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Method for preparing electrode from natural graphite

A natural graphite, electrode preparation technology, applied in battery electrodes, circuits, electrical components, etc., can solve the problems of small specific surface area, complex electrode production process, etc., to increase specific surface area, improve electrode stability and activity, and easily conduct network. The effect of the passage

Inactive Publication Date: 2016-04-20
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a method for preparing an electrode using natural graphite, which overcomes the problems of complex production process and small specific surface area of ​​the existing electrode, and provides a method for simple production process and increasing the specific surface area of ​​the electrode

Method used

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  • Method for preparing electrode from natural graphite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The first step: preparation of high-grade graphite products

[0031] Liaoning graphite mine, raw ore grade is 8.69%, other element analysis is as follows:

[0032]

[0033] 1. Take 400g of graphite raw ore, grind the ore for 4 minutes under the condition of grinding concentration of 65%, put the ground ore in a 1.5L flotation tank for 5 minutes of flotation; and regrind the roughed ore concentrate three times The re-election process, the grinding time is 6min, 8min, 10min respectively, and the flotation time is: 7min, 4min, 4min; the obtained concentrate grade is 90.88%.

[0034] 2. Take 20g of flotation concentrate, add NaOH solution with a concentration of 15% according to the liquid-solid ratio of 3:1, react in an autoclave at 180°C for 4 hours, and filter to obtain the filter residue.

[0035] 3. Get 10g of the ore (filter residue obtained in step 2) after high-pressure alkali leaching, add a concentration of 60% NaOH solution according to the alkali-mine ratio ...

Embodiment 2

[0047] The first step: preparation of high-grade graphite products

[0048] Amu Beach Graphite Mine, raw ore grade is 10.42%, other element analysis is as follows:

[0049]

[0050] 1. Take 400g of graphite raw ore, grind the ore for 4 minutes under the condition of grinding concentration of 65%, put the ground ore in a 1.5L flotation tank for 5 minutes of flotation; and regrind the roughed ore concentrate three times The re-election process, the grinding time is 6min, 8min, 10min respectively, and the flotation time is: 7min, 4min, 4min; the obtained concentrate grade is 91.95%.

[0051] 2. Take 20g of flotation concentrate, add NaOH solution with a concentration of 15% according to the liquid-solid ratio of 3:1, react in an autoclave at 180°C for 4 hours, and filter to obtain the filter residue.

[0052]3. Get 10g of the ore (filter residue obtained in step 2) after high-pressure alkali leaching, add a concentration of 60% NaOH solution according to the alkali-mine ratio...

Embodiment 3

[0064] The first step: preparation of high-grade graphite products

[0065] Liaoning graphite mine, raw ore grade is 8.69%, other element analysis is as follows:

[0066]

[0067]

[0068] 1. Take 400g of graphite raw ore, grind the ore for 5 minutes under the condition of grinding concentration of 55%, put the ground ore into a 1.5L flotation tank for flotation for 5 minutes; and regrind the roughed ore concentrate three times The re-election process, the grinding time is 6min, 8min, 10min respectively, and the flotation time is: 7min, 4min, 4min; the grade of the obtained concentrate is 90.74%.

[0069] 2. Take 20g of flotation concentrate, add 10% ammonia water at a liquid-solid ratio of 5:1, react in an autoclave at 200°C for 1 hour, and filter to obtain a filter residue.

[0070] 3. Take 10 g of the ore after high-pressure alkali leaching (the filter residue obtained in step 2), add ammonia water with a concentration of 50% according to the alkali-mineral ratio of ...

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Abstract

The invention relates to and belongs to the technical field of new energy and new material application, and particularly relates to a method for preparing an electrode from natural graphite. The method is characterized in that natural graphite is physically and chemically processed to obtain high-carbon-content graphite; the processed graphite is granulated and fixed to plastic nets, and the plastic nets are put in a single-chamber microbiological battery in different layers to be used as the electrode. The method is used in a biological electrochemical system and is excellent in performance, green and environmentally friendly. Compared with a graphite felt electrode, the electrode is simple in production process, better in performance, low in price and wide in application prospect.

Description

technical field [0001] The invention belongs to the technical field of new energy and new material application, and in particular relates to a method for preparing electrodes from natural graphite. Background technique [0002] With the increase of energy consumption and the deterioration of the global environment, energy and the environment have become the two most important and urgent problems in the world today. At the same time, countries around the world are also seeking ways to obtain new energy and efficient environmental governance. [0003] Bioelectrochemical system is a kind of device that utilizes the extracellular electron transfer ability of anode microorganisms to recover biomass energy, mainly including microbial fuel cells that generate electrical energy and microbial electrolysis cells that generate hydrogen. One of the key factors affecting the electricity production of microbial fuel cells and the hydrogen production of microbial electrolysis cells is the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/96H01M4/88H01M8/16
CPCH01M4/88H01M4/96H01M8/16Y02E60/50
Inventor 李浩然王琪杜竹玮孙铭刘鹏伟
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI