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Graphene-containing high flame-retardant, low-smoke and halogen-free cable material and preparation method thereof

A graphene, high flame retardant technology, used in insulated cables, cables, circuits, etc., can solve the problems of poor mechanical properties, hard quality, low flame retardant and high smoke of cable materials, and achieve long service life, excellent mechanical properties, Beneficial for processing and laying

Active Publication Date: 2017-01-04
JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to solve the defects of poor mechanical properties, low flame retardancy, high smoke, and hard quality of cable materials in the prior art, the present invention provides a graphene-containing high flame-retardant low-smoke halogen-free cable material and its preparation method

Method used

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  • Graphene-containing high flame-retardant, low-smoke and halogen-free cable material and preparation method thereof
  • Graphene-containing high flame-retardant, low-smoke and halogen-free cable material and preparation method thereof
  • Graphene-containing high flame-retardant, low-smoke and halogen-free cable material and preparation method thereof

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Embodiment Construction

[0024] In order to better understand the present invention, the content of the present invention is further illustrated below in conjunction with the examples, but the content of the present invention is not limited to the following examples.

[0025] Examples 1-5 The raw material components of graphene-containing high flame-retardant low-smoke halogen-free cable materials are shown in Table 1:

[0026] Table 1. Raw material components of high flame-retardant low-smoke halogen-free cable materials containing graphene in Examples 1-5

[0027]

[0028] EVA in Table 1 is U.S. DuPont EVA 40L-03; Elastomer is POE 8200 (U.S. Dow), POE8230 (Exxon Mobil), POE6102 (Exxon Chemical Mobil); polyethylene is mLLDPE 3518CB (Exxon Chemical ); the compatibilizer is DuPont's 588P; the silicone masterbatch is MB50-B004 silicone masterbatch (Shanghai Tongzhuo New Material Technology Co., Ltd); the antioxidant is 1:1 of antioxidant 1010 and antioxidant 168 Compound system; the hydroxide is a m...

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Abstract

The invention discloses a graphene-containing high flame-retardant, low-smoke and halogen-free cable material and a preparation method thereof. The graphene-containing high flame-retardant, low-smoke and halogen-free cable material comprises the following components: 55-75 parts of an ethylene-vinyl acetate copolymer, 10-20 parts of an elastomer, 10-25 parts of metallocene linear-low density polyethylene, 5-10 parts of a compatilizer, 3-8 parts of a lubricant, 0.5-2 parts of an antioxidant, 60-100 parts of inorganic filler, 1-5 parts of graphene and 3 parts of carbon black master batches, wherein the weight sum of the ethylene-vinyl acetate copolymer, the elastomer and the metallocene linear-low density polyethylene is 100 parts, the inorganic filler is a mixture of at least one of magnesium hydroxide and aluminum hydroxide and huntite, and the part is weight part. The graphene-containing high flame-retardant, low-smoke and halogen-free cable material can reach the flame-retardant level of UL94 V-0, and is flexible in texture, excellent in mechanical property, long in service life and beneficial to processing and laying.

Description

technical field [0001] The invention relates to a graphene-containing high flame-retardant low-smoke halogen-free cable material and a preparation method thereof, belonging to the field of wire and cable materials. Background technique [0002] Due to the low smoke density released when low-smoke and halogen-free cable materials are burned, the demand for low-smoke and halogen-free cables in the domestic market is increasing. Generally, low-smoke halogen-free cable material manufacturers add a large amount of inorganic flame retardants to the formula and add red phosphorus to improve the flame retardant performance of the cable. But this will bring three problems: 1. The mechanical properties of the cable material deteriorate, and for cables with large cross-sections, it is easy to cause cracking; 2. Red phosphorus burns to produce a lot of smoke, which greatly increases the smoke density generated when the cable burns , which is contrary to the "low smoke" performance; 3. ...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L51/06C08K13/06C08K9/04C08K9/06C08K3/22C08K3/26C08K3/04H01B3/44H01B7/295
CPCC08K2201/003C08K2201/011C08L23/0853C08L2201/02C08L2201/22C08L2203/202C08L2205/025C08L2205/035C08L2205/08H01B3/441H01B7/295C08L23/0815C08L51/06C08K13/06C08K9/04C08K9/06C08K2003/2224C08K2003/2227C08K3/26C08K3/04
Inventor 沈清刘雄军郭剑桥汤志强徐桦
Owner JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD
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