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Polyether antifoaming agent and preparation method thereof

A polyether defoamer and stabilizer technology, applied in the field of polyether defoamer and its preparation, can solve the problem of hindering the growth of bacteria, killing a small number of bacteria cells, failing to keep up with the speed of fermentation and foaming, and affecting defoaming Effect and other problems, to achieve the effect of eliminating low toxicity, small surface tension, and improving defoaming speed

Active Publication Date: 2016-08-10
ZIBO HUISHENG IND & TRADE CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyether defoamers mainly include straight-chain polyether, etc., which have strong antifoaming ability and are currently the leading defoamers used in the fermentation industry, but their defoaming speed is slower than that of silicone defoamers, which cannot keep up with fermentation foaming speed, which affects the effect of defoaming, and because the polyoxyethylene chain of the hydrophilic chain has low toxicity, it will hinder the growth of bacteria and kill a small amount of bacteria cells when used in the fermentation process. affect the efficiency of fermentation
[0003] Polyether "330", "PPG", and "GP" polyoxypropylene ether, because their chain ends are hydrophobic chains, are not easy to disperse in the fermentation broth, resulting in slow defoaming speed, which cannot keep up with the foaming speed of fermentation. Affected the defoaming effect
"GPE", "PPE", "3010", polyoxypropylene oxyethylene glyceryl ether, although the defoaming performance of the previous defoamers has been improved, but because of the low toxicity of the hydrophilic polyoxyethylene chain, In the fermentation production, the phenomenon of hindering the growth of bacteria and killing a small amount of bacteria cells occurs, which affects the fermentation efficiency.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of polyether defoamer, is made up of the raw material of following percentage by weight: polyoxypropylene oxyethylene glyceryl ether 89%, aliphatic higher carbon alcohol 2.1%, silicone grease and silicone oil (viscosity is 260mpa.s) 7.7%, penetrant TW -80 0.5%, catalyst NPE-10 0.2%, diffusing agent NPE-7 0.2%, stabilizer OPE-4 0.3%. The total weight percentage is 100%.

[0026] The mass ratio of silicone grease and silicone oil is 1:1.

[0027] The preparation method of this polyether defoamer is as follows:

[0028] (1) Put polyoxypropylene oxyethylene glyceryl ether into the reaction device, heat and stir, the stirring speed is 60r / min, the stirring time is 1.2h, and heat to 40°C at the same time;

[0029] (2) On the basis of 40°C, put fatty high-carbon alcohol into the reaction device for stirring, the stirring speed is 90r / min, and the stirring time is 1h; its structure is blocked with fatty high-carbon alcohol, so that both ends of the chain segment It be...

Embodiment 2

[0033] A kind of polyether antifoaming agent, is made up of the raw material of following percentage by weight: polyoxypropylene oxyethylene glyceryl ether 95%, aliphatic high carbon alcohol 0.6%, silicone grease and silicone oil (viscosity is 260mpa.s) 4%, penetrant TW -80 0.1%, catalyst NPE-10 0.1%, diffusing agent NPE-7 0.1%, stabilizer OPE-4 0.1%. The total weight percentage is 100%.

[0034] The mass ratio of silicone grease and silicone oil is 1:0.8.

[0035] The preparation method of this polyether defoamer is as follows:

[0036] (1) Put polyoxypropylene oxyethylene glyceryl ether into the reaction device, heat and stir, the stirring speed is 90r / min, the stirring time is 1h, and heat to 35°C at the same time;

[0037] (2) On the basis of 35°C, put fatty high-carbon alcohol into the reaction device for stirring, the stirring speed is 60r / min, and the stirring time is 1.2h; its structure is terminated with fatty high-carbon alcohol, so that the two chain segments The...

Embodiment 3

[0041] A kind of polyether antifoaming agent, is made up of the raw material of following percentage by weight: polyoxypropylene oxyethylene glyceryl ether 92%, aliphatic higher carbon alcohol 1.3%, silicone grease and silicone oil (viscosity is 260mpa.s) 6%, penetrant TW -80 0.3%, catalyst NPE-10 0.1%, diffusing agent NPE-7 0.1%, stabilizer OPE-4 0.2%. The total weight percentage is 100%.

[0042] The mass ratio of silicone grease and silicone oil is 1:0.5.

[0043] The preparation method of this polyether defoamer is as follows:

[0044](1) Put polyoxypropylene oxyethylene glyceryl ether into the reaction device, heat and stir, the stirring speed is 70r / min, the stirring time is 1h, and heat to 40°C at the same time;

[0045] (2) On the basis of 40°C, put fatty high-carbon alcohol into the reaction device for stirring, the stirring speed is 70r / min, and the stirring time is 1h; its structure is capped with fatty high-carbon alcohol, so that both ends of the chain segment ...

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Abstract

The invention belongs to the field of chemical auxiliaries and particularly relates to a polyether antifoaming agent and a preparation method thereof. The polyether antifoaming agent is prepared from, by weight, 89-95% of polyoxypropylene oxyethylene glycol ether, 0.6-2.1% of fatty high-carbon alcohols, 4-7.7% of silicon grease and silicon oil, 0.1-0.5% of a penetrating agent, 0.1-0.2% of a catalyst, 0.1-0.2% of a diffusing agent and 0.1-0.3% of a stabilizer, wherein viscosity of the silicon oil is 260mpa.s. The polyether antifoaming agent is high in stability, antifoaming strength and antifoaming speed, and nutrients are provided for hyphae in a fermentation process while toxicity is reduced. In addition, the polyether antifoaming agent is effective in foam elimination and inhibition in industries of papermaking, fermentation, foods, medicines and the like.

Description

technical field [0001] The invention belongs to the field of chemical auxiliary agents, and in particular relates to a polyether defoamer and a preparation method thereof. Background technique [0002] In the industrial production process of synthetic latex, papermaking, textile, food, fermentation, medicine, etc., many foams, even harmful foams, are often produced, which affect the normal production, which requires the use of defoamers to eliminate or suppress them. At present, there are many kinds of defoamers at home and abroad. Mainly include: grease defoamer, silicone defoamer and polyether defoamer, etc. Among them, the defoaming performance of grease-based defoamers is low, and the usual dosage is 20-60 times that of silicone-based and polyether-based defoamers. However, its ability to eliminate dense foam is poor. Silicone defoamers generally include polydimethylsiloxane, etc. Although these defoamers have high defoaming efficiency, their antifoaming effect is not...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D19/04
CPCB01D19/0404B01D19/0409
Inventor 张燕玲于慧生
Owner ZIBO HUISHENG IND & TRADE CO LTD
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