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A kind of high-emissivity glass glaze and method for preparing high-emissivity coating from the glaze

A glaze and coating technology, which is applied in the field of functional composite materials, can solve the problems of poor matching of linear expansion coefficient and insufficient temperature resistance of rigid heat insulation tile base

Active Publication Date: 2017-11-10
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The technical problem of the present invention is: to overcome the disadvantages of insufficient temperature resistance of existing high-emissivity coatings and poor matching with the linear expansion coefficient of rigid heat insulation tile substrates, to provide a high-emissivity glass coating glaze composition, and Method for preparing high-emissivity coating on the outer surface of ceramic fiber rigid heat-insulating tile from the glaze composition

Method used

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  • A kind of high-emissivity glass glaze and method for preparing high-emissivity coating from the glaze
  • A kind of high-emissivity glass glaze and method for preparing high-emissivity coating from the glaze
  • A kind of high-emissivity glass glaze and method for preparing high-emissivity coating from the glaze

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] Embodiment 1 prepares high emissivity glass frit

[0050]Pass the following raw materials through a 300-mesh sieve: fused silica powder, extra-hard glass powder, boron carbide powder, molybdenum disilicide powder and clay powder. Then weigh two portions of sieved raw materials according to the following dosages: each portion includes 140 grams of fused silica powder, 40 grams of extra-hard glass powder, 20 grams of boron carbide powder, 10 grams of molybdenum disilicide powder, and 10 grams of clay powder. Put the above two parts of powder into two ball milling tanks with a volume of 2 liters respectively, add 660 grams of deionized water and 4.0 grams of polyacrylate ammonium salt solution with a concentration of 20% by mass and a pH value of 7 into the ball milling tanks, Each ball mill jar is filled with zirconia balls with a cumulative volume of 700 milliliters. Put the ball mill jar on a horizontal industrial ball mill, adjust the rotating speed to 500 rpm, and mi...

Embodiment 19

[0055] Embodiment 19 prepares high emissivity coating

[0056] Use compressed air to blow off the dust on the surface of the rigid heat insulation tile substrate, and then put it in a muffle furnace at 600°C for 30 minutes to completely remove the oil stains remaining on the surface of the heat insulation tile during processing and handling. Repair small defects on the surface of the heat insulation tile base. Then use adhesive tape to protect the side breathing area and the bottom surface (the area not to be coated) of the rigid insulation tile, and place it on the spraying tool to prepare for spraying. Adjust the pressure of compressed air to 4MPa for spraying. According to 0.06g / cm 2 The amount of slurry used in Example 1 was sprayed on the surface and side of the heat insulation tile. Put the sprayed thermal insulation tile in the air to dry for at least 2 hours, then put it in an oven at 80°C for 2 hours, then transfer it to an oven at 120°C and bake it to constant wei...

Embodiment 20

[0057] Embodiment 20 The influence of ammonium polyacrylate ceramic dispersant on glaze dispersion effect

[0058] The basic formula and process are exactly the same as in Example 1, but the above-mentioned ammonium polyacrylate ceramic dispersant is not added. Take a small amount of the glass frit obtained from Example 1 and the above formula without adding the above-mentioned ammonium polyacrylate ceramic dispersant, respectively, and put them into two settling tubes to stand still, and observe the settling process. It was found that the glass powder of the above-mentioned glaze composition without the above-mentioned ammonium polyacrylate ceramic dispersant was placed for 20 minutes, and the glass powder had obviously settled, while the glass powder of the glaze composition of Example 1 was still not observed after being placed for 1 month. Obvious subsidence. It can be seen that the addition of ammonium polyacrylate ceramic dispersant improves the suspension characteristi...

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Abstract

The invention relates to a high-emissivity glass glaze and a method for preparing a high-emissivity coating. Specifically, the present invention relates to a glaze composition and its application in forming a glaze coating on, for example, ceramic fiber rigid insulation tiles, said glaze composition comprising glass powder, water and a ceramic dispersant; preferably It is desirable that the mass ratio of the glass powder, water and ceramic dispersant is 1:2 to 4:0.01 to 0.02. The present invention also relates to a method for preparing a glaze coating on a substrate, the method comprising the steps of: obtaining the glaze composition; coating the glaze composition on the surface of the substrate to form a glaze coating drying the glaze coating; and firing the dried glaze coating, thereby forming a fired glaze coating on the surface of the substrate. The method of the invention can obtain a hard and bright black glaze coating which has a hemispherical full-spectrum emissivity of not less than 0.90, and whose hemispherical full-spectrum emissivity decreases by no more than 10% after being reused 100 times under service conditions.

Description

technical field [0001] The invention belongs to the technical field of functional composite materials, and in particular relates to a glaze coating material and a method for preparing the glaze coating on a substrate, especially on a ceramic fiber rigid heat-insulating tile. Background technique [0002] When using lightweight and rigid ceramic insulation tiles as thermal protection materials for aircraft, a layer of high-emissivity coating is generally compounded on the outer surface of the lightweight and porous insulation tiles. High emissivity coatings can radiate most of the aerodynamic heat generated during flight back to the background space. In addition, the coating also acts as surface reinforcement, scour resistance and water repellency. [0003] US Patent No. 4093771 discloses a highly reactive reaction cured glass powder (Reaction Cured Glass, RCG) and a method for preparing a glass coating using RCG as a raw material. This glass frit is suitable for use as a s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C8/14C04B41/86
Inventor 鲁胜张凡刘斌苏力军李文静赵英民
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH