Treatment method of methanol rectification wastewater in coal chemical industry

The technology of methanol rectification and treatment method is applied in the treatment field of methanol rectification waste water of coal chemical industry, and can solve the problems of restricting the development of coal chemical industry, low resource utilization rate and high operation cost, so as to realize resource utilization and solve treatment problems. Effect

Inactive Publication Date: 2016-04-13
中国寰球工程有限公司辽宁分公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the conventional methanol industrial wastewater treatment methods mainly include steam stripping and biochemical treatment methods, which require separate treatment of wastewater, high operating costs and low resource utilization, which restrict the development of the coal chemical industry.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The treatment method of the coal chemical industry methanol rectification wastewater of the present embodiment comprises the following steps:

[0024] Step 1: After the coal is initially crushed, sieve it with 150 mesh and 50 mesh sieves, take the coal with a particle size range of 150-50 mesh as coarse coal powder, and take the coal with a particle size range of less than 50 mesh as fine coal powder. Parts are weighed: 59 parts of coal powder, 36.5 parts of pulping water, 5 parts of activated sludge, 0.4 part of dispersant, wherein the mass ratio of coarse coal powder to fine coal powder is 3:7;

[0025] Step 2: Pour pulping water, activated sludge, and dispersant into the container, stir for 15 minutes at 150r / min, mix evenly, and fully expand the molecular structure of the dispersant;

[0026] Step 3: Gradually pour the coal powder into the mixture obtained in step 2, and increase the stirring speed. When all the coal powder is added, stir for 25 minutes under the co...

Embodiment 2

[0030] The treatment method of the coal chemical industry methanol rectification wastewater of the present embodiment comprises the following steps:

[0031] Step 1: After the coal is initially crushed, sieve it with 150 mesh and 50 mesh sieves, take the coal with a particle size range of 150-50 mesh as coarse coal powder, and take the coal with a particle size range of less than 50 mesh as fine coal powder. Parts are weighed: 60 parts of pulverized coal, 32 parts of pulping water, 7 parts of activated sludge, 0.6 part of dispersant, wherein the mass ratio of pulverized coal to pulverized coal is 3:7;

[0032] Step 2: Pour pulping water, activated sludge, and dispersant into the container, stir for 12 minutes at 180r / min, mix evenly, and fully expand the molecular structure of the dispersant;

[0033] Step 3: Gradually pour the coal powder into the mixture obtained in step 2, and increase the stirring speed. When all the coal powder is added, stir for 23 minutes under the cond...

Embodiment 3

[0037] The treatment method of the coal chemical industry methanol rectification wastewater of the present embodiment comprises the following steps:

[0038] Step 1: After the coal is initially crushed, sieve it with 150 mesh and 50 mesh sieves, take the coal with a particle size range of 150-50 mesh as coarse coal powder, and take the coal with a particle size range of less than 50 mesh as fine coal powder. Parts are weighed: 63 parts of pulverized coal, 37.5 parts of pulping water, 9 parts of activated sludge, 0.7 part of dispersant, wherein the mass ratio of pulverized coal to pulverized coal is 3:7;

[0039] Step 2: Pour the pulping water, activated sludge, and dispersant into the container, stir for 8 minutes under the condition of 200r / min, mix evenly, and fully expand the molecular structure of the dispersant;

[0040]Step 3: Gradually pour the coal powder into the mixture obtained in step 2, and increase the stirring speed. When all the coal powder is added, stir for 2...

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Abstract

The invention relates to the field of sewage treatment, in particular to a treatment method of methanol rectification wastewater in the coal chemical industry. The treatment method comprises steps as follows: coal is primarily broken, coal with the particle size of 150-50 meshes is crude coal powder, and coal with the particle size smaller than 50 meshes is fine coal powder; 59-63 parts of the coal powder, 31-37.5 parts of slurrying water, 5-9 parts of activated sludge and 0.4-0.8 parts of a dispersing agent are weighed in parts by weight, and the mass ratio of the crude coal powder to the fine coal powder is 3:7; the slurrying water, the activated sludge and the dispersing agent are stirred and uniformly mixed, and the molecular structure of the dispersing agent is sufficiently spread; the coal powder is gradually poured into the mixture obtained in the step 2, the stirring rotation speed is increased, and after all the coal powder is added, the mixture continues to be stirred for 20-25 min, and methanol rectification wastewater, sludge and coal slurry is obtained. Organic matters, such as alcohols, a little oil and the like, in the methanol rectification wastewater can generate heat in the gasification process, the organic matters in the wastewater can be sufficiently used, resource utilization of the methanol rectification wastewater is realized, and the treatment problem of the methanol rectification wastewater is fundamentally solved.

Description

technical field [0001] The invention relates to the field of sewage treatment, in particular to a method for treating coal chemical methanol rectification wastewater aimed at the field of coal chemical industry. Background technique [0002] In the process of coal chemical industry, raw coal gasification produces crude synthesis gas. The crude synthesis gas enters the methanol synthesis unit after transformation, low-temperature methanol washing and sulfur recovery section purification. Crude methanol is synthesized in the methanol synthesis unit and methanol rectification is carried out. The production is qualified Methanol for use in subsequent sections. [0003] In the process of methanol synthesis and methanol rectification, a certain amount of waste water will be generated at the bottom of the synthesis tower, the bottom of the pre-rectification tower and the bottom of the main rectification tower. This part of wastewater mainly contains methanol, and also contains a l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/32C10J3/46
CPCC10J3/46C10J2300/0923C10J2300/169C10L1/326Y02E50/30
Inventor 曾蓬沈虹韩建新赵东风卢磊崔海峰段潍超
Owner 中国寰球工程有限公司辽宁分公司
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