A radial micro-catalytic reaction unit and its application
A catalytic reaction and micro-reaction channel technology, applied in chemical instruments and methods, chemical/physical processes, chemical/physical/physicochemical processes, etc., can solve problems such as short residence time, large height and diameter, and local overheating, and achieve Ensure smooth operation, reduce production costs and prolong service life
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Embodiment 1
[0047] Such as figure 1 As shown, the radial micro-catalytic reaction unit adopted in this embodiment includes a central tube 1 made of a top sealing plate, a bottom sealing plate and side surfaces, and the central tube 1 also includes a central tube 2 arranged at the center of the central tube, and the central tube 2 The lower end is an opening. Such as figure 2 As shown, the central tube 2 is in fluid communication with the central cylinder 1 through the micro-reaction channel 3 . Such as Figure 5 As shown, in the micro-reaction channel 3 of the conical tube structure, the tube wall is coated with nickel, an active component of methanation reaction, and the two ends are hermetically connected to the side wall of the central tube 1 and the central tube 2 respectively.
[0048] The height of the micro-catalytic reaction unit is 200mm, the diameter is 150mm, and the diameter of the central tube is 30mm. The volume ratio of the central cylinder 1 is 65%.
[0049] The radi...
Embodiment 2
[0053] The difference between embodiment 2 and embodiment 1 is that the figure 1 Shown micro-catalysis reaction unit is inverted, and the reaction raw material inlet of embodiment 2 is the open end of center tube 2, and reaction raw material enters micro-reaction channel 3 through microchannel inboard opening 4 and after reacting with active component or catalyzer wherein, obtains The reaction product leaves the micro-reaction channel 3 from the opening 5 outside the micro-channel. This type of reactor is suitable for chemical reactions with increased reaction volume, such as cyclohexane dehydrogenation, ethylbenzene dehydrogenation, and ammonia decomposition reactions.
[0054] The radial micro-catalytic reaction unit is used for cyclohexane dehydrogenation reaction. The dehydrogenation reaction of cyclohexane is an endothermic reaction with increased volume. Cyclohexane evenly enters the micro-reaction channel 3 coated with platinum metal on the inner surface from the open ...
Embodiment 3
[0056] Such as image 3 with Figure 4 Shown, the structure parameter of the micro-catalysis reaction unit that embodiment 3 adopts is identical with embodiment 1 and 2, and quantity is 9, adopts 3 * 3 square arrangement, is used for methanation reaction, the micro-catalysis reaction unit of adjacent Seal between bottom sealing plates.
[0057] The conical tube micro-reaction channel in the integrated module is coated with Ni-based active metal components, and the module can be used for methanation reaction. The syngas enters the gap between the micro-catalytic reaction units from the feed port above, and the syngas enters each radial micro-catalytic reaction unit evenly, and enters the micro-reaction channel 3 coated with Ni-based catalyst from the outer opening 5 of the micro-channel , a methanation reaction occurs on the surface of the Ni-based active metal, and the reaction product leaves the micro-catalytic reaction channel 3 from the inner opening 4 of the micro-channe...
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