Binder composition and binding method using same
A composition and adhesive technology, applied in the direction of bonding method, adhesive type, starch adhesive, etc., can solve the problems of air pollution, loss of raw materials, etc., and achieve the effect of saving curing conditions
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preparation example 1
[0070] Preparation Example 1: Preparation of Urea-Formaldehyde Resin 1
[0071] 340 g of formaldehyde (Formalin: Formaline (37%)) and 126 g of urea (Urea) were added to a 4-necked synthesis flask equipped with a thermometer and a stirring device, and stirred at room temperature while blowing nitrogen gas. Then, after confirming that the liquid phase was clear, 0.8 g of sodium hydroxide (20% aqueous solution) was added. Then, after confirming that the pH reached the level of 8-9, the temperature was gradually raised to 80°C. After maintaining at this temperature for 2 hours, the temperature was lowered to room temperature, and then diluted with 232 g of distilled water. As a result, a urea-formaldehyde resin having a solid content of 36% and a pH of 8.26 was obtained. Here, it was confirmed that the total molar equivalent ratio of formaldehyde to the urea (Urea) was 2:1.
preparation example 2
[0072] Preparation Example 2: Preparation of Urea-Formaldehyde Resin 2
[0073] 511 g of formaldehyde (formalin (37%)) and 126 g of urea (Urea) were added to a 4-neck synthesis flask equipped with a thermometer and a stirring device, and stirred at room temperature while blowing nitrogen gas. Then, after confirming that the liquid phase was clean, 1.0 g of sodium hydroxide (20% aqueous solution) was added. Then, after confirming that the pH reached the level of 8-9, the temperature was gradually raised to 80°C. After maintaining at this temperature for 2 hours, the temperature was lowered to room temperature, and then diluted with 238 g of distilled water. As a result, a urea-formaldehyde resin having a solid content of 36% and a pH of 8.31 was obtained. Here, it was confirmed that the total molar equivalent ratio of formaldehyde to the urea was 3:1.
Embodiment 1
[0075] Add 350kg of the urea-formaldehyde resin composition prepared in Preparation Example 1, 310kg of molasses (Molasses (80%)), 30kg of citric acid (Citricacid (98%)), 3800kg of distilled water, 2kg of Silicone water repellent (SI1420Z-KCC) and 3 kg of dustproof oil (DustOil-GoviGaro217S) were stirred for 30 minutes with a mixer to prepare an adhesive composition. It was confirmed that the solid content of the prepared adhesive was about 9%.
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