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Treating agent for removing sulfide from coking sewage volatile gas and treatment method thereof

A technology for coking sewage and treatment agent, which is applied in chemical instruments and methods, separation methods, dispersed particle separation, etc., can solve the problems of foul odor of coking sewage volatile gas disturbing the people, and achieves the effect of solving the odor disturbing the people, the formula is reasonable, and the use is convenient.

Inactive Publication Date: 2016-12-07
CNOOC ZHOUSHAN PETROCHEM
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The first technical problem to be solved by the present invention is to provide a treatment agent for removing sulfides in the volatile gas of coking sewage in view of the above-mentioned current state of the art. The efficiency of sulfide in the gas is high, which effectively solves the problem of volatile gas and odor of coking sewage that disturbs the residents

Method used

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Embodiment Construction

[0020] The present invention will be described in further detail below in conjunction with specific examples.

[0021] The treatment agent for removing sulfides in coking sewage volatile gas in this embodiment, the formulation of the treatment agent is composed of alkali, sodium hypochlorite, sulfonated cobalt phthalocyanine as a catalyst and water, and the mixing ratio in the formulation is, alkali : Sodium hypochlorite: Cobalt sulfonated phthalocyanine: Water = 5000-7000: 1400-1600: 0.6-1.2: 8000-12000. The base is sodium hydroxide. The alkali is a liquid containing 30% sodium hydroxide by mass percentage.

[0022] Adopt the method for sulfide in the coking sewage volatile gas of above-mentioned treating agent, by the following steps:

[0023] 1. Fill the treatment agent with a hydrogen sulfide concentration of 50-500 mg / m 3 The hourly gas flow rate is 300m 3 Carry out the reaction of removing hydrogen sulfide, methyl mercaptan and organic sulfur in the gas container; Th...

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Abstract

A treatment agent for removing sulfide in coking sewage volatile gas and a treatment method thereof, the formulation of the treatment agent is composed of alkali, sodium hypochlorite, cobalt sulfonated phthalocyanine as a catalyst and water, and the mixing ratio in the formulation is , alkali: sodium hypochlorite: cobalt sulfonated phthalocyanine: water=5000~7000: 1400~1600: 0.6~1.2: 8000~12000. Adopt the method for the sulfide in the coking sewage volatilization gas of above-mentioned treating agent, by the following steps: 3 The hourly gas flow rate is 300m 3 The reaction to remove hydrogen sulfide, methyl mercaptan and organic sulfur is carried out in a separate gas container; 2. Then, through laboratory tests, analyze the components of the gas before and after treatment, and discharge the gas that meets the emission standards into the atmosphere. The method has the advantages of simple formulation and convenient preparation of the treatment agent; simple operation of the method, high removal rate of hydrogen sulfide, and effective removal of methyl mercaptan and organic sulfur.

Description

technical field [0001] The invention relates to the technical field of waste gas treatment, in particular to a treatment agent for removing sulfide in volatile gas of coking sewage and a treatment method thereof. Background technique [0002] An existing Chinese invention patent with application number CN201410792347.4 titled "Environmental Treatment Method for Waste Liquid Containing Caustic Soda Sodium Hypochlorite" discloses an environmentally friendly treatment method for waste liquid containing caustic soda sodium hypochlorite. When the NaOH solution absorbs chlorine waste gas, it will form Caustic soda sodium hypochlorite waste liquid, the above waste liquid is concentrated above 80°C, and NaClO is decomposed into NaCl and NaClO during the concentration process 3 , NaCl crystallizes out and is removed by filtration; the filtered caustic soda-containing waste liquid returns to continue to absorb chlorine waste gas, and the obtained waste liquid repeats the above-mention...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/86B01D53/78B01D53/52B01D53/48
CPCB01D53/8612B01D53/78B01D53/8606
Inventor 赵培江黄敬远李晓静张建设贾正万陈进旺洪浩王从顺杨涛王金玲张红旭
Owner CNOOC ZHOUSHAN PETROCHEM
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