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Method for preparing antifouling functional ceramic

A functional ceramics and antifouling technology, applied in the field of preparation of antifouling functional ceramics, can solve the problems of large porosity, difficult to remove, ceramic surface pollution, etc., and achieve the effects of simple preparation steps, good anti-fogging performance and low cost

Inactive Publication Date: 2016-11-09
董晓
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The main technical problem to be solved by the present invention is to solve the problem that currently common daily-use ceramic materials have large porosity due to their own structural characteristics, and are easy to attach pollutants under capillary action, making the ceramic surface polluted and difficult to remove, thus affecting the application of ceramics problem, a preparation method of antifouling functional ceramics is provided

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0019] Weigh 400g of aluminum isopropoxide and dissolve it in 5L of absolute ethanol, and use an ultrasonic oscillator to oscillate and mix for 30 minutes at a power of 200W to obtain a precursor solution. Transfer the precursor solution to a water bath at 80°C, and then drop it into the precursor solution through a dropping funnel. Drop in 1 / 2 of the volume of nitric acid solution with a mass concentration of 40%, add dropwise while stirring, control the drop rate so that the dropwise addition is completed within 40 minutes, keep warm and hydrolyze for 2 hours, and then get the self-made aluminum sol; take ordinary daily-use ceramics and put them in Clean in an ultrasonic cleaner for 10 minutes and dry naturally. Dip the above self-made aluminum sol with a wool brush and apply it evenly on the washed ceramic surface in the same direction, put it in an oven to dry, repeat the above coating steps twice and dry; Move the aluminum sol-coated ceramics into a muffle furnace, heat up...

example 2

[0022] Weigh 450g of aluminum isopropoxide and dissolve it in 5L of absolute ethanol, and use an ultrasonic oscillator with a power of 250W to ultrasonically oscillate and mix for 35 minutes to obtain a precursor solution. Transfer the precursor solution to a water bath at 85°C, and then drop it into the precursor solution through a dropping funnel. Drop into 1 / 2 of the volume of nitric acid solution with a mass concentration of 40%, add dropwise while stirring, control the drop rate so that the dropwise addition is completed within 45 minutes, keep warm and hydrolyze for 2 hours, and then get the self-made aluminum sol; take ordinary daily-use ceramics and put them in Clean in an ultrasonic cleaner for 13 minutes and dry naturally. Dip the above-mentioned self-made aluminum sol with a wool brush and apply it evenly on the washed ceramic surface in the same direction, put it in an oven to dry, repeat the aforementioned coating steps twice and dry; Move the aluminum sol-coated c...

example 3

[0025]Weigh 500g of aluminum isopropoxide and dissolve it in 6L of absolute ethanol, and use an ultrasonic oscillator to oscillate and mix for 40 minutes with a power of 300W to obtain a precursor solution. Transfer the precursor solution to a 90°C water bath, and then drop it into the precursor solution through a dropping funnel. Drop into 1 / 2 of the volume of nitric acid solution with a mass concentration of 40%, and add dropwise while stirring. Clean in an ultrasonic cleaner for 15 minutes and dry naturally. Dip the above self-made aluminum sol with a wool brush and apply it evenly on the washed ceramic surface in the same direction, put it in an oven to dry, repeat the above coating steps 3 times and dry; Move the above alumina sol-coated ceramics into a muffle furnace, heat up to 900°C at a rate of 10°C / min, heat-preserve and calcinate for 3 hours, and then leave the furnace to obtain pretreated ceramics for later use; collect discarded sardine bones and pulverize them wit...

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PUM

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Abstract

The invention relates to a method for preparing an antifouling functional ceramic, and belongs to the field of ceramic preparation. The method comprises the following steps: firstly, preparing aluminum sol by using an alkoxide hydrolysis method, coating an ordinary daily ceramic with the aluminum sol, sintering to obtain a prefabricated ceramic, mixing the prefabricated ceramic with fluorine-enriched sardine bone and then biologically modifying the surface to finally obtain an antifouling functional ceramic. Nano-aluminum oxide hydroxide particles in the aluminum sol and the ceramic are combined and are fired at high temperatures, so that the pores of the ceramic are effectively clogged, and a compact nano-alumina protective layer is formed on the surface, and thus the antifouling ability of the ceramic is improved; the ceramic is biologically modified with a low-surface energy fluorine substance, so that the surface energy of the ceramic is reduced, and further the adhesion of the ceramic is reduced, and thus the adhesion of contaminations is fundamentally avoided, the antifouling property is excellent, and the application field of ceramics is broadened.

Description

technical field [0001] The invention relates to a method for preparing antifouling functional ceramics, belonging to the field of ceramic preparation. Background technique [0002] Since the microstructure of ceramic materials is composed of crystal phase, glass phase and pores, the final product has a porosity of 5% to 10% (volume). At the same time, the surface of ceramic materials is generally lipophilic. When pollutants come into contact with the product Due to surface capillary action, some pollutants go deep into the open pores; in addition, the microscopic unevenness of the ceramic surface also leads to the adhesion of pollutants. Studies have found that pollutants are basically composed of soluble colored inorganic or organic substances in water, usually acidic or alkaline, such as sewage, tea, dust, ink and organic oil in daily life, which make the ceramic surface polluted and difficult to clean. Clear, affecting cleanliness and aesthetics. The accumulated oil wil...

Claims

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Application Information

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IPC IPC(8): C04B41/89
CPCC04B41/52C04B41/009C04B41/89
Inventor 董晓林茂平
Owner 董晓