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38 results about "Molecular junction" patented technology

Molecular Junctions. Nanostructure-based solar- and fuel cells, both organic and inorganic, hold promise for efficiently and cheaply converting solar energy into forms convenient for storage and transportation.

Preparation method of addressable nano molecular junction

The invention discloses a preparation method of an addressable nano molecular junction, belonging to the field of micro machining of nano materials and testing of nano electronic devices. The preparation method comprises the steps of: firstly, washing a piezoelectric ceramic substrate; preparing an insulation layer film on the piezoelectric ceramic substrate and obtaining a micro nano strip-shaped bulge on the middle; preparing a narrow-neck-shaped Au electrode film layer on the insulation layer film; placing the piezoelectric ceramic substrate in a vacuum chamber, respectively welding leads on two sides of the piezoelectric ceramic substrate and leading out a vacuum chamber; electrifying the piezoelectric ceramic substrate to ensure that the Au electrode film layer is broken to obtain a metal electrode pair with a nano gap; and finally, filling an organic molecular material in the nano electrode gap to obtain the addressable nano molecular junction. According to the invention, the gap controllable nano Au electrode pair is obtained through regulating bias voltages and electrifying time of two ends of the piezoelectric ceramic substrate, thus pollution and thermally induced ablation on a metal molecular interface when electrodes deposit on a molecular layer are avoided through molecule self-assembly in the gap.
Owner:NORTHEASTERN UNIV

Carbon nanotube single molecular junction preparation method with high success rate

The invention discloses a method of precisely stretching a carbon nanotube, and a method and process flow of efficiently constructing a single molecular junction by mean of a carbon nanotube. The carbon nanotube single molecular junction preparation method with a high success rate is implemented through a micro nano processing correlation technique and a mechanical controllable breakage junction technique. The carbon nanotube single molecular junction preparation method includes the steps: through a series of micro nano processing flows, making a stable single wall carbon nanotube chip; disposing the single wall carbon nanotube chip on a three-point bending device; continuously bending the chip substrate to break the single wall carbon nanotube so as to form a gap-controllable electrode pair; and forming a single wall carbon nanotube single molecule junction by adding organic molecules in the gap. The carbon nanotube single molecular junction preparation method can accurately regulate and control the size of the gap to match various molecule lengths, thus being able to realize high production capacity production of single wall carbon nanotube single molecule junctions, laying the foundation for realizing molecule devices with high performance, and having a relatively higher reference value for development of molecular electronics.
Owner:NANKAI UNIV

Graphene electrode chip for mechanically controllable break junction (MCBJ) technique

The invention discloses a graphene electrode chip for a mechanically controllable break junction (MCBJ) technique, and relates to a graphene electrode chip. The graphene electrode chip comprises a stainless steel sheet, graphene metal wires and epoxy resin, wherein the stainless steel sheet is used for preparing a substrate of a graphene chip; the graphene metal wires are mounted above the stainless steel sheet in a hanging manner and are fixed through the epoxy resin. A preparation method of the graphene electrode chip comprises the following steps of 1), preparing a stainless steel substrate; 2), preparing the epoxy resin; 3), coating the epoxy resin; 4), constructing a graphene electrode on one side; 5), curing the epoxy resin; 6), constructing the graphene electrode on the other side; 7), dropwise coating the epoxy resin; 8), curing the epoxy resin. The novel graphene chip applicable to an MCBJ is made by adopting the graphene metal wires which are relatively low in price and a simple stainless steel sheet structure; some defects of a metal electrode are successfully overcome; the graphene electrode chip has advantages of being low in cost, simple and convenient to operateion and further high in the stability of a molecular junction stability, and the like. The graphene electrode chip can be prepared in a common chemical laboratory, and has favorable generality.
Owner:XIAMEN UNIV

STM-BJ-based monomolecular junction thermoelectric potential measurement method and equipment thereof

The invention discloses an STM-BJ-based monomolecular junction thermoelectric potential measurement method and STM-BJ-based monomolecular junction thermoelectric potential measurement equipment. A Seebeck coefficient of a molecular junction is obtained by acquiring a single molecule, verifying the single molecule, measuring a thermal voltage, verifying the single molecule, repeatedly acquiring a plurality of pieces of data, and then carrying out corresponding statistics and calculation. A stable and easily-adjusted heat source is provided for a substrate based on an STM-BJ technology, so thatthe temperature difference is constructed at the two ends of the molecular junction, an independent voltage amplifier is introduced to measure the electromotive force generated by the temperature difference after the molecular junction is formed, and therefore measurement of the thermoelectric potential of the monomolecular junction is achieved. Compared with an MCBJ technology and an STM-BJ needle tip temperature control technology, the research means has the advantages of being simple, efficient, wide in adjustable range, high in error-tolerant rate and the like, the measurement efficiency of the monomolecular junction thermoelectric potential is greatly improved, research and development of a novel organic thermoelectric material are promoted, and powerful assistance is provided for thesociety where the energy urgently needs to be changed.
Owner:XIAMEN UNIV

Composite material, preparation method thereof and quantum dot light-emitting diode

The invention discloses a composite material, a preparation method thereof and a quantum dot light-emitting diode. The composite material comprises carbon quantum dots, organic molecule connectors and metal nano particles, and the surfaces of the carbon quantum dots are combined with hydroxyl groups; and one ends of the organic molecule connectors are combined with hydroxyl groups of the carbon quantum dots through carboxyl groups, and the other ends of the organic molecule connectors are combined with the metal nano particles through functional groups with a metal bonding property. On the premise of keeping the excellent performance of the carbon quantum dots, the luminescence performance of the carbon quantum dots can be enhanced by utilizing surface plasma resonance formed on the surfaces of the carbon quantum dots by the metal nano particles. The carbon quantum dots have very excellent conductivity by utilizing the good conductivity of the metal nano particles. The composite material disclosed by the invention is excellent in film-forming property, capable of effectively inhibiting the phenomenon of carbon quantum dot solid-state fluorescence quenching, good in bio-compatibility, low in preparation cost and easy to prepare.
Owner:TCL CORPORATION

A method for measuring reaction kinetics based on single-molecule electrical detection

The invention discloses a reaction kinetics measurement method based on single molecule electrical detection, and involves a chemical reaction kinetics measurement method. The method comprises the following steps: mixing molecular solid and a solvent, and obtaining a molecular solution; placing a chip under a microscope, aligning a blade with a metal wire, firstly conducting cross-cutting, and then cutting the metal wire through a tip of the blade to get the chip; installing the chip, a reaction pool, an O-ring and a seal cover; opening a motor, passing the blade to an incision through the upper top of the motor, and fracturing to form a nano-gap; conducting an in situ test, data record and data analysis, when the metal atoms point contact is disconnected and an electrode is formed; and conducting statistics on the distance between the step and the end in a conductance-distance curve, obtaining a column-like statistical chart, providing another dimension information for an electrical measurement of a molecular junction by the conductance-distance curve, observing changes in conductance in a BJ process when the molecular junction is stretched and closed with the electrode pair, obtaining the interval size opened by the electrode pair, and ultimately inferring the evolution information that the molecular junction conductance changes with the distance.
Owner:XIAMEN UNIV

Mercaptobenzene functionalized graphene/copper composite heat-conducting coating and preparation method

The invention relates to a mercaptobenzene functionalized graphene/copper composite heat-conducting coating and a preparation method. The synthesis general formula is TP-Gr-Cu, functionalized graphene TP-Gr and nano-copper are chemically connected through a mercaptobenzene molecular junction, sulfur atoms in the mercaptobenzene molecular junction and the nano-copper form a strong S-Cu covalent bond through electron tunneling, and an electron tunneling heat conduction path is constructed so that electrons can be freely conducted. The preparation method comprises the following steps of firstly, preparing the mercaptobenzene functionalized graphene, and then preparing the mercaptobenzene functionalized graphene/copper composite heat-conducting coating on a metal copper substrate through a pulse electrochemical co-deposition method. A novel graphene/metal composite heat conduction coating electron tunneling heat conduction path is constructed, chemical connection of graphene and nano-copper through mercaptobenzene molecular junctions is successfully established, the deposited mercaptobenzene functionalized graphene is compactly attached to the copper substrate, and the function of radiation heat dissipation of a molecular fan is achieved. A graphene/copper composite material has high heat conductivity coefficient and high heat conductivity; and compared with a composite material in which pi electrons participate in heat transfer, the heat-conducting coefficient is higher.
Owner:SHAOYANG UNIV

Preparation method of addressable nano molecular junction

The invention discloses a preparation method of an addressable nano molecular junction, belonging to the field of micro machining of nano materials and testing of nano electronic devices. The preparation method comprises the steps of: firstly, washing a piezoelectric ceramic substrate; preparing an insulation layer film on the piezoelectric ceramic substrate and obtaining a micro nano strip-shaped bulge on the middle; preparing a narrow-neck-shaped Au electrode film layer on the insulation layer film; placing the piezoelectric ceramic substrate in a vacuum chamber, respectively welding leads on two sides of the piezoelectric ceramic substrate and leading out a vacuum chamber; electrifying the piezoelectric ceramic substrate to ensure that the Au electrode film layer is broken to obtain a metal electrode pair with a nano gap; and finally, filling an organic molecular material in the nano electrode gap to obtain the addressable nano molecular junction. According to the invention, the gap controllable nano Au electrode pair is obtained through regulating bias voltages and electrifying time of two ends of the piezoelectric ceramic substrate, thus pollution and thermally induced ablation on a metal molecular interface when electrodes deposit on a molecular layer are avoided through molecule self-assembly in the gap.
Owner:NORTHEASTERN UNIV LIAONING

Mechanically controllable break junction device with multilevel control electrode spacing continuously changed as well as method

ActiveCN110455865AOvercome the jitter problemSmooth and continuous driveMaterial analysis by electric/magnetic meansHydraulic cylinderEngineering
The invention discloses a mechanically controllable break junction (MCBJ) device with multilevel control electrode spacing continuously changed as well as a method, applied to the field of molecular electronics. The mechanically controllable break junction device mainly comprises the following devices: a hydraulic cylinder, a piston push rod, an X axis linear displacement platform, a multichannelhydraulic valve, a support, a motor, a spiral push rod, a steel disc, a strut and a base, the hydraulic cylinder is divided into five hydraulic cylinders with different cross-sectional areas, a hydraulic cylinder with the largest cross-sectional area is pushed by moving pistons in four hydraulic cylinders with smaller cross-sectional areas and closing the valve, large cross-sectional area and small displacement are controlled by small cross-sectional area and large displacement, and high thrust is controlled by low thrust. When the mechanically controllable break junction device disclosed by the invention is acted on a nano break junction device chip, sub-femtometer-level precision control on distance between two electrodes can be realized, so that a molecular junction is precisely constructed. The mechanically controllable break junction device disclosed by the invention is a novel mechanically controllable break junction device and has longer displacement and more precise distance control compared with the traditional break junction device.
Owner:NANKAI UNIV

A single-molecule junction thermoelectric potential measurement method and equipment based on stm-bj

The invention discloses an STM-BJ-based monomolecular junction thermoelectric potential measurement method and STM-BJ-based monomolecular junction thermoelectric potential measurement equipment. A Seebeck coefficient of a molecular junction is obtained by acquiring a single molecule, verifying the single molecule, measuring a thermal voltage, verifying the single molecule, repeatedly acquiring a plurality of pieces of data, and then carrying out corresponding statistics and calculation. A stable and easily-adjusted heat source is provided for a substrate based on an STM-BJ technology, so thatthe temperature difference is constructed at the two ends of the molecular junction, an independent voltage amplifier is introduced to measure the electromotive force generated by the temperature difference after the molecular junction is formed, and therefore measurement of the thermoelectric potential of the monomolecular junction is achieved. Compared with an MCBJ technology and an STM-BJ needle tip temperature control technology, the research means has the advantages of being simple, efficient, wide in adjustable range, high in error-tolerant rate and the like, the measurement efficiency of the monomolecular junction thermoelectric potential is greatly improved, research and development of a novel organic thermoelectric material are promoted, and powerful assistance is provided for thesociety where the energy urgently needs to be changed.
Owner:XIAMEN UNIV
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