Pest control composition including novel iminopyridine derivative
A technology of iminopyridine and its derivatives, which is applied in the direction of drug combination, chemicals for biological control, biocides, etc., and can solve the problems of drug sensitivity, long-term efficacy and safety
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[0870] The present invention is specifically described below with reference to examples, but the present invention is not limited to the examples.
[0871] Synthetic Example P1: N-[1-((6-chloropyridin-3-yl)methyl)pyridin-2(1H)-ylidene]-2,2,2-trifluoroacetamide (compound P212)
[0872] (1) 25g (270mmol) of 2-aminopyridine was dissolved in 200ml of anhydrous dichloromethane, 41ml (30g, 300mmol) of triethylamine was added thereto and the mixture was cooled to 0°C. Thereto was added dropwise 38 ml (57 g, 270 mmol) of anhydrous trifluoroacetic acid over 15 minutes, and the resulting mixture was stirred at room temperature for 2 hours. After the reaction was completed, the reaction solution was poured into about 100 ml of ice water and the mixture was stirred for 10 minutes. The mixture was transferred to a separatory funnel for liquid separation, the organic layer was washed twice with 150 ml of water and twice with 150 ml of 1% aqueous HCl, dried over anhydrous magnesium sulfate ...
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[1154] [Formulation Example]
preparation Embodiment 1
[1155] Formulation Example 1 [wettable powder]
[1156]
[1157] The ingredients are homogeneously mixed and ground to obtain a wettable powder.
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