Application of 1,4-palladium porphyrin-butadiyne as microcontact printing ink
A technology of microcontact printing and porphyrin palladium, applied in 1 field, can solve the problems of inability to prepare surface patterns and limited materials for microcontact printing, and achieve the effects of low cost, easy operation and easy availability of raw materials
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0039] A kind of 1, the application of 4-porphyrin palladium-butadiyne as microcontact printing ink, comprises the following steps:
[0040] Step 1, first 80g polytetrafluoroethylene substrate is ultrasonically cleaned with 75% ethanol for 1 hour, taken out, dried under the condition of 0.2MPa vacuum degree at 80°C, soaking the polytetrafluoroethylene substrate in 1% vinyl tri( β-methoxyethoxy)silane solution for 30 hours, take it out, wash it with 75% ethanol solution, and dry it at 80°C at 0.1MPa; then put the polytetrafluoroethylene substrate into the container, add solution one, The first solution is a solution obtained by dissolving 1 g of methacrylic acid and 0.1 g of azobisisobutyronitrile in 500 ml of distilled water, and reacting at 80° C. for 3 hours to obtain a pretreated polytetrafluoroethylene substrate;
[0041] Step 2: Take 1-10g of 1,4-porphyrin palladium-butadiyne and dissolve it in 50-100ml of dichloromethane solution to obtain 1,4-porphyrin palladium-butadiy...
Embodiment 2
[0045] A kind of 1, the application of 4-porphyrin palladium-butadiyne as microcontact printing ink, comprises the following steps:
[0046] Step 1: Clean 100g of polyethylene terephthalate substrate with 75% ethanol ultrasonically for 1 hour, take it out, and dry it at 80°C under a vacuum of 0.1MPa, and then clean the polyethylene terephthalate substrate Soak in 1% vinyl tris (β-methoxyethoxy) silane solution for 24 hours, take it out, wash it with 75% ethanol solution, and dry it at 80°C under a vacuum of 0.1MPa; then polypylene Put the ethylene glycol diformate substrate into the container, add solution 1, the solution 1 is a solution prepared by dissolving 1.5g of methacrylic acid and 0.1g of azobisisobutyronitrile in 500ml of distilled water, and react at 80°C for 1 hour , to obtain a pretreated polyethylene terephthalate substrate;
[0047] Step 2, take 10g of 1,4-porphyrin palladium-butadiyne and dissolve it in 100ml of dichloromethane solution to obtain a 1,4-porphyri...
Embodiment 3
[0051] A kind of 1, the application of 4-porphyrin palladium-butadiyne as microcontact printing ink, comprises the following steps:
[0052] Step 1. First, ultrasonically clean 150g of polyimide substrate with 65% ethanol for 1.5 hours, take it out, and dry it at 100°C under a vacuum of 0.4MPa. Soak the polyimide substrate in 2% butadiene In the triethoxysilane solution for 30 hours, take it out, wash it with 65% ethanol solution, and dry it at 90°C under a vacuum of 0.1 MPa; then put the polyimide substrate into the container, add solution 1, and Solution 1 is a solution obtained by dissolving 2 g of methacrylic acid and 0.2 g of azobisisobutyronitrile in 600 ml of distilled water, and reacting at 90° C. for 2 hours to obtain a pretreated polyimide substrate;
[0053] Step 2, get 5g of 1,4-porphyrin palladium-butadiyne and dissolve it in 80ml dimethyl sulfoxide solution to obtain 1,4-porphyrin palladium-butadiyne dimethyl sulfoxide with a concentration of 5g / L Sulfone soluti...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More