Method for preparing anti-microbial formaldehyde degradation plastic masterbatch
A technology for plastic masterbatch and formaldehyde is applied in the field of preparation of antibacterial and formaldehyde-removing plastic masterbatch, which can solve the problems of high cost, difficult implementation, low efficiency and the like, and achieve the effects of low production cost, easy implementation and high efficiency
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Embodiment 1
[0016] In one embodiment of the present invention, the preparation method of this kind of antibacterial and formaldehyde-removing plastic masterbatch is as follows:
[0017] (1) with TiCl 4 As a titanium source, slowly drop it into the ice-water mixture to obtain Ti-containing 4+ Ionic colorless transparent liquid; add dropwise ammonia water with a volume fraction of 4% to the transparent liquid to obtain a white precipitate Ti(OH) 4 , wash the precipitate with deionized water to remove the NH 4+ and Cl - ion;
[0018] (2) The precipitated Ti(OH) obtained in step (1) 4 dissolved in H 2 o 2 , to obtain a transparent orange-yellow liquid, adding a volume fraction of 4% ammonia water, stirring rapidly, the transparent orange-yellow liquid turns into a white emulsion;
[0019] (3) A certain amount of ethyl orthosilicate (Si(OC 2 h 5 ) 4 ) into the white emulsion obtained in step (2), stirred, heated to reflux for 4 hours, and then filtered to obtain white uniform TiO 2 ...
Embodiment 2
[0023] In one embodiment of the present invention, the preparation method of this kind of antibacterial and formaldehyde-removing plastic masterbatch is as follows:
[0024] (1) with TiCl 4 As a titanium source, slowly drop it into the ice-water mixture to obtain Ti-containing 4+ Ionic colorless transparent liquid; add dropwise ammonia water with a volume fraction of 5% to the transparent liquid to obtain a white precipitate Ti(OH) 4 , wash the precipitate with deionized water to remove the NH 4+ and Cl - ion;
[0025] (2) The precipitated Ti(OH) obtained in step (1) 4 dissolved in H 2 o 2 , to obtain a transparent orange-yellow liquid, adding a volume fraction of 5% ammonia water, stirring rapidly, the transparent orange-yellow liquid turns into a white emulsion;
[0026] (3) A certain amount of ethyl orthosilicate (Si(OC 2 h 5 ) 4 ) into the white emulsion obtained in step (2), stirred, heated to reflux for 6h, and then filtered to obtain white uniform TiO 2 / SiO ...
Embodiment 3
[0030] In one embodiment of the present invention, the preparation method of this kind of antibacterial and formaldehyde-removing plastic masterbatch is as follows:
[0031] (1) with TiCl 4 As a titanium source, slowly drop it into the ice-water mixture to obtain Ti-containing 4+ Ionic colorless transparent liquid; add dropwise ammonia water with a volume fraction of 6% to the transparent liquid to obtain a white precipitate Ti(OH) 4 , wash the precipitate with deionized water to remove the NH 4+ and Cl - ion;
[0032] (2) The precipitated Ti(OH) obtained in step (1) 4 dissolved in H 2 o 2 , to obtain a transparent orange-yellow liquid, add volume fraction of 6% ammonia water, stir quickly, and the transparent orange-yellow liquid turns into a white emulsion;
[0033] (3) A certain amount of ethyl orthosilicate (Si(OC 2 h 5 ) 4 ) into the white emulsion obtained in step (2), stirred, heated to reflux for 8 hours, and then filtered to obtain white uniform TiO 2 / SiO ...
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