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A radial micro-catalytic reaction unit and its application

A catalytic reaction and micro-reaction channel technology, applied in chemical instruments and methods, chemical/physical processes, chemical/physical/physicochemical processes, etc., can solve problems such as short residence time, large height and diameter, and local overheating, and achieve Ensure smooth operation, reduce production costs and prolong service life

Active Publication Date: 2019-01-25
SINOPEC ENG +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Axial reactor design, relatively easy processing, and simple operation, but there are problems with large reactor equipment, large bed pressure drop, prone to local overheating, slow heat transfer, low conversion rate, obvious amplification effect, and the need for materials for the reactor. higher grade questions
The radial bed reactor has a large height-to-diameter ratio, a small bed pressure drop, and a short residence time of the reactants in the catalyst bed, but it is difficult to achieve uniform distribution of the reactants in the radial direction, and the production intensity of the unit catalyst bed is low
[0003] In order to overcome the problems of low heat transfer and mass transfer efficiency in traditional chemical industry, microchemical technology emerged in the 1980s and 1990s.

Method used

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  • A radial micro-catalytic reaction unit and its application
  • A radial micro-catalytic reaction unit and its application
  • A radial micro-catalytic reaction unit and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Such as figure 1 As shown, the radial micro-catalytic reaction unit adopted in this embodiment includes a central tube 1 made of a top sealing plate, a bottom sealing plate and side surfaces, and the central tube 1 also includes a central tube 2 arranged at the center of the central tube, and the central tube 2 The lower end is an opening. Such as figure 2 As shown, the central tube 2 is in fluid communication with the central cylinder 1 through the micro-reaction channel 3 . Such as Figure 5 As shown, in the micro-reaction channel 3 of the conical tube structure, the tube wall is coated with nickel, an active component of methanation reaction, and the two ends are hermetically connected to the side wall of the central tube 1 and the central tube 2 respectively.

[0048] The height of the micro-catalytic reaction unit is 200mm, the diameter is 150mm, and the diameter of the central tube is 30mm. The volume ratio of the central cylinder 1 is 65%.

[0049] The radi...

Embodiment 2

[0053] The difference between embodiment 2 and embodiment 1 is that the figure 1 Shown micro-catalysis reaction unit is inverted, and the reaction raw material inlet of embodiment 2 is the open end of center tube 2, and reaction raw material enters micro-reaction channel 3 through microchannel inboard opening 4 and after reacting with active component or catalyzer wherein, obtains The reaction product leaves the micro-reaction channel 3 from the opening 5 outside the micro-channel. This type of reactor is suitable for chemical reactions with increased reaction volume, such as cyclohexane dehydrogenation, ethylbenzene dehydrogenation, and ammonia decomposition reactions.

[0054] The radial micro-catalytic reaction unit is used for cyclohexane dehydrogenation reaction. The dehydrogenation reaction of cyclohexane is an endothermic reaction with increased volume. Cyclohexane evenly enters the micro-reaction channel 3 coated with platinum metal on the inner surface from the open ...

Embodiment 3

[0056] Such as image 3 with Figure 4 Shown, the structure parameter of the micro-catalysis reaction unit that embodiment 3 adopts is identical with embodiment 1 and 2, and quantity is 9, adopts 3 * 3 square arrangement, is used for methanation reaction, the micro-catalysis reaction unit of adjacent Seal between bottom sealing plates.

[0057] The conical tube micro-reaction channel in the integrated module is coated with Ni-based active metal components, and the module can be used for methanation reaction. The syngas enters the gap between the micro-catalytic reaction units from the feed port above, and the syngas enters each radial micro-catalytic reaction unit evenly, and enters the micro-reaction channel 3 coated with Ni-based catalyst from the outer opening 5 of the micro-channel , a methanation reaction occurs on the surface of the Ni-based active metal, and the reaction product leaves the micro-catalytic reaction channel 3 from the inner opening 4 of the micro-channe...

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Abstract

The invention discloses a radial micro-catalytic reaction unit and application thereof. The radial micro-catalytic reaction unit comprises a central cylinder having a central tube. One end of the central tube is an opening. The outboard of the central cylinder is in fluid communication with the central tube through micro-reaction channels which radially penetrate through the central cylinder. The micro-reaction channels have micro-channel inside openings and micro-channel outside openings which have different diameters. The micro-catalytic reaction unit can be used for a reaction with reaction volume changing. In addition, use amount of a catalyst is small; pressure drop is low; retention time is short; utility rate of space is high; and there is no gas bias current or short circuit phenomenon.

Description

technical field [0001] The invention relates to a radial micro-catalysis reaction unit and its application. Background technique [0002] At present, there are mainly two types of fixed bed reactors, one is axial fixed bed reactor, and the other is radial fixed bed reactor. Axial reactor design, relatively easy processing, and simple operation, but there are problems with large reactor equipment, large bed pressure drop, prone to local overheating, slow heat transfer, low conversion rate, obvious amplification effect, and the need for materials for the reactor. high-level issues. The radial bed reactor has a large height-to-diameter ratio, a small bed pressure drop, and a short residence time of the reactants in the catalyst bed, but it is difficult to achieve uniform distribution of the reactants in the radial direction, and the production intensity of the unit catalyst bed is low. [0003] In order to overcome the problems of low heat transfer and mass transfer efficienc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J19/00C10L3/08
Inventor 张旭戴文松王子宗蒋荣兴
Owner SINOPEC ENG
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