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Polymer composite lightweight rubber and preparation method thereof

A polymer and rubber technology, applied in the field of polymer composite lightweight rubber and its preparation, can solve the problems of unsatisfactory physical properties, poor anti-slip effect, low formula cost, etc., and achieves wide processing methods, convenient processing, and light specific gravity. Effect

Active Publication Date: 2015-11-18
DONGGUAN JISU PLASTIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The main materials for the production of soles are rubber, PU, ​​PVC, MD, TPR, TPU, EEVA, etc. Rubber soles are widely used in footwear due to their advantages such as non-slip, high elasticity, good wear resistance, not easy to break, good elongation, and stable shrinkage. It can be said that it occupies half of the country in the finished products. At present, most of the finished shoes of domestic first-line brands use rubber soles, but the disadvantage of rubber soles is that the formula cost is low, and the physical properties are not satisfactory. If you want to make high-quality soles, the rubber soles used The cost of rubber formula is generally higher
For every 100 grams increase in the weight of the shoe, the physical energy consumption will increase by 1%. High elasticity and light weight are the current development direction of rubber sole materials. Although rubber materials have strong elasticity, their quality is relatively heavy. In order to achieve the purpose of light weight, At present, most of them use EEVA and other materials to replace rubber materials to solve the problem of lightweight. However, although EEVA foam soles and PU soles are light in weight, they have poor anti-slip effects, fast aging, and high cost.
[0003] Traditional rubber needs to be vulcanized in order to make it have high elasticity, aging resistance, high wear resistance and oil resistance, but vulcanization is not friendly to the environment

Method used

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  • Polymer composite lightweight rubber and preparation method thereof
  • Polymer composite lightweight rubber and preparation method thereof
  • Polymer composite lightweight rubber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A polymer composite lightweight rubber, including calculated in parts by weight:

[0037] 50 parts of SBR, 50 parts of SEBS, 5 parts of RB8305, 5 parts of vinyl acetate, 20 parts of white mineral oil, 30 parts of butadiene rubber and 40 parts of elastomer.

[0038] Wherein said elastomer comprises calculated by weight percentage: high pressure bulk polymer 60%, accelerant (DM) 10%, binding agent 10%, bridging agent 7%, EVA12.7%, blowing agent 0.3 %.

[0039] The preparation method of polymer composite lightweight rubber, the preparation process is as follows:

[0040] A. First mix and stir said amount of SBR, SEBS, RB830, vinyl acetate and butadiene rubber evenly, then add said amount of white mineral oil and continue to stir for 4-5 hours to obtain mixture I;

[0041] B. Add 1 / 3 of the amount of elastomer to the mixture I for plasticizing and banburying to obtain the mixture II; the plasticizing temperature is 110-140°C, and the plasticizing pressure is 6-8MPA; The ...

Embodiment 2

[0046] A polymer composite lightweight rubber, including calculated in parts by weight:

[0047] 100 parts of SBR, 10 parts of SEBS, 30 parts of RB83030, 30 parts of vinyl acetate, 5 parts of white mineral oil, 5 parts of butadiene rubber and 20 parts of elastomer.

[0048] Wherein the elastic body includes: calculated by weight percentage: 40% of high-pressure bulk polymer, 10% of accelerator (CZ), 10% of binder, 9% of bridging agent, 30% of EVA, and 1% of foaming agent.

[0049] The preparation method of the polymer composite lightweight rubber is the same as in Example 1.

Embodiment 3

[0051] A polymer composite lightweight rubber, including calculated in parts by weight:

[0052] 60 parts of SBR, 40 parts of SEBS, 10 parts of RB830, 10 parts of vinyl acetate, 10 parts of white mineral oil, 10 parts of butadiene rubber and 50 parts of elastomer.

[0053] Wherein said elastomer comprises calculated by weight percentage: high pressure bulk polymer 44.5%, accelerant (DM10%, CZ10%) 20%, binding agent 20%, bridging agent 5%, EVA10%, blowing agent 0.5% %.

[0054] The preparation method of the polymer composite lightweight rubber is the same as in Example 1.

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Abstract

The invention belongs to the technical field of new materials and in particular relates to polymer composite lightweight rubber and a preparation method thereof. The rubber comprises the following components in parts by weight: 50-100 parts of SBR (styrene butadiene rubber), 10-50 parts of SEBS (styrene-ethylene / butylene-styrene elastomer), 5-30 parts of crystalline 1,2-polybutadiene resin B, 5-30 parts of vinyl acetate, 5-20 parts of white mineral oil, 5-30 parts of cis-polybutadiene and 20-50 parts of elastomer. The rubber and the preparation method have the beneficial effects that the rubber has excellent properties as traditional vulcanized rubber, such as high elasticity, aging resistance, high wear resistance and oil resistance, also has the independent characteristics of high property, light specific gravity, flex resistance, high pressure resistance and no vulcanization and can be produced by adopting the processing methods, such as injection molding, extrusion and blow molding; wastes (extruded waste rubber and raw edges) generated in the production process and finally emerging wastes can be directly returned and recycled, thus reducing the cost and environmental pollution and expanding the resource regeneration sources.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a polymer composite lightweight rubber and a preparation method thereof. Background technique [0002] The main materials for the production of soles are rubber, PU, ​​PVC, MD, TPR, TPU, EEVA, etc. Rubber soles are widely used in footwear due to their advantages such as non-slip, high elasticity, good wear resistance, not easy to break, good elongation, and stable shrinkage. It can be said that it occupies half of the country in the finished products. At present, most of the finished shoes of domestic first-line brands use rubber soles, but the disadvantage of rubber soles is that the formula cost is low, and the physical properties are not satisfactory. If you want to make high-quality soles, the rubber soles used The cost of rubber formulations is generally higher. For every 100 grams increase in the weight of the shoe, the physical energy consumption wil...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/06C08L53/02C08L47/00C08L91/00C08L9/00C08L23/06
Inventor 杨国雷
Owner DONGGUAN JISU PLASTIC TECH
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