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A kind of ammonia storage active mixture sample block with rich pores and preparation method thereof

A technology of active mixture and mixture, which is applied in the field of ammonia-storage active mixture samples with rich channels and its preparation, can solve the problems of lack of clear claim details and technical personnel's inability to implement, and achieve the effect of meeting the requirements of use

Active Publication Date: 2016-05-04
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent uses solid material for direct compression molding, uses binder, only declares that it may be silica fiber binder, and does not add the proportion, and other claims and examples only state that the solid material may include Composition of granular materials, porous materials, crystalline materials, amorphous materials or their combinations, without clear claim details, it is almost impossible for those skilled in the industry to implement

Method used

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  • A kind of ammonia storage active mixture sample block with rich pores and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] 73wt% industrial anhydrous strontium chloride salt powder, 8wt% sucrose, 5wt% molecular sieve and 14wt% industrial alcohol are used to form a mixture; the mixture is stirred evenly by a mixer for 1 hour to form a semi-dry mixed powder; The semi-dry mixed powder is added into an openable airtight container and mechanically shaken for 30 minutes to form a wet sample block; the sample block is sintered at 350°C for 4 hours to obtain a solid sample of the ammonia storage mixture containing amorphous carbon piece.

[0013] Fill the 10g solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container into a water tank with enough cooling water in advance, connect the ammonia steel cylinder, and pass through the pressure reducing valve and drying system. Ammonia charging is carried out slowly within the pressure range of 0.4Mpa, and the ammonia charging time is 5 hours; after ammonia charging, the mass of the sample block is 14.2g, tha...

Embodiment 2

[0015] 81wt% industrial anhydrous strontium chloride salt powder, 3wt% sucrose, 5wt% molecular sieve and 11wt% industrial alcohol are used to form a mixture; the mixture is stirred evenly by a mixer for 5 hours to form a semi-dry mixed powder; The semi-dry mixed powder is added into an openable airtight container and mechanically shaken for 30 minutes to form a wet sample block; the sample block is sintered at 450°C for 3 hours to obtain a solid sample of the ammonia storage mixture containing amorphous carbon piece.

[0016] Fill the 10g solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container into a water tank with enough cooling water in advance, connect the ammonia steel cylinder, and pass through the pressure reducing valve and drying system. Charge ammonia slowly within the pressure range of 0.3Mpa, and the ammonia charging time is 5 hours; after ammonia charging, the mass of the sample block is 14.6g, that is, 4.6g of am...

Embodiment 3

[0018] 69wt% industrial anhydrous strontium chloride salt powder, 11wt% sucrose, 10wt% molecular sieve and 10wt% industrial alcohol are used to form a mixture; the mixture is stirred evenly by a mixer for 10 hours to form a semi-dry mixed powder; The semi-dry mixed powder is added into an openable airtight container and mechanically shaken for 40 minutes to form a wet sample block; the sample block is sintered at 400°C for 5 hours to obtain a solid sample of the ammonia storage mixture containing amorphous carbon piece.

[0019] Fill the 10g solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container into a water tank with enough cooling water in advance, connect the ammonia steel cylinder, and pass through the pressure reducing valve and drying system. Charge ammonia slowly within the pressure range of 0.4Mpa, and the ammonia charging time is 4 hours; after ammonia charging, the mass of the sample block is 13.8g, that is, 3.8g of...

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Abstract

The invention relates to a sample block of an ammonia storage active mixture with rich channels, which is composed of anhydrous strontium chloride, amorphous carbon and molecular sieve, and is characterized in that the preparation method thereof, the specific steps are as follows: industrial anhydrous strontium chloride salt powder, Sucrose, molecular sieve and industrial alcohol form a mixture; the mixture is stirred evenly by a mixer to form a semi-dry mixed powder; the semi-dry mixed powder is added to an openable airtight container for mechanical vibration to form a wet body sample block; the sample block is sintered at 350~450°C for 3~5h to obtain a porous solid sample block of the ammonia storage mixture containing amorphous carbon. The ammonia storage mixture solid sample block containing metal salt and amorphous carbon prepared by it not only ensures the ammonia storage characteristics of the metal salt but also improves the adsorption efficiency and adsorption capacity of the mixture sample block. In the process of preparing the ammonia storage active mixture, An appropriate amount of molecular sieve is also added to make the solid sample of the mixture rich in microscopic and nanopore channels, with several large pores in the macroscopic view, with faster ammonia filling and better ammonia storage performance, and can quickly release ammonia gas, which can be recycled without breaking. With high-efficiency adsorption and desorption characteristics, it is suitable for the adsorption and storage of ammonia.

Description

technical field [0001] The invention relates to an ammonia-storage active mixture sample block with abundant pores and a preparation method thereof, which are applied to a post-treatment system of automobile exhaust and a hydrogen fuel cell system of a new energy automobile. Background technique [0002] At present, the world is facing the dual challenges of energy crisis and environmental crisis. People are still facing many problems in the selection of technical means to meet the emission standards of traditional vehicles, and in the fuel supply technology of new energy vehicles. [0003] In terms of traditional automobiles, the SCR after-treatment system relies on the precise supply of urea reducing agent and decomposes it into ammonia gas at the front end of the catalyst to remove NOX hazards, achieve the purpose of purifying exhaust gas, and achieve the vehicle's National 4 or above standards. However, in actual use, there are many deficiencies and difficulties in the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/30C01C1/02
Inventor 张克金崔龙姜涛王丹林伟青王金星安宇鹏于力娜许德超
Owner CHINA FIRST AUTOMOBILE
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