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A metal surface silane treatment agent containing diethanolamine and preparation method thereof

A technology of silane treatment agent and diethanolamine, which is applied in the coating process of metal materials, can solve the problems of weak metal support, low energy consumption in the production process, uneven density, etc., and achieve improved film quality and high density. The effect of small polarizing current density

Active Publication Date: 2016-03-02
ANHUI LIUFANG ZHONGLIAN MECHANICAL SHARE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the field of metal surface treatment, although traditional phosphate conversion and chromate passivation surface treatment technologies can achieve good results, the waste liquid discharged during the treatment process contains heavy metal ions such as zinc, manganese, nickel, chromium and nitrous acid. Carcinogens such as salt are very serious to environmental pollution, and metal surface silanization treatment technology is considered to be expected to replace phosphate conversion treatment and chromate passivation treatment because it does not involve substances that are harmful to the environment, the production process has low energy consumption, and the technology has a wide range of applications. Chemical treatment is the latest development direction of metal surface protection alone. In the existing technology, the film formed on the surface of metal workpieces treated with silane solution has uneven density, holes, cracks, and weak adhesion to the metal body.

Method used

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Embodiment 1

[0021] A metal surface silane treatment agent containing diethanolamine is a mixed solution prepared from the following components, and the parts by weight (grams) of each component in each liter of the mixed solution are:

[0022] 1,2-bis(triethoxysilyl)ethane 35, γ-aminopropyltriethoxysilane 40, water-based nano zinc oxide material 160, propenyl alcohol 3, ethylene glycol 2, sodium tripolyphosphate 3 , propylene glycol 4, zirconium tetrafluoride 3, diethanolamine 3, ammonium chloride 3, diethylene glycol butyl ether 2, trimethylolpropane 2, sodium dodecylbenzenesulfonate 0.5, and the rest is water;

[0023] The preparation method of described aqueous nano zinc oxide material is:

[0024] (1) Ultrasonic disperse nano-zinc oxide in absolute ethanol 5 times its mass to obtain a dispersion, and then add 4% of its mass of dicumyl peroxide and 2% of anilinomethyltriethoxysilane In the above dispersion liquid, reflux reaction at 90°C for 2 hours, after the reaction, a nano-zinc ox...

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Abstract

The invention discloses a metal surface silicane treating agent containing diethanol amine. The metal surface silicane treating agent containing the diethanol amine is characterized by being a mixed solution which is prepared from following compositions of, by weight part ratio in every liter of the mixed solution, 28-35 parts of 1,2-bis (triethoxy silicon) ethane, 32-40 parts of gamma-aminopropyl triethoxy silicane, 100-160 parts of aqueous nanometer zinc oxide material, 2-3 parts of allyl alcohol, 1-2 parts of ethylene glycol, 2-3 parts of sodium tripolyphosphate, 2-4 parts of propylene glycol, 2-3 parts of zirconium tetrafluoride, 2-3 parts of diethanol amine, 2-3 parts of ammonium chloride, 1-2 parts of diethylene glycol monobutyl ether, 1-2 parts of trimethylolpropane, 0.3-0.5 part of sodium dodecyl benzene sulfonate, and the balance water. The metal surface silicane treating agent containing the diethanol amine has the advantages that, a silicane coating formed on the surface of metal after the metal is processed by using the surface silicane treating agent has good decay resistance, service life of the metal is prolonged, and a compact and firm coating is formed on the surface of the metal by combining the 1,2-bis (triethoxy silicon) ethane and the gamma-aminopropyl triethoxy silicane for use.

Description

technical field [0001] The invention mainly relates to a metal surface silane treatment agent and a preparation method thereof, in particular to a metal surface silane treatment agent containing diethanolamine and a preparation method thereof. Background technique [0002] In the field of metal surface treatment, although traditional phosphate conversion and chromate passivation surface treatment technologies can achieve good results, the waste liquid discharged during the treatment process contains heavy metal ions such as zinc, manganese, nickel, chromium and nitrous acid. Carcinogens such as salt are very serious to environmental pollution, and metal surface silanization treatment technology is considered to be expected to replace phosphate conversion treatment and chromate passivation treatment because it does not involve substances that are harmful to the environment, the production process has low energy consumption, and the technology has a wide range of applications. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C22/36
Inventor 王立新
Owner ANHUI LIUFANG ZHONGLIAN MECHANICAL SHARE
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