Supermolecular composite retardance acidifying agent for carbonate reservoir and preparation method thereof

A technology of composite acidifying agent and supramolecular polymer, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of fast acid-rock reaction speed, inability to eliminate clogging, low permeability, and consumption of far-well reservoirs

Inactive Publication Date: 2014-03-12
JILIN INST OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] A mixture of hydrochloric acid and hydrofluoric acid (earth acid) system is often used in conventional oilfield acidizing construction. The problem is that the acid-rock reaction speed is fast, and most of the acid liquid is consumed in the near-well zone of the reservoir, which cannot eliminate Blockage and hypotonic problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] Weigh 4g of maleic anhydride, put it into a beaker, add 10g of water to dissolve and prepare an acid solution, then weigh 10g of acrylamide with cyclodextrin side groups, put it into a beaker, add 200g of water to dissolve and prepare a polymer solution, and then The above two solutions were poured into a 500mL Erlenmeyer flask, placed in an ultrasonic cleaner and vibrated at room temperature for 20 minutes to obtain a supramolecular composite acidifier.

Embodiment 2

[0013] Take 2g of the Cambrian micritic limestone in the tower and grind it to 40-80 mesh, put it into the 100mL solution prepared in Example 1 for testing, the experimental results show that it takes 8.2 hours for the complete reaction to complete.

Embodiment 3

[0015] Take 2g of the Cambrian micritic limestone in the tower and grind it to 40-80 mesh, put it into a 1% by mass hydrochloric acid solution for testing, the experimental results show that it only takes 5 minutes for the complete reaction to complete.

[0016] It can be seen from the above examples that the supramolecular composite acidifier has a good retarding effect.

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PUM

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Abstract

The invention relates to a supermolecular composite retardance acidifying agent for increasing the recovery ratio of crude oil in a carbonate reservoir in the oil and gas exploitation process and a preparation method thereof. The supermolecular composite retardance acidifying agent aims at the purpose of deep acidification through the slow reaction of the carbonate reservoir. According to the technical scheme, the supermolecular composite retardance acidifying agent is formed by maleic anhydride and a supermolecular polymer, wherein the supermolecular polymer is acrylamide with a cyclodextrin lateral group, and the mass ratio of the maleic anhydride to the supermolecular polymer is 0.4: 1. The preparation method comprises the following steps: firstly weighting and putting 4g of maleic anhydride in a beaker, adding 10g of water so as to dissolve the maleic anhydride, thus obtaining a maleic anhydride solution, then weighting and putting 10g of acrylamide with the cyclodextrin lateral group in a beaker, adding 200g of water so as to dissolve the acrylamide with the cyclodextrin lateral group, thus obtaining a solution of the acrylamide with the cyclodextrin lateral group, pouring the two solutions into a 500mL-concial flask, putting the conical flask in a supersonic cleaner, and vibrating for 20 minutes at a room temperature, thus finally obtaining the supermolecular composite acidifying agent. The preparation method of the composite acidifying agent is simple, convenient and mild in conditions, has relatively good retardance acidifying effect and is used in the carbonate reservoir so as to increase the recovery ratio.

Description

technical field [0001] The invention relates to a supramolecular composite retarded acidifier used for improving the recovery rate of crude oil in carbonate rock reservoirs in the process of oil and gas exploitation and a preparation method thereof. Background technique [0002] A mixture of hydrochloric acid and hydrofluoric acid (earth acid) system is often used in conventional oilfield acidizing construction. The problem is that the acid-rock reaction speed is fast, and most of the acid liquid is consumed in the near-well zone of the reservoir, which cannot eliminate Blockage and hypotonic problems. Therefore, the application of retarded acid for deep formation acidification to improve the effect of acid treatment is gradually rising. Contents of the invention [0003] The purpose of the present invention is to improve the plugging effect of acid rock reaction in the acidification operation of crude oil recovery in carbonate rock reservoirs, realize the synergistic eff...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/74
CPCC09K8/725C09K8/74
Inventor 谭乃迪金玉子陈哲邹长军
Owner JILIN INST OF CHEM TECH
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