Method for recycling hydrogen in ethylbenzene dehydrogenation waste gas
A technology for the dehydrogenation of ethylbenzene and hydrogen, which is applied in the field of petrochemical industry, can solve the problems of accelerating styrene self-polymerization, unfavorable regeneration of adsorbents, and limiting technical feasibility, so as to reduce the possibility and prolong the service life
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Embodiment 1
[0019] The ethylbenzene dehydrogenation tail gas produced by the styrene production unit is compressed by the compressor to form a gas-liquid mixture and put into the cryocooler, cooled to 20°C; the non-condensed ethylbenzene dehydrogenation tail gas enters from the bottom of the circulating absorption tower, Countercurrent contact with the ethylbenzene input from the top of the absorption tower, the hydrocarbons in the gas phase in the absorption tower are absorbed by ethylbenzene, the pressure at the top of the absorption tower is controlled to 170Kpa, and the liquid phase at the bottom of the absorption tower is sent to the ethylbenzene catalytic dehydrogenation reactor; from the absorption tower The gas phase discharged from the top enters the gas-liquid mixer, and after gas-liquid separation, the liquid phase returns to the ethylbenzene dehydrogenation device; the gas phase after removing hydrocarbons and water vapor enters the hydrogen separation and purification equipment...
Embodiment 2
[0022] The ethylbenzene dehydrogenation tail gas produced by the styrene production unit is compressed by the compressor to form a gas-liquid mixture and put into the deep cooler, cooled to 10°C; the non-condensed ethylbenzene dehydrogenation tail gas enters from the bottom of the circulating absorption tower, Countercurrent contact with the ethylbenzene input from the top of the absorption tower, the hydrocarbons in the gas phase in the absorption tower are absorbed by ethylbenzene, the pressure at the top of the absorption tower is controlled to 195Kpa, and the liquid phase at the bottom of the absorption tower is sent to the ethylbenzene catalytic dehydrogenation reactor; from the absorption tower The gas phase discharged from the top enters the gas-liquid mixer, and after gas-liquid separation, the liquid phase returns to the ethylbenzene dehydrogenation device; the gas phase after removing hydrocarbons and water vapor enters the hydrogen separation and purification equipmen...
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