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Method for preparing tin-copper alloy pole piece by using alloy powder

A technology of tin-copper alloy and alloy powder, which is applied in the field of preparation of tin-copper alloy pole pieces, can solve the problems of poor surface performance and low quality of tin-copper alloy, and achieves high performance, uniform particle size, and improved electrochemical performance. Effect

Active Publication Date: 2019-02-01
LIUZHOU HAOXIANGTE SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

From the perspective of preparation methods, the preparation of tin-copper alloys has the advantages of low cost, simple operation, and easy control of composition and thickness. However, the quality of tin-copper alloys prepared by existing methods is not high and the surface properties are not good.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Bulk Cu 5 sn 6 melted, and then the molten Cu 5 sn 6 The fluid is sprayed vertically through the nozzle to the surface of the rotating roller with grooves; the opening diameter of the groove on the roller surface is 0.5 mm, the mass flow rate of the fluid injection is 6g / s, and the vertical distance between the nozzle and the roller is 0.01mm 1. The diameter of the roller is 40mm, and the rotation speed of the roller is 300r / min; then the powder in the atomization chamber is collected, and the diameters of all particle sizes are analyzed to be between 15-23μm, and the powder is pressed into a 50μm thick tin-copper alloy foil; Then put the foil in the furnace for sintering. During the sintering, a mixed gas of argon and air with a flow rate of 20mL / min is introduced, wherein the volume ratio of argon to air is preferably 5:1, and the temperature is raised at 25°C / min. The rate was raised from room temperature to 400°C, and then kept at a temperature of 24 hours, and t...

Embodiment 2

[0027] Bulk Cu 5 sn 6 melted, and then the molten Cu 5 sn 6 The fluid is sprayed vertically through the nozzle to the surface of the rotating roller with grooves; the opening diameter of the groove on the roller surface is 0.7 mm, the mass flow rate of the fluid injection is 7g / s, and the vertical distance between the nozzle and the roller is 0.05mm 1. The diameter of the roller is 45mm, and the rotation speed of the roller is 320r / min; then the powder in the atomization chamber is collected, and the diameters of all particle sizes are analyzed to be between 11-18 μm, and the powder is pressed into a 50 μm thick tin-copper alloy foil; Then place the foil in a furnace for sintering. During sintering, a mixed gas of argon and air with a volume ratio of 6:1 is introduced, and the flow rate is 20mL / min, and the temperature rises from room temperature to 400°C at a rate of 25°C / min. , and then keep warm for 24h, and then naturally cool to room temperature, so as to obtain a tin-...

Embodiment 3

[0029] Bulk Cu 5 sn 6 melted, and then the molten Cu 5 sn 6 The fluid is sprayed vertically through the nozzle to the surface of the rotating roller with grooves; the opening diameter of the groove on the roller surface is 1.0 mm, the mass flow rate of the fluid injection is 8g / s, and the vertical distance between the nozzle and the roller is 0.1mm 1. The diameter of the roller is 42mm, and the rotation speed of the roller is 350r / min; then the powder in the atomization chamber is collected, and the diameters of all particle sizes are analyzed to be between 11-22μm, and the powder is pressed into a 55μm thick tin-copper alloy foil; Then place the foil in a furnace for sintering. During sintering, a mixture of argon and air with a volume ratio of 7:1 is introduced, and the flow rate is 20mL / min, and the temperature rises from room temperature to 400°C at a rate of 25°C / min. , and then keep warm for 24h, and then naturally cool to room temperature, so as to obtain a tin-coppe...

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Abstract

The invention relates to the preparation field of a tin-copper alloy pole piece, and specifically discloses a method for preparing the tin-copper alloy pole piece from alloy powder. The method comprises the steps of melting bulk Cu5Sn6; perpendicularly spraying the melted Cu5Sn6 fluid to the surface of a high-speed rotating rolling wheel through a nozzle; throwing the fluid by the rolling wheel to an atomizing chamber to be atomized; collecting atomized tin-copper alloy powder; pressing the powder into tin-copper alloy foil sheet; and putting the foil sheet into a furnace, and pumping mixed gas of air and argon for sintering the foil sheet to obtain the tin-copper alloy pole piece. According to the method, the sprayed fluid is smashed by centrifugal force of the rotating rolling wheel, so that the prepared powder is uniform in grain diameter, and the electrochemical performance of the tin-copper alloy pole piece can be greatly improved; and meanwhile, the mixed gas of air and argon is adopted for sintering to obtain the tin-copper alloy oxide film pole piece, so that the performance of the pole piece can be further improved.

Description

technical field [0001] The invention relates to the field of preparation of tin-copper alloy pole pieces, in particular to a method for preparing tin-copper alloy pole pieces by using alloy powder. Background technique [0002] Lithium battery is one of the most important power sources of existing electrical appliances or power tools. In order to improve the performance of lithium battery and increase the specific capacity of negative electrode, most manufacturers currently use tin negative electrode material. However, during the charge-discharge process, the tin anode has a large volume expansion rate, which will cause pulverization after long-term cycling, resulting in poor cycle performance. In order to solve these problems, composite alloys such as tin-copper alloys and tin-iron alloys are generally used as negative electrodes. From the perspective of preparation methods, the preparation of tin-copper alloys has the advantages of low cost, simple operation, and easy con...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/1395H01M4/38
CPCH01M4/1395H01M4/387Y02E60/10
Inventor 易鉴荣林荔琍唐臻吴坚林荔珊
Owner LIUZHOU HAOXIANGTE SCI & TECH