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Stress-whitening-resistant PP (propene polymer) plastics

An anti-stress whitening and plastic technology, applied in the field of PP plastics, can solve the problems of stress whitening of the card foot, stress whitening resistance, and polypropylene cannot achieve high modulus at the same time, and achieves good anti-stress whitening characteristics, good Fold-resistant effect

Active Publication Date: 2015-06-24
昕亮科技(深圳)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although polypropylene has many advantages, polypropylene also has some disadvantages. For example, it does not achieve a good balance of rigidity and toughness. High-modulus polypropylene often cannot achieve high impact at the same time, and high-impact polypropylene cannot achieve both. High modulus; at the same time, some parts also require the material to have good resistance to stress whitening and stress cracking
[0003] During the injection molding process of polypropylene PP products, the force tends to be relatively concentrated at the ejection part, and silver streaks are generated at the stressed part, and a large number of tiny internal cracks are generated in the silver streak area. The top white phenomenon leads to unqualified product appearance; some polypropylene products are in use, and some special structures such as clip feet are easy to be stressed, resulting in stress whitening and cracking

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0013] The stock preparations were weighed according to the respective components of Examples 1-4 in Recipe Table 1, and the materials were dry blended in a high speed mixer for 5 minutes.

[0014] (3) Put the above-mentioned mixed raw materials into a twin-screw extruder for extrusion granulation, the screw speed is 500 rpm, and the temperature is 190-200 ℃ in the first zone, 200-220 ℃ in the second zone, and 220-220 in the third zone. 235°C, four zones 215-220°C; extrusion process time is 2 minutes, pressure is 12-18MPa.

[0015] The stress-whitening PP plastic of the present invention can be obtained.

[0016] Table 1: Lid plastic material formula table Unit: kg

[0017]

Example 1

Example 2

Example 3

Example 4

Comparative ratio

PP resin

90

90

90

90

90

POE resin

3

3

3

3

3

TiO 2

1

1.5

1.5

-

-

SnO 2

1

1.5

-

1.5

-

ZrO 2

1 ...

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PUM

PropertyMeasurementUnit
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Abstract

The invention discloses stress-whitening-resistant PP (propene polymer) plastics. The stress-whitening-resistant PP plastics consist of the following raw materials in part by weight: 90 parts of PP resin, 1-5 parts of POE (polyolefin elastomer) resin, 1-5 parts of stress-whitening-resistant agents, 2-6 parts of maleic anhydride grafted polypropylene and 0.1-0.9 part of antioxygen 1010. The stress-whitening-resistant PP plastics have high folding resistance and stress whitening resistance, and cannot be whitened after being repeatedly bent manually more than 200 times.

Description

technical field [0001] The invention relates to a PP plastic, in particular to a stress-whitening PP plastic. Background technique [0002] Polypropylene PP is one of the five types of general-purpose plastics. Because of its rich raw material sources, low price, easy processing and excellent product performance, it has a wide range of uses and has become the fastest-growing variety of general-purpose resins. It is widely used inside and outside the car. in accessories, electronics and home appliances. Although polypropylene has many advantages, it also has some shortcomings. For example, it does not achieve a good balance of rigidity and toughness. High-modulus polypropylene often cannot achieve high impact at the same time, and high-impact polypropylene cannot achieve high impact at the same time. High modulus; at the same time, some parts also require materials with good resistance to stress whitening and stress cracking. [0003] During the injection molding process of...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L23/08C08L51/06C08K3/22C08K5/134
CPCC08L23/12C08L2205/03C08L23/0815C08L51/06C08K13/02C08K2003/2237C08K2003/2231C08K2003/2244C08K5/1345
Inventor 袁峰
Owner 昕亮科技(深圳)有限公司
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