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High-nuclear manganese cluster compound based on sulfur-containing triazole ligand and preparation method thereof

A technology of high nuclear manganese clusters and cluster compounds, which is applied in organic chemistry methods, organic chemistry and other directions, can solve the problems of difficulty in obtaining single crystals, easy formation of precipitation, and low solubility of complexes, and achieves wide application prospects, The effect of improving solubility

Inactive Publication Date: 2016-07-13
GUANGXI NORMAL UNIV
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  • Abstract
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Problems solved by technology

However, the solubility of complexes formed by sulfur-containing triazoles and transition metals is very small, and precipitation is very easy to form, so it is difficult to obtain the single crystal required for determining the crystal structure.

Method used

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  • High-nuclear manganese cluster compound based on sulfur-containing triazole ligand and preparation method thereof
  • High-nuclear manganese cluster compound based on sulfur-containing triazole ligand and preparation method thereof
  • High-nuclear manganese cluster compound based on sulfur-containing triazole ligand and preparation method thereof

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Experimental program
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Embodiment

[0017] Synthesis of pernuclear manganese clusters based on sulfur-containing triazole ligands:

[0018] Weigh 0.2mmol (0.0294g) H 3 L, 0.2mmol (0.0724g) Mn (ClO 4 ) 2 ·6H 2 O, 0.2mmol (0.0617g) Cd(NO 3 ) 2 4H 2 O was mixed in 10 mL of N,N-DMF; the resulting mixture was stirred and reacted at room temperature for 6 hours, and filtered to obtain a colorless solution. The filtrate was allowed to stand for slow volatilization. After 25 days, light yellow cube-like crystals were precipitated from the mother liquor, separated, washed, and dried. Its yield was 29%.

[0019] see figure 1 In the molecular structure diagram of the high-nuclear manganese cluster compound of the present invention, for the convenience of observation, the peripheral guest solvent molecules are deleted. It can be clearly observed from the figure that the high-nuclear manganese cluster compound of the present invention is a 24-nuclear double-layer ring cluster compound composed of twenty-four mangane...

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Abstract

The invention discloses a high-nuclear manganese cluster compound based on a sulfur-containing triazole ligand and a preparation method thereof. According to the molecular structural graph, the high-nuclear manganese cluster compound is the 3-thioketone-5-mercapto methyl-1,2,4-triazole 24-nuclear manganese cluster compound. In the preparation process, by the adoption of the method of adding the second kind of metal salt cadmium nitrate, the solubleness of the indissolvable sulfur-containing triazole cluster compound is improved; the manganese cluster compound has the potential application value in the aspects of modern medicine, optics, magnetics, and ion selective absorption and separation. The method has the wide application prospect in the aspect of preparation of indissolvable cluster compound monocrystals.

Description

technical field [0001] The invention relates to a synthesis method of a complex, in particular to a preparation method of an insoluble cluster single crystal, in particular to a high-nuclear manganese cluster compound based on a sulfur-containing triazole ligand and a preparation method thereof. technical background [0002] There are many kinds of triazole derivatives, and as important functional groups, triazole ligands have relatively strong ability to complex metal ions and form hydrogen bonds, so they have attracted the attention of many researchers in the field of chemistry. In biological systems, because sulfur-containing compounds exist around the metal center of metalloproteases, they have potential application value in disease treatment. They can also be used as raw materials for metalloproteases in medicinal chemistry, and can also be used as synthetic semiconductors in material chemistry. The raw material of the material is widely used. In the synthesis of compl...

Claims

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Application Information

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IPC IPC(8): C07D249/12
CPCC07B2200/13C07D249/12
Inventor 蒋毅民郑云云黄富平张晓强王慧
Owner GUANGXI NORMAL UNIV
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