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Treating and recycling method for pesticide intermediate wastewater

A technology for intermediates and waste water, which is applied in the treatment and reuse of pesticide intermediate waste water. It can solve the problems that the effluent is difficult to meet the national discharge standard, the profit margin of the product is reduced, and the by-products are difficult to degrade. Processing cost and cost reduction effect

Inactive Publication Date: 2017-05-10
江苏和氏璧环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the high energy consumption of the traditional multi-effect evaporation process, the profit margin of the product is reduced
However, it is difficult to treat high-salt and high-COD wastewater by biochemical and physical chemical methods. At the same time, some by-products in pesticide intermediates are difficult to degrade, making it difficult for the final effluent to meet the national discharge standards.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] With a processing capacity of 6 tons per hour, design, install and debug each treatment device of the whole process, and finally conduct a field test, and conduct a pilot test on the pickling and alkali washing wastewater produced by a pesticide intermediate factory:

[0025] 1. The pH of the alkali washing wastewater in the factory is 13.6, COD cr is 220000mg / L, the pH of pickling wastewater is 1.4, COD cr 30000mg / L;

[0026] 2. The pickling and alkaline washing wastewater are sent to the flocculation tank through centrifugal pumps for flocculation treatment, in which the flocculant is polyaluminum chloride, the dosage is 50 g / ton of wastewater, and the coagulant is polyacrylamide with a molecular weight of 18 million. The dosage is 3 grams per ton of waste water, and the settling time is 1 hour;

[0027] 3. The supernatant after the flocculation and sedimentation treatment is passed into the sand filter tank device through the centrifugal pump, wherein the pomegrana...

Embodiment 2

[0033] With a treatment capacity of 4 tons per hour, the design, installation and commissioning of each treatment device in the whole process was carried out, and finally a field test was carried out, and a pilot test was carried out on the pickling and alkali washing wastewater produced by a pesticide intermediate factory:

[0034] 1. The pH of the alkali washing wastewater in the factory is 13.6, COD cr is 226000mg / L, pH of pickling wastewater is 1.2, COD cr 31000mg / L;

[0035] 2. The wastewater from pickling and alkali washing is sent to the flocculation tank through centrifugal pumps for flocculation treatment. The flocculant is polyaluminum chloride, the dosage is 60 g / ton of wastewater, and the coagulant is polyacrylamide with a molecular weight of 18 million. The dosage is 4 grams / ton of waste water, and the settling time is 1.5 hours;

[0036] 3. The supernatant after the flocculation and sedimentation treatment is passed into the sand filter tank device through the ...

Embodiment 3

[0042] Design, install and debug each treatment device of the whole process with a treatment capacity of 2 tons per hour, and finally conduct a field test, and conduct a pilot test on the pickling and alkali washing wastewater produced by a pesticide intermediate factory:

[0043] 1. The pH of the alkali washing wastewater in the factory is 13.8, the COD cr 228000mg / L, pH of pickling wastewater is 1.1, COD cr 32000mg / L;

[0044] 2. The wastewater from pickling and alkali washing is sent to the flocculation tank by centrifugal pumps respectively for flocculation treatment. The flocculant is polyaluminum chloride, the dosage is 70 g / ton of wastewater, and the coagulant is polyacrylamide with a molecular weight of 18 million. The dosage is 5 grams per ton of waste water, and the settling time is 2 hours;

[0045] 3. The supernatant after the flocculation and sedimentation treatment is passed into the sand filter tank device through the centrifugal pump, wherein the pomegranate ...

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Abstract

The invention belongs to the technical field of sewage treatment, and particularly relates to a treating and recycling method for pesticide intermediate wastewater. By process design of pretreatment, electroosmosis concentration, triple-effect evaporation and recycling and the like, wastewater zero discharging is implemented basically, and water resources can be recycled. The treating and recycling method for the pesticide intermediate wastewater has the advantages of small occupied area, high recycling rate of water resources, low running costs and good economic and social effects. The treating and recycling method can be widely used in pesticide intermediate enterprises.

Description

[0001] Technical field: [0002] The invention belongs to the technical field of sewage treatment, and in particular relates to a method for treating and reusing pesticide intermediate waste water. Through the coupling of flocculation sedimentation, electrodialysis concentration and three-effect evaporation and other technologies, the high-salt and high-COD wastewater generated in the pickling and alkali washing process stages in the production of pharmaceutical intermediates can be effectively treated. [0003] Background technique: [0004] In recent years, China's pesticide industry has developed very rapidly. In about 10 years, the output of pesticides has almost doubled, and the variety of pesticides has doubled. By the end of 2011, there were 774 chemical pesticide production enterprises above designated size in my country, which can produce more than 300 kinds of technical materials; more than 800 kinds of pesticide intermediates have been produced, with an output of nea...

Claims

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Application Information

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IPC IPC(8): C02F9/06C02F1/52C02F1/469C02F1/66C02F103/36
Inventor 高学理何召龙
Owner 江苏和氏璧环保科技有限公司