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Low-ash coal-based activated carbon quick activation production technology

A production process and activated carbon technology, which is applied in the field of rapid activation production process of low-ash coal activated carbon, can solve problems such as affecting the quality of product activated carbon, difficult activation, and increased ash content.

Inactive Publication Date: 2013-06-26
NINGXIA UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As a raw material for high-quality activated carbon production, Ningxia Taixi anthracite has an ash content of only about 8.54%. It is popular because of its low ash, well-developed micropores, large specific surface area, and high strength. However, activation of Taixi anthracite is difficult. A big problem in production, the traditional solution is to add a certain proportion of bituminous coal to Taixi anthracite to improve the activation efficiency, but the ash content of the product will increase after adding bituminous coal, which will affect the quality of the final product activated carbon

Method used

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  • Low-ash coal-based activated carbon quick activation production technology
  • Low-ash coal-based activated carbon quick activation production technology
  • Low-ash coal-based activated carbon quick activation production technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Such as figure 1 As shown, its technological process is:

[0018] 1) Pulverization: Pulverize the cleaned Taixi coal to coal powder of less than 200 mesh, and then add industrial NaOH and Ca(NO 3 ) 2 , after mixing evenly, add coal tar and knead, press into shape, dry, and enter the carbonization furnace for carbonization;

[0019] 2) Kneading and carbonization: the above-mentioned uniformly mixed coal powder is kneaded with coal tar according to the existing process, pressed into shape, dried, and then enters the carbonization furnace for carbonization;

[0020] 3) Water washing, pickling, activation: Soak the carbonized material in hot water at 60°C, wash for 60 minutes to remove floating ash, then soak in dilute hydrochloric acid with a mass fraction of 5% for 80 minutes, wash with water and take out the activated carbon , drying, and activation are finished products.

[0021] In the carbonization process of the above-mentioned embodiment, the ash mainly composed...

Embodiment 1—7

[0035] On the basis of above-mentioned embodiment 1, change following condition:

[0036]

[0037] In the above examples, the alkaline substances are NaOH, KOH, Ca(OH) 2 , Mg(OH) 2 、Na 2 CO 3 One or a mixture of two or more in any proportion, the nitrate is Ca (NO 3 ) 2 、KNO 3 、NaNO 3 , Fe (NO 3 ) 3 , NH 4 NO 3 One or a mixture of two or more in any proportion, the above-mentioned alkaline substances and nitrates are of industrial purity.

[0038] The technical indicators of CTC-60 are:

[0039]

[0040] The technical index of CTC-70 is very close to the technical index of CTC-60 mentioned above. As can be seen from the foregoing examples, compared with the prior art, the technical solution of the present invention has improved carbon tetrachloride adsorption rate (CTC), iodine adsorption value, and methylene blue adsorption value, and the ash content has decreased by about 2- About 4 percentage points, the activation time, activation energy consumption and ...

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Abstract

The invention relates to an active carbon production technology, and in particular relates to a low-ash coal-based activated carbon quick activation production technology which comprises the following steps of grinding, kneading, carbonizing, washing, acid washing and activation to obtain a finished product. Through the technology improvement, the activation time, the activation energy consumption and the ablation of carbonized material can be reduced by about 10%; meanwhile, the ash content of the finished product of active carbon can be reduced by 2-4%, and the carbon tetrachloride adsorption rate (CTC), the iodine adsorption value and the methylene blue adsorption value are increased; for an active carbon production enterprise, by only adding a trace amount of alkaline substance and nitrate, the cost per ton is only increased by *-* yuan, the energy use and product quality can be effectively reduced, and the energy saving and emission reducing effect is obvious; and the cost per ton can be reduced by about ** yuan, and the production cost can be reduced by *** thousand yuan per year for an active carbon enterprise with annual output of 10 thousand tons.

Description

technical field [0001] The invention relates to a production process of activated carbon, in particular to a rapid activation production process of low-ash coal-based activated carbon. Background technique [0002] Activated carbon is a very versatile adsorbent, catalyst and catalyst support. At present, some coal-based activated carbons with high requirements, such as activated carbon used for water purification and activated carbon used as quasi-carbon molecular sieves, must be produced using low-ash anthracite as raw material to reduce heavy metals and ash in the product. The existing activated carbon production process is: raw material washing, drying, pulverization, coal tar kneading, drying, carbonization, activation. In the activation stage, the ablation degree of the carbonized material gradually increases with the prolongation of the activation time. Due to the low reactivity of low-ash anthracite, it will take a long time for the activation of the activated carbon...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/08C01B32/33C01B32/348
Inventor 胡奇林杨旭洲齐志丽
Owner NINGXIA UNIVERSITY
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