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Combined ore pulp pH (power of hydrogen) regulator for phosphorite flotation technology

A technology of adjusting agent and process mine, which is applied in flotation, solid separation, etc., and can solve the problems that sodium carbonate has a small buffer range for the pH value of ore pulp, affects the collection capacity and selectivity of collectors, and the flotation process is not smooth, etc. , achieve good bubble mineralization effect, smooth flotation process, improve collection capacity and selectivity

Inactive Publication Date: 2014-05-28
WUHAN INSTITUTE OF TECHNOLOGY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, in the prior art, sodium carbonate is used as a pH regulator for flotation pulp, and there are still the following problems: (1) the amount of sodium carbonate is large, which makes the cost of mineral processing high; (2) the buffer range of sodium carbonate to the pH value of the pulp is small; (3) ) When the amount of sodium carbonate is high, the foam will be dense and sticky, and the foam transportation will be difficult, making the flotation process unsmooth. When the amount of sodium carbonate is insufficient, the collection capacity and selectivity of the collector will be affected.

Method used

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  • Combined ore pulp pH (power of hydrogen) regulator for phosphorite flotation technology
  • Combined ore pulp pH (power of hydrogen) regulator for phosphorite flotation technology
  • Combined ore pulp pH (power of hydrogen) regulator for phosphorite flotation technology

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Embodiment 1

[0022] The raw ore selected in this embodiment is Fangmashan phosphate rock in Hubei. The main useful minerals of the ore are collophoste, followed by fine-crystalline apatite. The gangue minerals are dolomite, chalcedony, quartz and a small amount of calcite, limonite, Pyrite, clay, etc. P in raw ore sample 2 o 5 The raw ore is crushed to -12mm by a crusher, and then ground by a grinder with a grinding fineness of -0.074mm93.38%, and then mixed with water to obtain a slurry with a concentration of 20-50wt%.

[0023] The above-mentioned ore pulp is subjected to a positive flotation roughing process, using water glass (sodium silicate) and sodium carboxymethyl starch (CM-1) as inhibitors, and fatty acid collector (TSM-46) as collector. The dosage of water glass is 3.0kg / t (raw ore), the dosage of carboxymethyl starch (CM-1) is 0.6kg / t (raw ore), and the dosage of collector TSM-46 is 0.6kg / t (raw ore) , the flotation process adds a mixture of sodium carbonate and sodium hydro...

Embodiment 2

[0032] The raw ore used in this example is Yunnan Huaning Phosphate Mine. Yunnan Huaning Phosphate Mine belongs to siliceous phosphorite, and the deposit type and rock combination are basically similar. The natural types of ores are mainly sandy phosphorites, phosphorous dolomite, banded and layered phosphorites, and the industrial types of ores are siliceous and silicate. The ore minerals are mainly collophosite, and the gangue minerals are mainly micrite dolomite, argillaceous dolomite, quartz, muscovite, sericite, calcite, chlorite, silica, etc. Collephantite: brown, sandy shape, round, nearly round, near round residual, particle size 0.05-0.10mm, evenly, semi-uniformly or semi-directionally densely distributed. Dolomite: mainly micrite dolomite and argillaceous dolomite, colorless, euhedral-semi-euhedral granular, particle size 0.01-0.05mm, content 15%. Quartz: colorless, angular-sub-angular-round distribution, mostly with a particle size of 0.05mm±, the content is genera...

Embodiment 3

[0040] The raw ore selected in this embodiment is a phosphate mineral in a phosphate rock in Sichuan. The vast majority of the minerals are collophanite and a small amount of micro-fine crystal apatite. Collephosite is mainly in the shape of aggregates and ovals, a small amount is irregular in shape, most of them are yellowish brown, and some are dark brown. The yellowish brown ones are mainly wrapped by limonite or carbonaceous film, and the dark brown ones are not covered by the above-mentioned film. , and often one or several micro-fine crystals (several to 20 μm) of pyrite are wrapped in it. Micro-fine-crystalline apatite particles can sometimes be seen around collophanite particles, sometimes 1-2 carbonate mineral micro-fine-crystalline inclusions can be seen in collophanite particles, and multiple inclusions can be seen in individual cases. Collophosite particles vary in size, mainly carbonate minerals with a particle size of 50-100 μm (the detailed classification of car...

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Abstract

The invention belongs to the technical field of phosphorite flotation, and particularly relates to a combined ore pulp pH (power of hydrogen) regulator for phosphorite flotation technology. The phosphorite flotation technology adopts obverse and reverse flotation or only obverse flotation, utilizes fatty acid or fatty acid soap as collectors and mixture of sodium carbonate and sodium hydroxide as the combined ore pulp pH regulator. The mass ratio of the sodium carbonate and the sodium hydroxide is 2:1 to 9:1, the usage of the combined pH regulator ranges from 3.0kg / t to 6.0kg / t (for raw ore), and the usage of the collector ranges from 0.4kg / t to 2.0kg / t (for raw ore). The combined pH regulator is wide in source and convenient to use, buffer range of the regulated pH value of the ore pulp is wide, and collecting capacity and selectivity of the collector can be effectively promoted, and recycling rate is high. Meanwhile, the combined pH regulator is low in usage and low in ore dressing cost.

Description

technical field [0001] The invention belongs to the technical field of phosphate rock beneficiation, and in particular relates to a combined pH regulator of pulp in the phosphate rock flotation process. Background technique [0002] Phosphate rock is an essential basic raw material for the production of phosphate fertilizers and phosphorus chemical products. my country's phosphate resource reserves are 16.786 billion tons, with an average grade of 16.95%. The high-grade ore that can be directly used can only be mined for more than ten years. Due to its poor dissociation and high gangue mineral content, its development and utilization is a worldwide problem. [0003] In the phosphate rock positive flotation process, sodium carbonate is generally added as the pH regulator of the flotation pulp, instead of using strong alkali (sodium hydroxide) as the pH regulator of the flotation pulp, mainly because sodium hydroxide is a strong Alkali modifier is also a pretreatment agent, w...

Claims

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Application Information

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IPC IPC(8): B03D1/002B03D1/02
Inventor 罗惠华汤家焰饶欢欢杨婕陈慧包梦池汝安李成秀陈炳炎
Owner WUHAN INSTITUTE OF TECHNOLOGY