Ultraviolet response type rare earth light conversion film and application thereof
A light conversion film, rare earth technology, applied in luminescent materials, chemical instruments and methods, radiation control devices, etc., can solve the problems of difficult disassembly and maintenance, hindering popular application, high price, etc., and achieves simplified operation, wide application range, and reduced The effect of instrument cost
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Embodiment 1
[0058] A method for preparing an ultraviolet-responsive rare earth photoconversion film device, the steps are as follows:
[0059] 1. Preparation of rare earth complexes: mix TbCl with a ratio of 1:3 3 Mix with 5-sulfosalicylic acid (Ssal), then add a mixture of dimethyl sulfoxide and water (volume ratio 1:10), mix well, add KOH aqueous solution dropwise under stirring until pH=5~8 . The solution is heated in a water bath at 60-80° C., and the solvent is evaporated to obtain a Tb-Ssal complex fluorescent material.
[0060] 2. Preparation of UV-responsive rare earth light conversion film device:
[0061] (1) Dissolve the Tb-Ssal complex in water to make a solution with a concentration of 20%, add an equal volume of polyvinyl alcohol (PVA) aqueous solution with a concentration of 1%, mix well, and then add 2mL of this mixture dropwise Spin coating on a quartz plate to form a film, the spin coating speed is 700-1000 rpm, and the spin coating time is 40-60 seconds. Then place ...
Embodiment 2
[0064] Application of UV Responsive Rare Earth Light Conversion Film:
[0065] 1. Installation of light conversion film devices
[0066] Disassemble a Canon digital camera (model: 500D), take out the CMOS, stick the light conversion film device on the CMOS surface and fix its position so that the light conversion film completely covers the CMOS surface. The installation position of the light conversion film device in the camera is as follows: Figure 4 shown. Install the CMOS with the light conversion film device installed back into the camera.
[0067] 2. The use of UV imaging system and fingerprint shooting
[0068] Irradiate the substrate printed with fingerprints with an LED ultraviolet lamp with a wavelength of 365nm, aim the Canon 500D digital camera installed with a light conversion film device and a 365nm ultraviolet filter at the fingerprints printed on the surface of the substrate, and adjust the focal length to make the fingerprint image clear , press the shutte...
Embodiment 3
[0070] A method for preparing an ultraviolet-responsive rare earth photoconversion film device, the steps are as follows:
[0071] 1. Preparation of rare earth complexes: mix TbCl with a ratio of 1:0.2:1.2 3 , GdCl 3 Mix with 5-sulfosalicylic acid (Ssal), then add a mixture of N,N-dimethylformamide and water (volume ratio 1:10), mix well, add KOH aqueous solution dropwise under stirring to pH =5~8. The solution is heated in a water bath at 60-80° C., and the solvent is evaporated to obtain a Tb-Gd-Ssal complex fluorescent material.
[0072] 2. Preparation of UV-responsive rare earth light conversion film device:
[0073] (1) Preparation of Tb-Gd-Ssal light conversion film
[0074] Dissolve the Tb-Gd-Ssal complex in water to make a solution with a concentration of 30%, then add 2mL of this solution dropwise onto a quartz plate, spin-coat to form a film, the spin-coating rate is 700-1000rpm, and the spin-coating time is 40 ~60 seconds. Then place the quartz sheet in an ove...
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