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Rye straw adsorbing material and preparation method thereof

A technology for rye straw and adsorption material, which is applied in chemical instruments and methods, adsorption water/sewage treatment, other chemical processes, etc., can solve the problems of low utilization efficiency, environmental pollution, waste of resources, etc., and achieves simple manufacturing method, environmental protection Friendly, low-cost effects

Inactive Publication Date: 2014-09-10
吴涛
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] As a large agricultural country, our country has a large output of crop straw, but in terms of comprehensive utilization of straw, the utilization efficiency is still very low, and most of the straw is burned or discarded, which wastes resources and pollutes the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Choose mature and long rye straws, soak them in tap water and wash them to remove dirt and dust, then wash them with distilled water, and dry them to constant weight at 80°C; grind the dried rye straws into powder and choose to disperse Pass through a 60-mesh sieve and collect the powder; weigh 50g of the obtained powder and soak it in deionized water, add 2mL each of the activated 0.01mol / L amylase solution and protease solution, and react at 35-50℃ for 1 hour. Then add 10mL of 0.05mol / L KOH solution, react for 50 minutes, and then use H 2 SO 4 The solution is neutralized, the neutralized liquid is filtered, and then dried; the dried powder and urea are mixed uniformly at a mass ratio of 1:1, then re-soaked in deionized water, reacted at 50°C for 6 hours, filtered, After that, it was washed with deionized water three times to remove the remaining ionic liquid, and then washed with 95% alcohol for two times. After washing, it was placed in an electric heating constant tem...

Embodiment 2

[0022] Choose mature and long rye straws, soak them in tap water and wash them to remove dirt and dust, then wash them with distilled water, and dry them to constant weight at 80°C; grind the dried rye straws into powder and choose to disperse Pass through a 60-mesh sieve and collect the powder; weigh 50g of the obtained powder and soak in deionized water, add 2mL each of the activated 0.05mol / L amylase solution and protease solution, and react at 35-50℃ for 2 hours. Then add 10mL of 0.1mol / L KOH solution, react for 50 minutes, and then use H 2 SO 4 The solution is neutralized. Filter the neutralized liquid, and then dry; mix the dried powder and urea at a mass ratio of 1:1, then soak it in deionized water, react at 50℃ for 8 hours, filter, and then deionize Wash with water 3 times to remove the residual ionic liquid, and then wash with 95% alcohol 2 times. After washing, it is placed in an electric heating constant temperature drying oven at 50°C and dried to obtain the rye st...

Embodiment 3

[0024] Choose mature and long rye straws, soak them in tap water and wash them to remove dirt and dust, then wash them with distilled water, and dry them to constant weight at 80°C; grind the dried rye straws into powder and choose to disperse Go through a 60-mesh sieve and collect the powder; weigh 100kg of the obtained powder into a 3 ton sanitary storage tank, and pour an appropriate amount of deionized water into the tank, add 2mL each of the activated 0.05mol / L amylase solution and protease solution , React for 2 hours at 50℃, then add 5L of 0.1mol / L KOH solution, react for 1 hour, then use H 2 SO 4 The solution is neutralized, the neutralized liquid is filtered with a plate and frame compressor, and then dried; the dried powder and urea are mixed uniformly at a mass ratio of 1:1, and then refilled into a 3 tons sanitary tank, and injected with deionization Water, keep at 50℃ and react for 8 hours, filter, wash with deionized water 4 times to remove residual ionic liquid, a...

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PUM

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Abstract

The invention discloses a preparation method of a rye straw adsorbing material. The preparation method comprises the following steps: grinding rye straws into powder and sieving the powder; then soaking the powder in deionized water and carrying out enzymolysis with activated amylase and protease; then adding a KOH solution, reacting and then neutralizing the solution with a dilute H2SO4 solution; filtering and airing the solution, then mixing the aired powder with urea in a mass ratio of 1:1 uniformly, re-soaking the mixture in the deionized water and reacting for 5-10 hours; filtering and airing the solution, then washing the product with the deionized water or 95% of alcohol three-four times to remove the residual ionic liquid and drying the product after washing the product, thus obtaining the rye straw adsorbing material. The adsorbing material has the characteristics of good adsorption property, simple preparation method, wide material source, low cost and the like.

Description

Technical field [0001] The invention relates to a rye straw adsorption material, in particular to an adsorption material that can be used as an adsorption material for wastewater treatment and a preparation method. Background technique [0002] With the development of industrialization, industrial technology has brought many new products to our lives, but at the same time it has also caused a lot of pollution to the environment, especially heavy metal pollution. Heavy metal pollution is different from the pollution of other organic compounds. Many organic compounds can reduce or eliminate their harmfulness through physical, chemical or biological purification of nature itself. The source of heavy metal pollution can be difficult to degrade for decades or even a hundred years. Heavy metal pollution is mainly the pollution of water sources. After these polluted water sources enter the environment or ecosystem, they can be transferred, accumulated, and amplified through the food ch...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/24B01J20/30C02F1/28C02F1/62
Inventor 吴涛
Owner 吴涛