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Reflective insulation nano-modified quartz sand and preparation method thereof

A nano-modification, quartz sand technology, applied in chemical instruments and methods, reflective/signal coatings, inorganic pigment treatment, etc. The effect of easy promotion and saving transformation cost

Inactive Publication Date: 2017-03-15
ZHEJIANG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these methods realize the reflection and heat insulation function by adding other functional materials such as titanium dioxide and vitrified microbeads to the textured paint, and the addition of these materials will affect the very important sandy texture effect of the textured paint. The microspheres are also easy to break under the friction and extrusion of the quartz sand filler that produces texture effects during the coating production process and lose their thermal insulation properties, etc.
Therefore, under the comprehensive goal of requiring both high texture effect and high heat insulation effect, the result of this material is not obvious. It is obvious that this technology is still difficult to be well popularized and applied in high texture coatings such as real stone paint.

Method used

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  • Reflective insulation nano-modified quartz sand and preparation method thereof
  • Reflective insulation nano-modified quartz sand and preparation method thereof
  • Reflective insulation nano-modified quartz sand and preparation method thereof

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preparation example Construction

[0029] A method for preparing reflective heat-insulating nano-modified quartz sand: comprising the following steps:

[0030] Step 1. Add butyl titanate into the solvent, stir to make it fully dissolved, then add the chelating agent dropwise while stirring, and stir for 40-180min to prepare solution A;

[0031] Step 2, adding the pH adjuster and water into the solvent, stirring and mixing evenly to obtain solution B;

[0032] Step 3. Add solution B dropwise to solution A while stirring, continue stirring for 30-90 minutes after the addition, and leave to age for 10-48 hours after stirring to obtain sol C;

[0033] Step 4: Add quartz sand to sol C, stir to make it fully wet, let stand for 5-24 hours, filter and dry the quartz sand at 60-90°C for 30-90min, then calcinate at 450-750°C for 2- 8h, after annealing and cooling, the product is reflective heat insulation nano-modified quartz sand.

Embodiment 1

[0036] A reflective heat-insulating nano-modified quartz sand, which consists of the following raw materials:

[0037]

[0038]

[0039] The above raw materials are 100g in total.

[0040] Prepared according to the following steps:

[0041] Step 1. Add 15g of butyl titanate into 30g of ethanol, stir to make it fully dissolved, then add 1.5g of acetylacetone dropwise while stirring, and stir for 90min to obtain solution A;

[0042] Step 2: Add 1g of acetic acid and 0.5g of water into 12g of ethanol, stir and mix evenly to prepare solution B;

[0043] Step 3. Add solution B dropwise to solution A while stirring, continue to stir for 60 minutes after the addition, and leave to age for 24 hours after stirring to obtain Sol C;

[0044] Step 4: Add 40g of quartz sand to sol C, stir to make it fully wet, let it stand for 12 hours, filter and dry the quartz sand at 80°C for 45 minutes, and then calcinate at 650°C for 5 hours, after annealing and cooling, the product is reflectiv...

Embodiment 2

[0047] A reflective heat-insulating nano-modified quartz sand, which consists of the following raw materials:

[0048]

[0049] The above raw materials are 100g in total.

[0050] Prepared according to the following steps:

[0051] Step 1. Add 10 g of butyl titanate into 30 g of isopropanol, stir to make it fully dissolve, then add 2 g of diethanolamine dropwise while stirring, and stir for 45 minutes to obtain solution A;

[0052] Step 2: Add 0.5g of hydrochloric acid and 0.5g of water into 15g of isopropanol, stir and mix evenly to prepare solution B;

[0053] Step 3. Add solution B dropwise to solution A while stirring, continue to stir for 90 minutes after the addition, and leave to age for 30 hours after stirring to obtain Sol C;

[0054] Step 4: Add 42g of quartz sand to sol C, stir to make it fully wet, let it stand for 15 hours, filter and dry the quartz sand at 70°C for 60 minutes, and then calcinate at 700°C for 3 hours, after annealing and cooling, the product ...

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Abstract

The invention discloses reflective insulation nano-modified quartz sand which comprises, in weight percentage, 5%-35% of butyl titanate, 20%-75% of solvents, 1%-8% of chelating agents, 0.2%-5% of pH (potential of hydrogen) regulators, 0.2%-5% of water and 15%-70% of quartz sand. The preparation method includes the steps: firstly, adding the butyl titanate into the solvents, stirring the butyl titanate, sufficiently dissolving the butyl titanate, dripping the chelating agents and stirring the chelating agents to obtain solution A; secondly adding the pH regulators and the water into the solvents and stirring the pH regulators and the water to obtain solution B; thirdly, dripping the solution B into the solution A, continuing stirring, and performing standing and aging after stirring to obtain sol C; fourthly, adding the quartz sand into the sol C, stirring the quartz sand, sufficiently wetting the quartz sand, drying the quartz sand after standing and filtering, calcining the quartz sand at high temperature and annealing and cooling the quartz sand to obtain final products. The reflective insulation nano-modified quartz sand has the advantages that the reflective insulation nano-modified quartz sand can be applied to really stone paint, and reflective insulation performance is enhanced while coating sand texture cannot be affected.

Description

technical field [0001] The invention relates to a reflection heat insulation material, in particular to a reflection heat insulation nano-modified quartz sand and a preparation method thereof. Background technique [0002] In recent years, with the rapid development of the petroleum industry, transportation industry, construction industry, weapon industry, etc., coatings that can make the coated object produce a cooling effect under sunlight have attracted widespread attention. Various solar shielding coatings, heat reflective coatings , space heat insulation coatings, energy-saving thermal insulation coatings and other products are constantly coming out to reduce the surface temperature of equipment exposed to solar radiation, prevent heat conduction, improve the working environment, and improve safety. For example, offshore drilling platforms, oil tanks, and oil transportation in the petroleum industry; surfaces of automobiles, trains, and aircraft in the transportation in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/33C09D7/12C09C1/28C09C3/06
CPCC01P2006/90C09C1/28C09C3/063C09D5/004C09D7/62
Inventor 徐金宝杜丕一王宗荣月杨宇胡锦平钟国伦
Owner ZHEJIANG UNIV
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