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A nanocrystalline composite rare earth permanent magnet material and its surface treatment method

A nanocrystalline composite, rare earth permanent magnet technology, applied in the direction of magnetic materials, magnetic objects, electrical components, etc., can solve the problems of easy oxidation and corrosion, magnetic performance degradation, component pollution, etc. Low cost and the effect of improving corrosion resistance

Active Publication Date: 2015-10-14
南通万宝磁石制造有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since rare-earth metal-based permanent magnets contain highly reactive rare-earth metals, namely: R, they are prone to oxidation and corrosion in the atmospheric environment, and when the permanent magnets are used without any surface treatment, they are prone to oxidation and corrosion in the presence of a small amount of acid Or alkaline substances or water conditions corrosion tends to start from the surface, resulting in rust, which causes a drop and fluctuation in magnetic properties
Also, when such rusty magnets are embedded in magnetic circuits and similar devices, the rust can spread around and contaminate surrounding components

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A nanocrystalline composite rare earth permanent magnet material and a method for surface treatment thereof, comprising the following steps:

[0031] (1) Preparation of nanocrystalline composite rare earth permanent magnet materials

[0032] The composition range of the nanocrystalline composite rare earth permanent magnet material is Nd 4.5 Tb 0.3 Fe 76.2 B 19, the preparation method is that the rare earth element Nd and Tb, pure iron and boron iron are mixed into the alloy of the above composition, all rare earth elements are added according to the burning loss rate of 3%, and then put into a vacuum melting furnace for melting and rapid quenching , smelting and quenching to obtain the nanocrystalline composite rare earth permanent magnet material, and then heat-treating it. The heat treatment system is to raise the temperature of the nanocrystalline composite rare earth permanent magnet material to 605°C at a heating rate of 200°C / min, and then increase the tempera...

Embodiment 2

[0049] A method for surface treatment of rare earth permanent magnetic materials, comprising the following steps: (1) preparation of nanocrystalline composite rare earth permanent magnetic materials The composition range of the nanocrystalline composite rare earth permanent magnetic materials is Nd 3.9 SM 0.6 Fe 78 B 17.5 , and its preparation method is that the rare earth element Nd and Sm, pure iron and boron iron are mixed into an alloy with the above composition, and all rare earth elements are added according to the burning loss rate of 3%, and then put into a vacuum melting furnace for melting and rapid quenching , smelting and quenching to obtain the nanocrystalline composite rare earth permanent magnet material, and then heat-treating it. The heat treatment system is to heat the nanocrystalline composite rare earth permanent magnet material at a heating rate of 220°C / min to 610°C, and then heat it up at a rate of 18°C / min. Raise the temperature to 685°C, keep it warm...

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Abstract

The invention relates to a nanocrystalline composite rare earth permanent magnet material and a surface treatment method thereof. The surface treatment method of the nanocrystalline composite rare earth permanent magnet material comprises the steps of (1) preparation of the nanocrystalline composite rare earth permanent magnet material, (2) surface cleaning, (3) shot blasting, (4) activating treatment, (5) surface coating, (6) secondary coating, (7) passivating treatment, and (8) aging treatment. According to the nanocrystalline composite rare earth permanent magnet material, the coercive force and the maximum magnetic energy product of the nanocrystalline composite rare earth permanent magnet material are improved obviously, a more reasonable microstructure can be obtained with the heating processing technique, and the performance is improved due to the reasonable microstructure. According to the surface treatment method of the nanocrystalline composite rare earth permanent magnet material, due to the fact that the surface of a base body is coated with a uniform and compact clad layer free of holes step by step in a layering mode from inside to outside, the base body is blocked, then the passivation and aging are carried out to enable the clad layer and the base body to be combined more tightly, the clad layer can be more compact, and then the base body can be better protected by the clad layer.

Description

technical field [0001] The invention relates to a nanocrystalline composite rare earth permanent magnet material and a surface treatment method thereof. Background technique [0002] Rare earth metal-based permanent magnets, such as R-Fe-B-based permanent magnets represented by Nd-Fe-B-based permanent magnets, or R-Fe-N-based permanent magnets represented by Sm-Fe-N-based permanent magnets Magnets and the like utilize inexpensive materials that are abundant in resources and have excellent magnetic properties, and especially for the above-mentioned two types of permanent magnets, R-Fe-B-based permanent magnets are used in various fields today. However, since the rare earth metal-based permanent magnets contain highly reactive rare earth metals, namely: R, they are prone to oxidation and corrosion in the atmospheric environment, and when the permanent magnets are used without any surface treatment, in the presence of a small amount of acid Or alkaline substances or water cond...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/057C22C1/04C22F1/00C23F17/00
Inventor 周连明曹阳
Owner 南通万宝磁石制造有限公司
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