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Styrene catalyst

A catalyst and styrene technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, organic chemistry, etc., can solve problems such as low stability and insufficient catalyst activity

Active Publication Date: 2019-02-19
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] One of the technical problems to be solved by the present invention is to overcome the shortcomings of insufficient catalyst activity and low stability in previous literatures, and provide a new styrene catalyst

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] 195 grams of iron oxide red, 80.5 grams of iron oxide yellow, 60.6 grams of potassium carbonate, 90.5 grams of persimmon nitrate, 13.3 grams of ammonium molybdate, 1.1 grams of molybdenum carbide, 10.4 grams of magnesium oxide, 19.5 grams of calcium oxide, 15 grams of cement and 10 grams of carboxylate Stir the methylcellulose in a kneader for 1 hour, add 83 grams of deionized water, and stir for another half an hour, take out the extruded strips, extrude them into particles with a diameter of 3 mm and a length of 5 to 10 mm, put them in an oven, and bake at 80 ° C for 4 Hours, and then placed in a muffle furnace, calcined at 780 ° C for 6 hours to prepare the catalyst.

[0039] For the convenience of comparison, the feed amount in catalyst preparation is listed in Table 1, and the results of catalyst evaluation for 200 hours are listed in Table 2.

Embodiment 2

[0041] 130.3 grams of iron oxide red, 152.6 grams of iron oxide yellow, 60.3 grams of potassium carbonate, 80.3 grams of persimmon nitrate, 10.6 grams of ammonium molybdate, 6.2 grams of molybdenum carbide, 8.4 grams of magnesium oxide, 19.5 grams of calcium oxide, 25 grams of cement and 8 grams of carboxylate Stir the methyl cellulose in a kneader for 1 hour, add 76 grams of deionized water, and stir for another half an hour, take out the extruded strips, extrude them into granules with a diameter of 3 mm and a length of 5 to 10 mm, put them in an oven, and bake at 80 ° C for 4 Hours, and then placed in a muffle furnace, calcined at 780 ° C for 6 hours to prepare the catalyst.

[0042] For the convenience of comparison, the feed amount in catalyst preparation is listed in Table 1, and the results of catalyst evaluation for 200 hours are listed in Table 2. The evaluation results of 200 hours and other evaluation time are listed in Table 3.

Embodiment 3

[0044] 130.3 grams of iron oxide red, 152.6 grams of iron oxide yellow, 60.3 grams of potassium carbonate, 80.3 grams of persimmon nitrate, 10.6 grams of ammonium molybdate, 6.2 grams of W 2 C, 8.4 grams of magnesium oxide, 19.5 grams of calcium oxide, 25 grams of cement and 8 grams of carboxymethyl cellulose were stirred in a kneader for 1 hour, 76 grams of deionized water was added, and then stirred for half an hour, the extruded strips were taken out and extruded into diameters The particles with a length of 3mm and a length of 5-10mm were put into an oven, baked at 80°C for 4 hours, then placed in a muffle furnace, and roasted at 780°C for 6 hours to obtain the catalyst.

[0045] For the convenience of comparison, the feed amount in catalyst preparation is listed in Table 1, and the results of catalyst evaluation for 200 hours are listed in Table 2. The evaluation results of 200 hours and other evaluation time are listed in Table 3.

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Abstract

The present invention relates to a styrene catalyst and a preparation method thereof. A purpose of the present invention is to mainly solve the problem of not enough high activity of the catalyst in the prior art. The styrene catalyst comprises the following active components by weight: a) 55-94 parts of Fe2O3, b) 5-30 parts of K2O, c) 3-15 parts of Ce2O3, d) 0.1-5 parts of MoO3 and / or WO3, e) 0.1-5 parts of a tungsten carbide, and f) 0.1-10 parts of at least the oxide of an alkaline earth metal selected from Mg, Ca, Sr and Ba. With the technical program of the present invention, the problem in the prior art is well solved. The styrene catalyst can be used in the industrial production of styrene.

Description

technical field [0001] The invention relates to a styrene catalyst and a preparation method thereof. Background technique [0002] At present, the vast majority of styrene in industry is realized by direct catalytic thermal dehydrogenation of ethylbenzene. The basic composition of the catalyst used includes main catalyst, co-catalyst, porogen, reinforcing agent and so on. Reports on catalysts can generally be divided into two categories, one is the early Fe-K catalysts containing Cr, such as published US patents US4467046, US4684619 and European patent EP0195252A2. Although this type of catalyst has good activity and stability, due to the existence of more or less Cr oxides in the composition, the preparation, operation and waste catalyst treatment of the catalyst will cause certain environmental pollution, and it has been gradually eliminated. The other is the Fe-K-Ce-Mo series successfully developed in the early 1980s, such as the published US patents US5190906, US480479...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/888C07C5/333C07C15/46
Inventor 陈铜倪军平刘剑锋范勤朱敏
Owner CHINA PETROLEUM & CHEM CORP