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Comprehensive treatment method of tail gas in mercury chloride production process

A production process and comprehensive treatment technology, applied in chemical instruments and methods, separation methods, hypochlorous acid, etc., can solve problems such as environmental hazards, and achieve the effects of reducing pollution, reducing mercury chloride content, and increasing economic benefits

Active Publication Date: 2014-02-05
贵州重力科技环保股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

serious harm to the environment

Method used

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  • Comprehensive treatment method of tail gas in mercury chloride production process

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] During the production of mercuric chloride, 7.2×10 7 m 3 Exhaust gas, in which the mercury chloride content is 0.00986g / m3 3 , the chlorine content is 0.83g / m 3 , the tail gas was passed into the sedimentation buffer tank, and 709.29kg of mercuric chloride was recovered after natural sedimentation. At this time, the content of mercuric chloride in the tail gas was 9.9×10 -6 g / m 3 Then the tail gas after the sedimentation is passed into the hydrochloric acid absorption tower to absorb the remaining mercuric chloride in the tail gas, and then the hydrochloric acid solution that is dissolved with mercuric chloride is pumped into the catalyst soaking tank of the mercuric chloride catalyst workshop, as the dissolving mother liquor of the catalyzer Recycling; the tail gas absorbed by hydrochloric acid is passed into the acid mist collection tower, and the hydrochloric acid acid mist mixed in the tail gas is collected to form acid droplets and then flow into the absorption ...

Embodiment 2

[0030] During the production of mercuric chloride, 2.592×10 7 m 3 Exhaust gas, in which mercury chloride content is 1×10 -5 g / m 3 , the chlorine content is 0.05g / m 3 , the tail gas was passed into the sedimentation buffer tank, and 259kg of mercuric chloride was recovered after natural sedimentation. At this time, the content of mercuric chloride in the tail gas was 7.716×10 -6 g / m 3 Then the tail gas after the sedimentation is passed into the hydrochloric acid absorption tower to absorb the remaining mercuric chloride in the tail gas, and then the hydrochloric acid solution that is dissolved with mercuric chloride is pumped into the catalyst soaking tank of the mercuric chloride catalyst workshop, as the dissolving mother liquor of the catalyzer Recycling; the tail gas absorbed by hydrochloric acid is passed into the acid mist collection tower, and the hydrochloric acid acid mist mixed in the tail gas is collected to form acid droplets and then flow into the absorption to...

Embodiment 3

[0032] During the production of mercuric chloride, 5.9×10 7 m 3 Exhaust gas, in which the mercury chloride content is 0.00486g / m3 3 , the chlorine content is 0.53g / m 3 , the tail gas was passed into the sedimentation buffer tank, and 285.3063kg of mercuric chloride was recovered after natural sedimentation. At this time, the content of mercuric chloride in the tail gas was 2.43×10-6 g / m 3 Then the tail gas after the sedimentation is passed into the hydrochloric acid absorption tower to absorb the remaining mercuric chloride in the tail gas, and then the hydrochloric acid solution that is dissolved with mercuric chloride is pumped into the catalyst soaking tank of the mercuric chloride catalyst workshop, as the dissolving mother liquor of the catalyzer Recycling; the tail gas absorbed by hydrochloric acid is passed into the acid mist collection tower, and the hydrochloric acid acid mist mixed in the tail gas is collected to form acid droplets and then flow into the absorption...

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Abstract

The invention relates to a comprehensive treatment method of a tail gas in a mercury chloride production process. The comprehensive treatment method comprises the following steps of ventilating the tail gas into a settling buffer slot to carry out natural settling, and recycling settled substances as products; ventilating the settled tail gas into a hydrochloric acid absorbing tower, absorbing the residual mercury chloride in the tail gas, and recycling hydrochloric acid liquor dissolved with the mercury chloride as dissolving mother liquor of a catalytic agent; ventilating the tail gas absorbed by the hydrochloric acid into an acid mist trapping tower, concentrating and naturally flowing the formed acid drops into a hydrochloric acid absorbing tower for recycling; pumping the trapped tail gas into alkaline liquor absorbing slot for reaction by a jet pump to obtain a byproduct sodium hypochlorite, and externally exhausting the residual tail gas after the tail gas is detected to reach standards. The comprehensive treatment method disclosed by the invention not only removes mercury chloride and chlorine gas in the tail gas, but also can comprehensively utilize a downstream absorption liquid to obtain the byproduct sodium hypochlorite, thereby increasing economic benefits; and meanwhile, the comprehensive treatment method is green and environment-friendly, capable of reducing pollution of the mercury chloride and the chlorine gas to environment.

Description

technical field [0001] The invention relates to a comprehensive treatment method for tail gas in the production process of mercuric chloride, belonging to the field of mercuric chloride production. Background technique [0002] 60% of mercury in my country is mainly used in calcium carbide polyvinyl chloride industry. Mercury chloride (Mercuric chloride), commonly known as mercuric chloride, is mainly used by the reaction of mercury and chlorine gas. Mercury chloride is obtained by burning metal mercury in chlorine gas to generate mercuric chloride vapor, which is naturally crystallized after cooling. [0003] Principle: Hg+Cl 2 =HgCl 2 [0004] Put metallic mercury (purity ≥ 99.99%) in a high-level metering tank, adjust its flow rate, naturally flow into the preheated quartz combustion furnace, and burn in contact with high-temperature chlorine gas (excessive, to ensure that the metallic mercury reacts completely), the reaction temperature Controlled between 460 ~ 600 ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D45/02B01D47/14B01D53/78B01D53/68C01B11/06
CPCY02P20/584
Inventor 王良栋
Owner 贵州重力科技环保股份有限公司