Carbon nanotube single molecular junction preparation method with high success rate

A carbon nanotube, single-walled carbon nanotube technology, applied in nanostructure fabrication, specific nanostructure formation, nanotechnology for materials and surface science, etc. The result may not be achieved, etc., to achieve the effect of good stability and conductivity

Inactive Publication Date: 2017-04-26
NANKAI UNIV
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Problems solved by technology

[0004] Generally, even if some methods use single-walled carbon nanotubes as electrodes to prepare single-molecule junctions, the success rate is low, consuming a lot of manpower, material and financial resources, and the results may not be realized.

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  • Carbon nanotube single molecular junction preparation method with high success rate
  • Carbon nanotube single molecular junction preparation method with high success rate
  • Carbon nanotube single molecular junction preparation method with high success rate

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Embodiment Construction

[0024] The specific implementation manner of the present invention will be described in detail below in conjunction with the accompanying drawings.

[0025] Elastic steel sheet (1) ( figure 1 ) to spin coat a layer of polyimide (2) to act as an isolation layer ( figure 2 ), about 2 microns thick; using standard photolithography techniques to fabricate two layers of gold (3) parallel to each other on top of the insulating layer to act as support electrode pairs ( image 3 ); using reactive ion etching technology to etch on the insulating layer to obtain suspended grooves (4) as nano-bridges ( Figure 4 ); using alternating current electrophoresis technology to place the single-walled carbon nanotubes (5) with a length of about 100-500 microns in alignment in the middle of the plane ( Figure 5 ); using a mask to vapor-deposit a layer of gold (6) directly above the pair of supporting electrodes, so that the single-walled carbon nanotubes are fixed in the middle of the two lay...

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Abstract

The invention discloses a method of precisely stretching a carbon nanotube, and a method and process flow of efficiently constructing a single molecular junction by mean of a carbon nanotube. The carbon nanotube single molecular junction preparation method with a high success rate is implemented through a micro nano processing correlation technique and a mechanical controllable breakage junction technique. The carbon nanotube single molecular junction preparation method includes the steps: through a series of micro nano processing flows, making a stable single wall carbon nanotube chip; disposing the single wall carbon nanotube chip on a three-point bending device; continuously bending the chip substrate to break the single wall carbon nanotube so as to form a gap-controllable electrode pair; and forming a single wall carbon nanotube single molecule junction by adding organic molecules in the gap. The carbon nanotube single molecular junction preparation method can accurately regulate and control the size of the gap to match various molecule lengths, thus being able to realize high production capacity production of single wall carbon nanotube single molecule junctions, laying the foundation for realizing molecule devices with high performance, and having a relatively higher reference value for development of molecular electronics.

Description

technical field [0001] The invention belongs to a single-molecule junction with a single-walled carbon nanotube as an electrode, and relates to molecular electronics, nanometer materials, chemistry and many other fields. Background technique [0002] In the trend of miniaturization of electronic devices, molecular electronics has developed rapidly in recent years, and various molecular junction technologies have emerged as the times require. Moreover, compared with the multi-molecular junction, the unimolecular junction is smaller but does not lose its original characteristics, so the unimolecular junction has been greatly developed. So far, there are many techniques for constructing unimolecular junctions, including electromigration, electrochemical deposition, surface expansion-mediated deposition, scanning probe microscopy, and mechanically controlled fracture junctions. Compared with other technologies, the mechanically controlled fracture junction method has shown many...

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Application Information

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IPC IPC(8): B82B3/00B82Y30/00B82Y40/00
CPCB82B3/0019B82Y30/00B82Y40/00
Inventor 向东王璐王玲赵智凯梅婷婷张天倪立发张伟强
Owner NANKAI UNIV
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