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Hydrophilic polyurethane composite grouting liquid with high strength of consolidation body and preparation method of hydrophilic polyurethane composite grouting liquid

A hydrophilic polyurethane and water-based polyurethane technology, applied in building components, building insulation materials, buildings, etc., can solve the problems of unreachable performance indicators of composite grouting, large specific surface area, uneven dispersion, etc., and reach the thermal decomposition temperature. And the effect of high residual quality, not easy to agglomerate, disperse and uniform agglomeration

Inactive Publication Date: 2016-10-12
ANHUI LENCAQI BUILDING MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to its small size and large specific surface area, nano-silica is easy to agglomerate and disperse unevenly in hydrophilic polyurethane. It is necessary to modify the surface of nano-silica before adding it to the raw material. The requirements are getting higher and higher, and the performance index of the composite grouting prepared in this paper can not meet the above requirements at all, so it is necessary to modify the existing production process and raw material ratio

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0012] A hydrophilic polyurethane composite grout with high strength of consolidated body, made of the following raw materials in parts by weight: water-based polyurethane emulsion 100, bisphenol A epoxy resin 19, polyacrylamide 1.4, glass fiber 8.5, calcined Kaolin 17, nano-silica 1.2, polytetrafluoroethylene emulsion 5, asphalt 3, methyldiethoxysilane 17, coconut shell 1.

[0013] A method for preparing a hydrophilic polyurethane composite grout with high strength of the consolidated body comprises the following steps:

[0014] (1) Heat and boil methyldiethoxysilane under the protection of nitrogen, add nano silicon dioxide to keep the temperature and stir for 1-2 hours, filter, wash and dry, freeze at minus 15-20°C for 3-5 hours, Add asphalt and grind it into powder to obtain organically modified nano-silica;

[0015] (2) Ultrasonically disperse the calcined kaolin in a mixed strong acid at 60-80°C for 4-6 hours, wash with deionized water until neutral, and vacuum-dry at 3...

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PUM

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Abstract

The invention discloses hydrophilic polyurethane composite grouting liquid with high strength of a consolidation body. After being modified organically, nano silicon dioxide is added in raw materials, can be dispersed uniformly and cannot be agglomerated easily, while the performance of the traditional polyurethane grouting liquid is kept basically, the thermal decomposition temperature and the residual mass of the hydrophilic polyurethane composite grouting liquid are obviously higher than those of the traditional polyurethane grouting liquid, active modifiers such as modified calcined kaolin, glass fibers and bisphenol A epoxy resin are further added, various components are mutually dispersed uniformly and do not sink, while the viscosity of the composite grouting liquid is improved, the strength of the consolidation body is further improved, the hydrophilic polyurethane composite grouting liquid can be quickly injected and permeates in tiny gaps of drift sand or sludge to form the consolidation body with certain strength, and accidents such as sand permeation, roof fall and rib spalling in a tunneling process are prevented.

Description

technical field [0001] The invention relates to the technical field of grouting materials, in particular to a hydrophilic polyurethane composite grouting liquid with high strength of consolidated body and a preparation method thereof. Background technique [0002] In the process of coal mine production, geological structures such as faults, folds, and fracture development zones are often encountered. The coal and rock masses are loose and broken, and large-scale roof caving and water inrush accidents are prone to occur, which seriously threatens the safe production of coal mines. Therefore, there is an urgent need for effective broken coal and rock mass reinforcement materials and technologies to solve this outstanding problem that affects the safety and efficiency of coal mines. At present, grouting technology is often used to reinforce the broken coal and rock mass and increase the support strength of the roadway. According to the grouting materials, it can be divided int...

Claims

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Application Information

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IPC IPC(8): C08L75/04C08L63/00C08L33/26C08L27/18C08L95/00C08K13/06C08K9/06C08K3/36C08K9/00C08K3/34C08K7/14
CPCC08K2201/011C08L75/04C08L2205/035C08L63/00C08L33/26C08L27/18C08L95/00C08K13/06C08K9/06C08K3/36C08K9/00C08K3/346C08K7/14
Inventor 乔启信金自海
Owner ANHUI LENCAQI BUILDING MATERIAL
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