Light-response room-temperature phosphorescent supramolecular anti-counterfeit material and preparation method thereof

A technology for room temperature phosphorescence and phosphorescence molecules, which is used in luminescent materials, chemical instruments and methods, gel preparation, etc., and can solve the problems of complex synthesis of compounds, reduction of anti-counterfeiting levels, and inconvenience in use.

Inactive Publication Date: 2016-07-27
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

It has been reported that the reversible switch of room temperature phosphorescence can be realized by the decyclization and cyclization of photochromic compounds, but the synthesis of the reported compounds is c

Method used

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  • Light-response room-temperature phosphorescent supramolecular anti-counterfeit material and preparation method thereof
  • Light-response room-temperature phosphorescent supramolecular anti-counterfeit material and preparation method thereof

Examples

Experimental program
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Embodiment 1

[0022] This embodiment provides a photoresponsive room temperature phosphorescent supramolecular anti-counterfeiting material, and its preparation method is as follows: take a clean test tube, add 5mL1×10 -2 mol / LPd-TCPP solution in DMSO, 15mL5×10 -1 mol / LNBA DMSO solution, 55mL1mol / L sodium sulfite aqueous solution, at a stirring speed of 300 rpm, heated to 70°C in a water bath, kept warm for 8 minutes, added 25mL of 1.5mol / LDBS DMSO solution, continued to press 300 rpm Stir at a speed of 5 minutes, and then statically cool to obtain a supramolecular gel that is a light-responsive room temperature phosphorescent supramolecular anti-counterfeiting material.

Embodiment 2

[0024] This embodiment provides a photoresponsive room temperature phosphorescent supramolecular anti-counterfeiting material, and its preparation method is as follows: take a clean test tube, add 15mL1×10 -2 mol / LPd-TCPP solution in DMSO, 25mL5×10 -1 mol / LNBA DMSO solution, 25mL1mol / L sodium sulfite aqueous solution, at a stirring speed of 300 rpm, heated to 70°C in a water bath, kept warm for 10 minutes, added 35mL of 1.5mol / LDBS DMSO solution, continued to press 300 rpm Stir for 10 minutes at a speed of 10 minutes, and then statically cool to obtain the supramolecular gel, which is the photoresponsive room temperature phosphorescent supramolecular anti-counterfeiting material.

Embodiment 3

[0026] This embodiment provides a photoresponsive room temperature phosphorescent supramolecular anti-counterfeiting material, and its preparation method is as follows: take a clean test tube, add 10mL1×10 -2 mol / LPd-TCPP butanediol solution, 20mL5×10 -1 mol / LNBA butanediol solution, 30mL1mol / L sodium sulfite aqueous solution, at a stirring speed of 300 rpm, heated to 70°C in a water bath, kept warm for 9 minutes, added 40mL of 1.5mol / LDBS butanediol solution, continued Stir at a speed of 300 rpm for 8 minutes, and then statically cool to obtain a supramolecular gel that is a photoresponsive room temperature phosphorescent supramolecular anti-counterfeiting material. Example 4:

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Abstract

The invention provides a light-response room-temperature phosphorescent supramolecular anti-counterfeit material with adjustable luminous intensity and a preparation method thereof.The material is prepared in the mode that a gelator 1,3:24-benzylidene-sorbitol (DBS) serves as a self-assembly unit, and tetracarbonyl phenyl palladium porphyrins (Pd-TCPP) and o-nitrobenzaldehyde (NBA) are added into DBS and self-assembled into supramolecular gel in a mixed solvent composed of an organic solvent and water.The material has the advantages that before the supramolecular is irradiated by ultraviolet light, room-temperature phosphorescence cannot be generated by optical excitation; when the supramolecular is irradiated by ultraviolet light with the wavelength being 365 nm and the wavelength is excited to be 417 nm, room-temperature phosphorescence with the emission wavelength being 700 nm can be generated; the phosphorescence intensity of the supramolecular material can be controlled through the NBA concentration and ultraviolet light illumination time.The obtained supramolecular gel material has potential application value in the anti-counterfeit field.

Description

technical field [0001] The invention belongs to the field of luminous anti-counterfeiting materials, and in particular relates to a light-responsive room-temperature phosphorescent supramolecular anti-counterfeiting material with adjustable luminous intensity and a preparation method thereof. Background technique [0002] Compared with fluorescence, phosphorescence has a larger Stokes shift, which can avoid the interference of excitation light. At the same time, phosphorescence has a longer lifetime, which can avoid the interference of short-lived fluorescence and scattered light, thereby obtaining a lower detection limit. Fluorescence has been widely used in the field of anti-counterfeiting due to its simple lighting conditions and convenient use. For example, fluorescence technology is used in the anti-counterfeiting of RMB. However, phosphorescence requires low temperature conditions in order to control the non-radiative transition of phosphorescent molecules, which grea...

Claims

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Application Information

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IPC IPC(8): C09K11/06C09K11/02B01J13/00
CPCB01J13/0052C09K11/025C09K11/06C09K2211/185
Inventor 王宏朱婷玉杨亚江解孝林郑成赋廖永贵
Owner HUAZHONG UNIV OF SCI & TECH
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