An experimental analysis method for microwave response characteristics of high-sulfur coal and sulfur-containing model compounds

A technology of model compounds and response characteristics, applied in the direction of material capacitance, etc., can solve the problem of inability to test the actual dielectric constant of coal microwave broadband, lack of systematic research on coal microwave dielectric response characteristics, and lack of selection of microwave desulfurization test conditions Theoretical guidance and other issues

Active Publication Date: 2017-10-10
CHINA UNIV OF MINING & TECH
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Problems solved by technology

[0004] The purpose of the present invention is to provide a microwave response characteristic test and analysis method of high-sulfur coal and sulfur-containing model compounds, to solve the current inability to carry out the actual dielectric constant test of coal microwave broadband, the lack of theoretical guidance for selecting microwave desulfurization test conditions and There is a lack of technical problems in systematically studying the microwave dielectric response characteristics of coal, the mechanism of microwave desulfurization and the law of coal quality change

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  • An experimental analysis method for microwave response characteristics of high-sulfur coal and sulfur-containing model compounds
  • An experimental analysis method for microwave response characteristics of high-sulfur coal and sulfur-containing model compounds
  • An experimental analysis method for microwave response characteristics of high-sulfur coal and sulfur-containing model compounds

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Embodiment 1

[0029] 1) Prepare powder samples. Taking Xinyu high-sulfur clean coal as an example, firstly, according to the sample preparation method 1, the Xinyu high-sulfur clean coal is crushed and then screened, floated and sank, separated from coal and rock components and added with a mass percentage of 0% to 30%. Water is used to prepare powder samples of different particle size grades, density grades, coal rock components and water content. Secondly, according to sample preparation method 2, XANES and XPS analyzes were carried out on Xinyu high-sulfur clean coal. The results showed that sulfur in coal mainly exists in the form of sulfide, thiophene, sulfone and sulfoxide. Dibenzyl sulfide, dibenzothiophene, diphenyl sulfone and diphenyl sulfoxide with similar occurrence forms represent model compounds containing sulfur in coal. Then prepare samples of the sulfur-containing model compounds selected by sample preparation method 2 according to sample preparation method 3, that is, to ...

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Abstract

The invention discloses a microwave response characteristic test and analysis method of high-sulfur coal and sulfur-containing model compounds, which belongs to the research method of coal microwave desulfurization technology. The method steps: 1) preparing a powder sample; 2) testing the dielectric constant of the powder sample; 3) analyzing and theoretically calculating the dielectric constant of the powder sample; 4) conducting a microwave desulfurization test; 5) analyzing and summarizing the high-sulfur coal and Microwave response properties of sulfur-containing model compounds. Advantages: Combining the measured data and theoretical conversion, the actual dielectric constant test method of coal microwave broadband is established, and then the dielectric property test is carried out on the basis of preparing various powder samples with comprehensive properties by integrating existing analysis methods and sample preparation methods. A comprehensive study of the microwave dielectric response characteristics of coal was realized, and then a comprehensive study of the microwave desulfurization mechanism and coal quality changes was realized through the microwave desulfurization test combined with industrial analysis, component determination, coal quality analysis, functional group and sulfur occurrence form detection, and finally A comprehensive study on the microwave response characteristics of coal has been realized.

Description

technical field [0001] The invention relates to a research method of coal microwave desulfurization technology, in particular to a microwave response characteristic test analysis method of high-sulfur coal and sulfur-containing model compounds. Background technique [0002] Coking coal and fat coal, which play a skeleton role in the coking process, account for about 7.56% of the total coal in my country, and are scarce coals. With the continuous growth of steel consumption and the development of large-scale blast furnaces, there has been a serious shortage of high-quality coking coal, causing more and more coking enterprises to start using high-sulfur coking coal. Thereby affecting coke quality and steel quality, also brought serious environmental pollution. [0003] Coal microwave desulfurization technology is a new type of coal temperature purification desulfurization method developed in recent years. It is a method to achieve the purpose of desulfurization by using the d...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N27/22
Inventor 陶秀祥谢茂华唐龙飞杨彦成罗来芹柳泉洲陈松降王市委
Owner CHINA UNIV OF MINING & TECH
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