Method of producing layer structure, layer structure, a method of forming patterns and a semiconductor device
A layer structure and pattern technology, applied in the field of pattern formation, can solve problems such as difficulty in providing fine patterns
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Synthetic example 1
[0129] 70g (0.2mol) of 4,4'-(9H-fluorene-9,9-diyl)diphenol, 33.2g (0.2mol) of 1,4-bis(methoxymethyl)benzene, 70g of Propylene glycol monomethyletheracetate (PGMEA) and 1.23 g (8 mmol) of diethyl sulfate were placed in a flask and polymerized while being kept at 110° C. The reaction was terminated when the weight average molecular weight of the sample was 2,500 to 3,000. When the polymerization reaction was complete, the reactant was slowly cooled to room temperature and added to 30 g of distilled water and 300 g of methanol, and the mixture was stirred vigorously and allowed to stand. Next, the precipitate obtained by removing the supernatant therefrom was dissolved in 60 g of propylene glycol monomethyl ether acetate (PGMEA), and then the solution was vigorously stirred by using 250 g of methanol and allowed to stand (first process). Herein, the precipitate obtained after removing the supernatant therefrom again was dissolved in 60 g of propylene glycol monomethyl ether acet...
Synthetic example 2
[0133] A polymer (Mw: 3000) represented by the following chemical formula 2a was obtained at 120° C. according to the same method as in Synthesis Example 1, except that 20.2 g (0.1 mol) of pyrene, 33.2 g (0.2 mol) of 1, 4-bis(methoxymethyl)benzene, 14.4 g (0.1 mol) of 2-naphthol, 0.6 g (4 mmol) of diethyl sulfate and 70 g of propylene glycol monomethyl ether acetate (PGMEA).
[0134] [chemical formula 2a]
[0135]
Synthetic example 3
[0137] A polymer (Mw: 3000) represented by the following chemical formula 3a was obtained at 120° C. according to the same method as in Synthesis Example 1, except that 16.7 g (0.1 mol) of carbazole, 25.8 g (0.1 mol) of 4 , 4'-oxybis((methoxymethyl)benzene), 0.77 g (0.05 mol) of diethyl sulfite and 43 g of propylene glycol monomethyl ether acetate (PGMEA).
[0138] [chemical formula 3a]
[0139]
PUM
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