A kind of low-temperature instant imidazoline quaternary ammonium salt cationic soft tablet and preparation method thereof

A quaternary ammonium salt cation and imidazoline-soluble technology, which is applied in textiles and papermaking, fiber treatment, plant fiber, etc., can solve the problems of low foam and good biodegradability, and achieve low foam, good biodegradability and low production cost. low effect

Active Publication Date: 2016-05-18
JIANGSU NEW REBA TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there is no low-temperature instant imidazoline quaternary ammonium salt cationic soft sheet that can be quickly dissolved in 40°C water, reduce the time of materialization, save energy, have low foam, and good biodegradability. It is suitable for soft finishing of cotton fibers and their blended fabrics. and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The raw material of the low-temperature instant imidazoline quaternary ammonium salt cationic soft sheet in the present embodiment comprises the stearic acid that parts by weight are 70 parts, the hydroxyethylethylenediamine that parts by weight are 10 parts, the Diethylenetriamine, parts by weight are 4 parts of triethylenetetramine, parts by weight are 4.5 parts of quaternizing agent, parts by weight are 2 parts of emulsifier, parts by weight are 3 parts of glacial acetic acid and weight The number of parts is 0.5 parts of the defoaming agent, wherein the stearic acid is stearic acid 1801, the emulsifier is Pingpinga O-25, the quaternizing agent is diethyl sulfate, hydroxyethyl ethylenediamine, diethylene triethylene Both the purity of amine and triethylenetetramine are above 99.0%.

[0027] The preparation method of the low-temperature instant imidazoline quaternary ammonium salt cationic soft tablet in this embodiment includes the following steps in sequence.

[00...

Embodiment 2

[0036] The raw material of the low-temperature instant imidazoline quaternary ammonium salt cationic soft sheet in the present embodiment comprises the stearic acid that parts by weight are 70 parts, the hydroxyethylethylenediamine that parts by weight are 9.5 parts, the hydroxyethyl ethylenediamine that parts by weight are 6.5 parts Diethylenetriamine, parts by weight are 4 parts of triethylenetetramine, parts by weight are 4.5 parts of quaternizing agent, parts by weight are 2 parts of emulsifier, parts by weight are 3 parts of glacial acetic acid and weight The number of parts is 0.5 parts of defoaming agent as raw material; wherein, stearic acid is stearic acid 1801, emulsifier is Pingping plus O-25, quaternizing agent is diethyl sulfate, hydroxyethylethylenediamine, di Both the purity of ethylene triamine and triethylene tetramine are above 99.0%.

[0037] The preparation method of the low-temperature instant imidazoline quaternary ammonium salt cationic soft tablet in th...

Embodiment 3

[0045] The raw material of the low-temperature instant imidazoline quaternary ammonium salt cationic soft sheet in the present embodiment comprises the stearic acid that is 70.5 parts by weight, the hydroxyethylethylenediamine that is 7.5 parts by weight, the hydroxyethylethylenediamine that is 6.5 parts by weight Diethylenetriamine, parts by weight are 4.5 parts of triethylenetetramine, 4 parts by weight of quaternizing agent, 2.5 parts of emulsifier, 3 parts of glacial acetic acid and weight The number of parts is 0.5 parts of defoaming agent as raw material; wherein, stearic acid is stearic acid 1801, emulsifier is Pingping plus O-25, quaternizing agent is diethyl sulfate, hydroxyethylethylenediamine, di Both the purity of ethylene triamine and triethylene tetramine are above 99.0%.

[0046] The preparation method of the low-temperature instant imidazoline quaternary ammonium salt cationic soft tablet in this embodiment includes the following steps in sequence.

[0047] (1...

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PUM

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Abstract

The invention relates to a low-temperature instant imidazoline quaternary ammonium salt cation flexible sheet and a preparation method thereof. At present, the low-temperature instant imidazoline quaternary ammonium salt cation flexible sheet fast dissolved in water having a temperature of 40 DEG C is a creative product. The low-temperature instant imidazoline quaternary ammonium salt cation flexible sheet comprises, by weight, 67 to 72 parts of stearic acid, 7 to 10 parts of hydroxyethyl ethylenediamine, 6 to 9 parts of diethylenetriamine, 4 to 7 parts of triethylene tetramine, 4 to 5 parts of a quaternization agent, 2 to 3 parts of an emulsifier, 3 to 4 parts of glacial acetic acid and 0.5 to 0.6 parts of a defoaming agent. The preparation method comprises the following steps of weighing the raw materials, heating a reaction bottle to a temperature of 80 to 85 DEG C, putting stearic acid into the reaction bottle, putting hydroxyethyl ethylenediamine, diethylenetriamine and triethylene tetramine into the reaction bottle to obtain alkyl amidoimidazoline, dropwisely adding the quaternization agent into alkyl amidoimidazoline to obtain a quaternary ammonium salt of alkyl amidoimidazoline, putting the emulsifier, glacial acetic acid and the defoaming agent into the quaternary ammonium salt of alkyl amidoimidazoline, and carrying out slicing to obtain a finished product. The low-temperature instant imidazoline quaternary ammonium salt cation flexible sheet provided by the invention can be fast dissolved in water having a temperature of 40 DEG C.

Description

technical field [0001] The invention relates to a low-temperature instant imidazoline quaternary ammonium salt cationic softening sheet and a preparation method thereof. The cationic softening sheet is mainly used as a softening agent for printing and dyeing processing to soften fibers and fabrics. Background technique [0002] Cotton and its blended fabrics are rough after scouring, bleaching and dyeing. They must be softened to meet customer requirements. Now cationic soft sheets are widely used, but these soft sheets must be at 60-80 It can only be dissolved in hot water at ℃, the chemical time is long, there are many foams, waste of energy, and the degree of yellowing is high, the softness and smoothness are not ideal, and the biodegradability is poor. Most of them use dimethyl sulfate as a quaternizing agent, which is toxic and not environmentally friendly. Strict labor protection measures must be taken during use to prevent leakage. [0003] There are also some cation...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M13/473C07D233/16C07D233/14D06M101/06
Inventor 于顺平陈小利邢志奇
Owner JIANGSU NEW REBA TECH CO LTD
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