Porous solid test piece for storing ammonia and preparation method thereof
A porous solid and sample block technology, which is applied in the preparation/separation of ammonia, chemical instruments and methods, and other chemical processes, can solve the problems of lack of clear claim details and technical personnel's inability to implement it, and meet the requirements of use Effect
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Embodiment 1
[0013] Mix 79wt% industrial anhydrous strontium chloride salt powder, 4wt% clay, 2wt% expanded graphite and 15wt% industrial alcohol to form a mixture, and stir evenly with a mixer for 1 hour to form a semi-dry mixed powder; Add the semi-dry mixed powder into an openable airtight container and perform mechanical vibration for 60 minutes to form a wet body sample; -1 Dry for 3 hours under the condition of Kpa to obtain a porous solid sample block of ammonia storage active mixture containing 4.7wt% clay.
[0014] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill the ammonia slowly within the pressure range of 0.3Mpa, the ammonia filling time is 5h; after the ammonia filling, the mass of the sample block is 14.7g, that is, the adsorbed ammonia ga...
Embodiment 2
[0017] 82wt% of industrial anhydrous strontium chloride salt powder, 6wt% of clay, 6wt% of expanded graphite and 6wt% of industrial alcohol are used to form a mixture, which is stirred evenly by a mixer for 5 hours to form a semi-dry mixed powder; Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 60 minutes to form a wet body sample; then dry it for 1 hour at 80°C and a vacuum of 1Kpa to obtain 6wt % clay ammonia storage active mixture porous solid sample block.
[0018] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.4Mpa, the ammonia filling time is 5h; after ammonia filling, the mass of the sample block is 14.3g, that is, 4.3g of ammonia gas is adsor...
Embodiment 3
[0020] 72wt% industrial anhydrous strontium chloride salt powder, 10wt% clay, 8wt% expanded graphite and 10wt% industrial alcohol are used to form a mixture, and stirred evenly by a mixer for 10 hours to form a semi-dry mixed powder; Add the semi-dry mixed powder into an openable airtight container and shake it mechanically for 30 minutes to form a wet body sample; then dry it at 100°C for 4 hours to obtain the ammonia storage activity containing 11wt% clay. Mixture of porous solid samples.
[0021] Fill the 10g porous solid sample block with ammonia in a naturally ventilated environment. Put the openable airtight container in a water tank with enough cooling water in advance, connect the ammonia cylinder, and pass through the pressure reducing valve and the drying system. , fill ammonia slowly within the pressure range of 0.4Mpa, the ammonia filling time is 5h; after ammonia filling, the mass of the sample block is 14g, that is, 4g of ammonia gas is adsorbed. Then the sample...
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