous solid sample coupon is mainly composed of anhydrous strontium chloride, carbon fibers and industrial ball clay. The preparation method comprises the steps of mixing industrial anhydrous strontium chloride powder, the carbon fibers, the industrial ball clay, ionized water and industrial alcohol; stirring the mixture uniformly with a stirring machine to form half-dried mixed powder; adding the half-dried mixed powder to a closed container capable of being opened to perform mechanical oscillation so as to form a wet sample coupon; and drying the coupon under a condition with a temperature of 60-80 DEG C and a vacuum degree of 10<-1>-1 kPa or drying at a temperature of 100 DEG C. The solid sample coupon guarantees the ammonia storage characteristic of the metal salt, increases the mechanical strength and structure stability of the mixture sample coupon, can prevent the powder falling phenomenon caused by oscillation during the using process from occurrence.

Description

technical field [0001] The invention relates to a porous solid sample block of an ammonia storage mixture containing carbon fiber and a preparation method thereof, which is applied to an automobile tail gas post-treatment system and a fuel cell system. Background technique [0002] Energy crisis and environmental pollution are two very serious problems that human beings must face in the 21st century. People are still facing many problems in the selection of technical means to meet the emission standards of traditional vehicles, and in the fuel supply technology of new energy vehicles. [0003] The automobile exhaust after-treatment system is a system that relies on the precise supply of urea reducing agent and decomposes it into ammonia gas at the front end of the catalyst to remove NOX harmful substances, thereby achieving the purpose of purifying exhaust gas. However, in actual use, there are many deficiencies and difficulties in the metered injection of liquid urea that ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30C01C1/00
Inventor 张克金崔龙姜涛王丹王金星安宇鹏于力娜许德超
Owner CHINA FIRST AUTOMOBILE
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