Drug delivery stent or support with novolimus and lactide based coating such that novolimus has a minimal amount of bonding to the coating
A lactide and coating technology, applied in the field of polymer coatings for medical devices, can solve the problems of high therapeutic value, no value, and expensive
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[0142] Implantable devices comprising macrocyclic drug-PLA polymer conjugates were fabricated and tested as described in the Prophetic Examples below.
[0143] implantable device
[0144] Stents composed of bioresorbable polymers are manufactured by manipulating the polymer into tubes at temperatures above the polymer's melting point, after which the stent model is machined with a laser. The bracket model itself is a multi-link made of a series of corrugated rings connected by links.
[0145] polymer
[0146] PLA-based polymers such as pure poly(L-lactide), poly(L-lactide-co-D, L-lactide) or poly(L-lactide-co-caprolactone ) for brackets. When D,L-lactide or caprolactone is present, the preferred amount is from 1% (w / w) to 10% (w / w). Poly(L-lactide) polymers having an intrinsic viscosity of 2.0 dL / gm to 5.0 dL / gm may also be used. Coronary stents were fabricated with strut thicknesses and strut widths ranging from 100 microns to 175 microns.
[0147] coating
[0148]A co...
Embodiment approach 1
[0156] Embodiment 1. A bioabsorbable stent comprising a stent body and a coating on the stent body comprising a poly(D,L-lactide) polymer and novolimus conjugated to the polymer, wherein The amount of novolimus conjugated to the polymer is less than or equal to 0.35% (weight of novolimus / weight of polymer) as measured by liquid chromatography-mass spectrometry (LC-MS).
Embodiment approach 2
[0157] Embodiment 2. The bioabsorbable scaffold of embodiment 1, wherein the amount of novolimus conjugated to the polymer is less than or equal to 0.30% (weight of novolimus) as measured by liquid chromatography-mass spectrometry (LC-MS). / polymer weight).
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