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Method for enriching low concentration copper in water through carrageenan chelating technology

A carrageenan and low-concentration technology, applied in the preparation of test samples, measuring devices, instruments, etc., can solve the problems of copper ion detection error and poor repeatability of results, and achieve simple operation process and high detection accuracy Effect

Inactive Publication Date: 2017-03-22
DALIAN UNIV OF TECH QINGDAO NEW ENERGY MATERIALS TECH RES INST CO LTD
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AI Technical Summary

Problems solved by technology

[0002] When measuring the copper content by the sodium diethylaminodithioformate method, it is necessary to use the cresyl red indicator to determine the titration end point by looking at the change of the titration color, which undoubtedly causes a great error in the detection of copper ions. The results are not reproducible

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  • Method for enriching low concentration copper in water through carrageenan chelating technology

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Embodiment Construction

[0018] Below in conjunction with example the present invention will be further described.

[0019] Carrageenan chelation method is the method for enriching low-concentration copper in water, and the steps are as follows:

[0020] (1) Accurately weigh three parts of carrageenan powder, 0.5-1.0g, into 200mL beakers labeled 1, 2, and 3 for later use, and set up blank comparison beakers No. 4, 5, and 6; dissolve the above-mentioned carrageenan powder in 30-70mL Heat and stir in deionized water, and set the constant temperature to 60-85° C. until the carrageenan powder is completely dissolved to obtain a clear and transparent carrageenan solution.

[0021] (2) Prepare copper ion standard solutions, and prepare several low-concentration copper ion standard solutions of 10mg / L~0.05mg / L respectively. The concentration of copper ions was detected by atomic absorption spectrophotometry and a standard curve was drawn.

[0022] (3) Measure 50 mL of copper ion standard solution with a co...

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Abstract

The invention provides a method for enriching low concentration copper in water through a carrageenan chelating technology. The method comprises the following steps: dissolving carrageenan powder, mixing obtained carrageenan solution with a standard copper ion solution, chelating carrageenan and copper ions to obtain a chelate, dialyzing the chelate, adding hydrochloric acid to break the chelate structure, detecting obtained copper ion enriched liquid by using an atomic spectrophotometer, and calculating according to a standard curve of the standard copper ion solution in order to obtain the copper content. The method improves the detection precision of copper in a water sample with low concentration of copper ions, is simple, and is easy to implement.

Description

technical field [0001] The invention relates to a metal ion detection method, in particular to a carrageenan chelation method for enriching low-concentration copper in water. Background technique [0002] When measuring the copper content by the sodium diethylaminodithioformate method, it is necessary to use the cresyl red indicator to determine the titration end point by looking at the change of the titration color, which undoubtedly causes a great error in the detection of copper ions. The results are not reproducible. Using the characteristics of chelated metal ions of carrageenan itself to enrich the low-concentration copper ion solution for atomic absorption spectrophotometric detection can avoid errors caused by visual color changes and improve detection accuracy. Contents of the invention [0003] The present invention aims to solve the above problems, and provides a method for enriching low-concentration copper in water by carrageenan chelation method, utilizing c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N1/34G01N21/31
CPCG01N1/34G01N21/3103
Inventor 池明刘鑫业李鹏廷
Owner DALIAN UNIV OF TECH QINGDAO NEW ENERGY MATERIALS TECH RES INST CO LTD
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