Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Porous solid test piece for storing ammonia and preparation method thereof

A porous solid and sample block technology, which is applied in the preparation/separation of ammonia, chemical instruments and methods, and other chemical processes, can solve the problems of lack of clear claim details and technical personnel's inability to implement it, and meet the requirements of use Effect

Active Publication Date: 2015-07-01
CHINA FIRST AUTOMOBILE
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent uses solid material for direct compression molding, uses binder, only declares that it may be silica fiber binder, and does not add the proportion, and other claims and examples only state that the solid material may include Composition of granular materials, porous materials, crystalline materials, amorphous materials or their combinations, without clear claim details, it is almost impossible for those skilled in the industry to implement

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Porous solid test piece for storing ammonia and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] Mix 79wt% industrial anhydrous strontium chloride salt powder, 4wt% clay, 2wt% expanded graphite and 15wt% industrial alcohol to form a mixture, and stir evenly with a mixer for 1 hour to form a semi-dry mixed powder; Add the semi-dry mixed powder into an openable airtight container and perform mechanical vibration for 60 minutes to form a wet body sample; -1 Dry for 3 hours under the condition of Kpa ​​to obtain a porous solid sample block of ammonia storage active mixture containing 4.7wt% clay.

[0014] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill the ammonia slowly within the pressure range of 0.3Mpa, the ammonia filling time is 5h; after the ammonia filling, the mass of the sample block is 14.7g, that is, the adsorbed ammonia ga...

Embodiment 2

[0017] 82wt% of industrial anhydrous strontium chloride salt powder, 6wt% of clay, 6wt% of expanded graphite and 6wt% of industrial alcohol are used to form a mixture, which is stirred evenly by a mixer for 5 hours to form a semi-dry mixed powder; Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 60 minutes to form a wet body sample; then dry it for 1 hour at 80°C and a vacuum of 1Kpa to obtain 6wt % clay ammonia storage active mixture porous solid sample block.

[0018] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.4Mpa, the ammonia filling time is 5h; after ammonia filling, the mass of the sample block is 14.3g, that is, 4.3g of ammonia gas is adsor...

Embodiment 3

[0020] 72wt% industrial anhydrous strontium chloride salt powder, 10wt% clay, 8wt% expanded graphite and 10wt% industrial alcohol are used to form a mixture, and stirred evenly by a mixer for 10 hours to form a semi-dry mixed powder; Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 30 minutes to form a wet body sample; then dry it at 100°C for 4 hours to obtain the ammonia storage activity containing 11wt% clay. Mixture of porous solid samples.

[0021] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.4Mpa, the ammonia filling time is 5h; after ammonia filling, the mass of the sample block is 14g, that is, 4g of ammonia gas is adsorbed. Then the sample...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a porous solid test piece for storing ammonia. The preparation method of the porous solid test piece comprises the following steps: mixing industrial anhydrous strontium chloride powder, clay, expanded graphite and industrial alcohol to form a mixture, and evenly stirring with a stirrer to form semidry mixture powder; adding the semidry mixture powder into an openable closed container, and carrying out mechanical oscillation to form a wet test piece; and drying at 60-80 DEG C under the vacuum degree of 1-10<-1>Kpa. The invention effectively improves the viscosity and mechanical strength of the mixture on the premise of ensuring the ammonia storage characteristic of the metal salt; by adding the expanded graphite, the strontium chloride metal salt powder has more NH3 molecular channels, thereby generating large specific area and enhancing the adsorption capacity of the mixture porous solid test piece; and the stable skeleton structure of the expanded graphite provides powerful guarantee for possible structure collapse of the mixture in the repeated adsorption / desorption process.

Description

technical field [0001] The invention relates to a porous solid sample block for storing ammonia and a preparation method thereof, which is applied to a post-treatment system of automobile exhaust and a hydrogen fuel cell system of a new energy automobile. Background technique [0002] Today, the world is facing the dual challenges of energy crisis and environmental crisis. People are still facing many problems in the selection of technical means to meet the emission standards of traditional vehicles, and in the fuel supply technology of new energy vehicles. [0003] In terms of traditional automobiles, the SCR aftertreatment system relies on the precise supply of urea reducing agent and decomposes it into ammonia at the front end of the catalyst to remove NOX hazards, thereby achieving the purpose of purifying exhaust gas. However, in actual use, there are many deficiencies and difficulties in the metered injection of liquid urea that relies on urea decomposed into ammonia ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/20B01J20/28B01J20/30C01C1/02
Inventor 张克金崔龙姜涛王丹王金星安宇鹏于力娜许德超
Owner CHINA FIRST AUTOMOBILE
Features
  • Generate Ideas
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More