Sensing material for concentration and temperature
A technology for sensing materials and concentration, applied in the field of concentration and temperature sensing materials, to achieve the effect of stable reproduction of spectral performance and not easy to quench fluorescence
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[0038] Preparation of temperature and concentration sensing materials:
[0039] Step 1: Rare earth precursor: Europium hexafluoroacetylacetonate Eu(hfac) hydrate 3 (H 2 O) 2Preparation: Add 3.3 times the molar equivalent of rare earth acetate hexafluoroacetylacetone (Hhfac) dropwise to the rare earth acetate aqueous solution with pH=6±0.5, stir at room temperature until a large amount of white precipitate precipitates, and wash the precipitate with a large amount of water After drying in vacuum, Eu(hfac) 3 (H 2 O) 2 ;
[0040] Step 2: Synthesis of L2: 9,10-Diphenylphosphineanthracene oxide (PAnPO 2 ) synthesis: Add 2 times 9,10-dibromoanthracene molar equivalent of n-butyllithium to the ether suspension containing 9,10-dibromoanthracene, stir the mixed solution for several minutes and add 2 times 9,10 -Diphenylphosphine chloride (PPh 2 Cl), the mixed solution continued to stir for 12 hours, a large amount of precipitation appeared, filtered, collected the solid, and wa...
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