Strong water-resistant white emulsion and preparation method thereof

A white latex and strong technology, applied in the field of white latex, can solve the problems of high toxicity of vinyl acetate, inability to meet strict requirements, and poor environmental protection performance, and achieve excellent curing time, meet strict requirements, and good environmental protection performance.

Inactive Publication Date: 2015-06-03
海安县紫石涂料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The vinyl acetate used in this glue is highly toxic and not environmentally friendly
[0007] Chinese invention patent application 201410004735.1 (public date: April 16, 2014) discloses a strong water-resistant white latex, the glue includes: polyvinyl alcohol PVA, vinyl acetate VAC, acrylic acid AA, acrylamide AM, persulfuric acid Ammonium, anionic emulsifier A-102, alkyl polyoxyethylene ether LCN-287 nonionic emulsifier; corn starch, transparent powder, plasticizer, diethylene glycol dibenzoate DEDB, preservative KSG-201, hydrogen Sodium oxide, and methanol; but this glue still uses toxic vinyl acetate, which has poor environmental performance
[0008] At the same time, the related glue disclosed in the prior art has poor comprehensive performance in terms of use effect and cannot meet the stringent demands of the market.

Method used

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  • Strong water-resistant white emulsion and preparation method thereof
  • Strong water-resistant white emulsion and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] This embodiment relates to a strong water-resistant white latex and its preparation method; the white latex consists of the following components in parts by weight:

[0040] Polyvinyl acetate 700,

[0041] Vinyl acetate 300,

[0042] polyvinyl alcohol 120,

[0043] Dibutyl phthalate 60,

[0044] Diethylene glycol dibenzoate 20,

[0045] Octanol 10,

[0046] Isopropanol 30,

[0047] Allyl methacrylate 10,

[0048] Ethylene glycol dimethacrylate 5,

[0049] Toluene diisocyanate 3,

[0050] Sodium bicarbonate 35,

[0051] water 1400,

[0052] Emulsifier 40, the emulsifier is sodium oleate (i.e. sodium octadecenoate);

[0053] Composite initiator 5,

[0054] Methylolacrylamide 20,

[0055] waxy cornstarch 10,

[0056] sodium hypochlorite 2,

[0057] The composite initiator is composed of the following components in weight ratio: potassium persulfate, ammonium persulfate, sodium bisulfite, sodium persulfate, and kaolin in a weight ratio of 3:1:2:1:1.

[0058] ...

Embodiment 2

[0065] This embodiment relates to a kind of white latex and preparation method thereof (preparation method is the same as embodiment 1); White latex is made up of each component of following parts by weight:

[0066] Polyvinyl acetate 1050,

[0067] Vinyl acetate 350,

[0068] polyvinyl alcohol 145,

[0069] Dibutyl phthalate 100,

[0070] Diethylene glycol dibenzoate 40,

[0071] Octanol 15,

[0072] Isopropanol 45,

[0073] Allyl methacrylate 25,

[0074] Ethylene glycol dimethacrylate 10,

[0075] Toluene diisocyanate 7,

[0076] Sodium bicarbonate 50,

[0077] water 1500,

[0078] Emulsifier 50, the emulsifier is sodium dodecylbenzenesulfonate;

[0079] Composite initiator 9,

[0080] Methylolacrylamide 32,

[0081] waxy cornstarch 15,

[0082] Sodium hypochlorite 7,

[0083] The composite initiator is composed of components in the following weight ratios: potassium persulfate, ammonium persulfate, sodium bisulfite, sodium persulfate, and kaolin in a weight r...

Embodiment 3

[0085] This embodiment relates to a kind of white latex and preparation method thereof (preparation method is the same as embodiment 1); White latex is made up of each component of following parts by weight:

[0086] Polyvinyl acetate 800,

[0087] Vinyl acetate 315,

[0088] Polyvinyl alcohol 125,

[0089] Dibutyl phthalate 80,

[0090] Diethylene glycol dibenzoate 25,

[0091] Octanol 12,

[0092] Isopropanol 35,

[0093] Allyl methacrylate 15,

[0094] Ethylene glycol dimethacrylate 7,

[0095] Toluene diisocyanate 4,

[0096] Sodium bicarbonate 39,

[0097] water 1450,

[0098] Emulsifier 45, the emulsifier is sodium dodecylbenzenesulfonate;

[0099] Composite initiator 6,

[0100] Methylolacrylamide 25,

[0101] waxy cornstarch 12,

[0102] Sodium hypochlorite 4,

[0103] The composite initiator is composed of components in the following weight ratios: potassium persulfate, ammonium persulfate, sodium bisulfite, sodium persulfate, and kaolin in a weight rati...

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Abstract

The invention provides strong water-resistant white emulsion and a preparation method thereof. The strong water-resistant white emulsion consists of the following components in parts by weight: 900 parts of polyvinyl acetate, 330 parts of vinyl acetate, 130 parts of polyving alcohol, 85 parts of phthalic acid dibutyl ester, 30 parts of diethylene glycol dibenzoate, 13 parts of octanol, 37 parts of isopropanol, 19 parts of methacrylic acid n-propyl ester, 8 parts of ethyleneglycol dimethacrylate, 5 parts of toluene diisocynate, 41 parts of sodium bicarbonate, 1460 parts of water, 46 parts of an emulsifier, 7 parts of a composite initiator, 27 parts of hydroxymethyl acrylamide, 13 parts of wax corn starch and 5 parts of sodium hypochlorite. The strong water-resistant white emulsion provided by the invention does not need to use solvents such as formaldehyde, and is good in environment-friendly property, excellent in index such as thermal stability, primary drying time, water resistance, adhesion strength and curing time, and excellent in comprehensive property.

Description

technical field [0001] The invention relates to the technical field of white latex, in particular to a strong water-resistant white latex and a preparation method thereof. Background technique [0002] At present, the threshold industry of doors and windows is relatively low, and the competition in the industry is relatively chaotic. In order to improve product quality and market competitiveness, continuous improvement is required. High-grade energy-saving wooden doors and windows widely used in building exterior windows include: pure wood doors and windows, aluminum-clad wood doors and windows, and wood-aluminum composite doors and windows. The wood-aluminum composite doors and windows are more suitable for the rainy, high temperature and humid climate conditions in the south because the outer side is made of heat-insulating aluminum alloy profiles and the inner side is made of wood decorative profiles. At present, the structure of wood-aluminum composite doors and windows...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J151/00C09J11/08C09J11/06C09J11/04C08F263/04C08F220/18C08F222/14C08F220/54C08F118/08C08F2/26
Inventor 董德明
Owner 海安县紫石涂料有限公司
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