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Porous solid sample block of ammonia storage active mixture containing industrial clay and preparation method thereof

A technology of active mixtures and porous solids, applied in the direction of ammonia compounds, silicon compounds, alkali metal compounds, etc., can solve the problems that technical personnel cannot implement, have no dosage ratio, and have no clear claim details, etc., to increase the number of macroscopic pores , improve the adsorption characteristics and meet the requirements of use

Active Publication Date: 2016-01-20
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this patent uses solid material for direct compression molding, uses a binder, only states that it may be a silica fiber binder, and does not have a dosage ratio, and other claims and examples only declare solid materials It may include granular materials, porous materials, crystalline materials, amorphous materials or their combinations. Without clear claim details, it is almost impossible for those skilled in the industry to implement

Method used

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  • Porous solid sample block of ammonia storage active mixture containing industrial clay and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] 36wt% industrial anhydrous strontium chloride salt powder, 24wt% industrial clay, 2wt% high specific surface area activated carbon, 12wt% deionized water and 26wt% industrial alcohol form a mixture, which is stirred evenly by a mixer, and the stirring time is After 1 hour, a semi-dry mixed powder is formed; the powder is added into an openable airtight container, subjected to mechanical vibration for 30 minutes, and then dried at 80°C for 1 hour under the condition of a vacuum of 1Kpa to obtain a content of 38.7 Porous solid samples of ammonia storage active mixture of wt% clay for industrial use.

[0016] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.6Mpa, and the ammonia filling time is ...

Embodiment 2

[0018] 80wt% of industrial anhydrous strontium chloride salt powder, 4wt% of industrial clay, 7wt% of high specific surface area activated carbon, 4wt% of deionized water and 5wt% of industrial alcohol form a mixture, which is stirred evenly by a mixer, and the stirring time is After 5 hours, a semi-dry mixed powder is formed; the powder is added to an openable airtight container and mechanically shaken for 60 minutes, and then at 60°C, the vacuum degree is 10 -1 Under the condition of Kpa, dry for 3h, you can get the porous solid sample block of ammonia storage active mixture containing 4.3wt% industrial clay 。

[0019] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill the ammonia slowly within the pressure range of 0.1Mpa, the ammonia filling...

Embodiment 3

[0021] 70wt% of industrial anhydrous strontium chloride salt powder, 15wt% of industrial clay, 5wt% of high specific surface area activated carbon, 5wt% of deionized water and 5wt% of industrial alcohol form a mixture, which is stirred evenly by a mixer, and the stirring time is After 10 hours, a semi-dry mixed powder was formed; the powder was added into an openable airtight container, mechanically shaken for 60 minutes, and then dried for 3 hours at a temperature of 100°C to obtain a powder containing 16.7wt% industrial clay. Ammonia storage active mixture porous solid sample block 。

[0022] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.4Mpa, and the ammonia filling time is 5h; after ammonia ...

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Abstract

The invention relates to a porous solid sample block of an ammonia storage active mixture containing industrial clay, which is composed of anhydrous strontium chloride, industrial clay and activated carbon with a high specific surface area, and is characterized by a preparation method thereof, and the specific steps are as follows: Industrial anhydrous strontium chloride salt powder 36~80wt%, industrial clay 4~24wt%, high specific surface area activated carbon 2~7wt%, deionized water 4~12wt% and industrial alcohol composition mixture 5~26wt%, stirred by a mixer Evenly, stir for 1~10h to form a semi-dry mixed powder; add the powder into an open airtight container for mechanical vibration for 30~60min, and then at 60~80℃, the vacuum degree is 10-1~ Dry at 1Kpa for 1~3h, or at 90~100℃ for 3~4h. The ammonia storage mixture porous solid sample containing metal salt and industrial clay prepared by it not only ensures the ammonia storage characteristics of the metal salt but also effectively improves the viscosity and mechanical strength of the mixture sample. In the process of sample block, an appropriate amount of activated carbon with high specific surface area is also added, which improves the adsorption characteristics of the mixture sample block and increases the number of macroscopic pores of the mixture sample block.

Description

technical field [0001] The invention relates to a porous solid sample block of an ammonia storage active mixture containing industrial clay and a preparation method thereof, which are applied to an SCR post-treatment system of automobile tail gas and an FCEV fuel cell system. Background technique [0002] Energy and environmental issues are two very difficult issues that human beings must face in the 21st century. People still face many problems in terms of meeting emission standards for traditional vehicles and fuel supply for new energy vehicles. The SCR post-treatment system of automobile exhaust gas relies on the precise supply of urea reducing agent and decomposes it into ammonia gas at the front end of the catalyst, and then removes NOX harmful substances to achieve the purpose of purifying exhaust gas. However, in actual use, there are many shortcomings and difficulties in the metered injection of liquid urea that relies on the decomposition of urea into ammonia gas....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/10B01J20/28B01J20/30C01C1/00
Inventor 张克金崔龙姜涛王丹王金星安宇鹏于力娜许德超
Owner CHINA FIRST AUTOMOBILE
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