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Polyelectrolyte and energy storage device

A polyelectrolyte and energy storage element technology, applied in the field of energy storage, can solve problems such as poor ion conductivity, hinder application and commercialization, and achieve the effect of improving characteristics

Active Publication Date: 2015-07-01
IND TECH RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Although the above-mentioned polyelectrolyte can inhibit the deposition and puncture of lithium metal, increase the safety of lithium batteries, and can be prepared flexibly in size and shape, it is suitable for various lithium batteries, but its poor ion conductivity (solid polymer electrolyte is ~ 10 -5 S / cm, single ion conductor is ~10 -6 S / cm) has been hindering its application and commercialization

Method used

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  • Polyelectrolyte and energy storage device

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Embodiment Construction

[0058] In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with specific embodiments and with reference to the accompanying drawings.

[0059] The polyelectrolyte of the present invention comprises a first chain segment and a second chain segment, wherein the first chain segment structure is at least one of formula (1) and formula (2); the second chain segment structure is formula (3) and formula ( 4) at least one of. The molecular weight (M W ) is, for example, between 10,000 and 90,000; the molecular weight of the second segment is, for example, between 10,000 and 30,000.

[0060]

[0061] In formula (1), R 1 ~R 8 each independently as H, F or n=1-10, x=1-1000. In addition, the molecular repeating unit x of the first segment is preferably 300-900.

[0062]

[0063] In formula (2), R 9 ~R 11 each independently as H, F or R 12 for R 1...

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Abstract

A polyelectrolyte includes a first segment and a second segment, wherein the structure of the first segment is at least one of formula (1) and formula (2); the structure of the second segment is at least one of formula (3) and formula (4). The polyelectrolyte undergoes microphase separation to form a nanoscale ordered self-assembled microstructure.

Description

technical field [0001] The invention relates to an energy storage technology, in particular to a polyelectrolyte and an energy storage element. Background technique [0002] As people's demand for lithium secondary batteries with high power and high energy density continues to increase, more and more research institutes are committed to improving their safety and stability. And because people's dependence on portable electronic products is increasing, and it is expected to increase the application of electrochemical energy storage devices in vehicles, uninterruptible power systems, etc., the safety of lithium secondary batteries must be further strictly required, especially for high-altitude flights aircraft or space shuttle. The current research on safety usually focuses on the development of flame retardant additives, solid electrolytes or new electrolyte systems, etc., all of which are aimed at improving various problems of liquid electrolytes and increasing the thermal ...

Claims

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Application Information

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IPC IPC(8): H01M10/0565H01M6/22H01M8/10H01G11/56H01G9/025
CPCH01G9/035H01M2008/1095H01M8/00H01M10/0566C08F36/08H01M6/162H01M8/1018H01M10/0565C08F12/08H01M2300/0025H01G9/028C08C19/04C08F12/22C08F212/08C08F212/14H01G11/56H01G11/60H01G11/62H01G11/64H01M10/052H01M2300/0082C08F236/08C08F8/12C08F8/44C08F236/10C08F212/22Y02E60/10Y02E60/50C08F8/34Y02E60/13
Inventor 赵崇翔蔡丽端方家振张志清赵基扬刘昆霖
Owner IND TECH RES INST
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